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71.
The parallel between orbital first and second electric moments and statistical first and second central moments is noted. Three measures of orbital spatial distribution in terms of their moments are proposed, and applied to the LMO's in a series of ten-electron hydrides. Consistent differences between bond and lone pair distributions are found. Using the statistical interpretation, for each LMO an effective solid angle around the central atom is postulated. 相似文献
72.
Alexander Kane Ren-Fan Shao Joseph E Maclennan Lixing Wang David M Walba Noel A Clark 《Chemphyschem》2007,8(1):170-174
We demonstrate, both theoretically and experimentally, that it is possible to use an electric field to drive the formation of macroscopic chiral (conglomerate) domains from an initially homogeneous fluid racemate. Field-induced segregation is exhibited in a fluid smectic liquid-crystal phase of a racemic mesogen, wherein enantiomerically-enriched domains are readily identifiable by their chiral electro-optical response. The sharp field-generated boundaries that form between opposite-handed domains broaden by diffusion in the absence of field, but reform rapidly if the field is switched on again, providing unambiguous evidence for the field-driven physical separation of enantiomers. A mean-field model successfully describes the steady-state and the dynamic evolution of conglomerate formation. 相似文献
73.
Ogbonnaya Ofor 《Journal of colloid and interface science》1996,180(2):323
Using “pure” natural hematite selected from a high silica Nigerian hematitic ore, oleate adsorption densities at the hematite–water interface were determined in the presence of various inorganic ions (anions and cations) of different charges and at varying concentrations. Adsorption density was determined using electrical conductivity measurements. The specific surface area of the hematite particles was determined using the method of adsorption of paranitrophenol in aqueous solution. Inorganic ions in solution depressed oleate adsorption at the aqueous hematite surface. The charge of the ion proved to be the dominant factor determining the depression of oleate adsorption. Ionic strength also was an influence, up to a limiting value at which monolayer oleate coverage of the hematite surface occurred. The inorganic ions in solution are considered to function through nonspecific adsorption in the diffuse region of the electric double layer. 相似文献
74.
The structure of the double electric layer (DEL) on a liquid dropping Sn-Ga electrode containing 8 at. % of Sn is studied in acetonitrile (AN) solutions of electrolytes. It is shown that the transition from aqueous to AN solutions of electrolytes makes it possible to expand the region of investigation of parameters of DEL on an Sn-Ga electrode from negative charges to a zero charge and to small positive charges. As follows from the obtained data, throughout the entire interval of charges studied, an excess, as compared with an Hg electrode, chemisorption interaction (Sn-Ga)-AN is absent. It is established that the distance of the closest approach of AN dipoles to an ionic core increases upon going from Hg to Sn-Ga to Ga. The Ga, Bi-Ga, and Sn-Ga electrodes, which possess close values of the “electrochemical work function,” are used as an example to show that the metal-solvent chemisorption interaction increases with decreasing distance of the closest approach of its dipoles to the ionic core of the metal. The effect of this factor becomes stronger as the donor number of the solvent increases. 相似文献
75.
Andrzej Czopnik Nataly Shitsevalova Alexander Krivchikov Vasyl Pluzhnikov Yuriy Paderno 《Journal of solid state chemistry》2004,177(2):507-514
We have measured heat capacity and thermal expansion of rare earth dodecaborides REB12 (RE=Y, Tb-Tm, Lu). YB12 and LuB12 are diamagnetics whereas the other dodecaborides are ordered antiferromagnetically. The amplitude of the heat capacity discontinuity at the Néel temperature and the shape of the heat capacity variation in the critical region for all these antiferromagnetics are characteristics for amplitude-modulated magnetic structures. In the ordered state TbB12 reveals two first-order phase transitions, most likely due to magnetic structure changes. The heat capacity of ErB12 just below the Néel point shows an anomaly of unclear origin. From the Schottky contribution to the heat capacity we have determined crystal field parameters. They are completely different than that is estimated from Point Charge Model. 相似文献
76.
共混合聚(醚-酯)多嵌段共聚物的表面表征及其血液相容性研究 总被引:2,自引:0,他引:2
本文通过X-射线光电子能谱(XPS)、表面接触角、表面ξ电位和血液相容性实验,研究了聚(醚-酯)多嵌段共聚物及其共混物的表面组成和性质与血液相容性的关系。实验结果表明,疏水性的PET-PTMO多嵌段共聚物的血液相容性很差,并且与表相中软段的富集量无关;当亲水性的PET-PEO多嵌段共聚物与疏水性的PET-PTMO多嵌段共聚物共混后,发现存在着一个最佳的共混比例,此时材料表面的血小板粘附量大大降低。对于共混物,表相△[C—O)/[C—O]和表面ξ电位可以较好地与血小板粘附量相关联。以上结果清楚地表明,材料表面的亲-疏水性平衡、软段深度层次分布及表面电位是影响血液相容性的重要因素。 相似文献
77.
The mutual influence of SO2 and Cl2 during their consecutive chemisorption on the In2O3 surface has been investigated. It was found that SO2 is chemisorbed in the uncharged form, and the amount of chemisorption decreases as the temperature increases. The preliminary chemisorption of Cl2 results in a dramatic decrease in the amount of SO2 sorbed and in a change in the character of the bonding of SO2 with the oxide surface. When SO2 is sorbed first, the temperature of the formation of chlorides during subsequent chemisorption of Cl2 decreases.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1718–1721, October, 1994. 相似文献
78.
微量元素锌在治疗Bell麻痹中的作用 总被引:1,自引:0,他引:1
陈贤雄 《广东微量元素科学》2002,9(3):31-35
为探讨急性早期应用补锌和综合疗法治疗Bell麻痹 ,将 1 5 8例Bell麻痹患者 ,随机分成两组 :(1 )补锌组 (补锌 +综合疗法 ) ;(2 )对照组 (单纯综合疗法 )。对其进行了观察对比治疗 ,同时检测了所有患者治疗前后自身对照发锌值 ,还对所有患者进行了定位诊断、面神经电反应测试、并对面肌功能进行评分。结果表明 ,对定位诊断其病变在D段、面肌功能评分在 1 1分以下、面神经无电反应患者 ,即使给予早期综合治疗 ,效果仍较差 ,而早期给予补锌加综合治疗效果优于对照组 ,其它段内患者治疗次数和治愈天数也均优于对照组。可见微量元素锌在发挥免疫应答、免疫调控中的重要作用 相似文献
79.
输电线路覆冰对电力系统安全运行具有严重威胁,目前已经发展了多种防冰除冰方法,但每种方法都有其局限性,对于一些具有微气象、微地形特征的重覆冰地区尚未有较好的解决方法。文中考虑到扩径导线的特点和分裂导线输电线路的局限性,根据波阻抗和自然功率将分裂导线等效为单导线,并考虑电流的集肤效应,得到了等效的单根扩径导线,进而分析比较覆冰地区的分裂导线及其等效的单根扩径导线的表面电场特性。研究表明:等效前后导线截面面积相同且波阻抗一致时,扩径导线与分裂导线相比,不仅显著降低了子导线根数和输电线路的覆冰荷载,而且在扩径导线的半径等于分裂导线的等效单导线半径时,扩径导线的表面最大电场强度小于分裂导线。因此,在严重覆冰地区,采用分裂导线等效半径的扩径导线具有非常好的表面电场特性,且可显著降低冰风荷载,提高抗冰强度。 相似文献
80.
为了解决当前电力系统巡检难度大、效率低、数据不足以支撑大规模训练的问题,提出一种基于孪生网络的小样本检测方法。首先,在Faster RCNN(faster region convolutional neural network)目标识别算法的框架下,搭建支持图片和查询图片共享的孪生网络模型;然后,利用改进的RPN(region proposal network)模块产生更高质量的proposals;最后,在检测头上对支持图片和查询图片的RoI(region of interest)进行关联匹配。结果表明,将算法应用于自主构建的EPD(electric power detection)数据集,在仅利用10张支持图片的情况下,就能实现对电力背景下鸟巢异物和绝缘子相关类别的检测,检测指标mAP达到18.92%。与其他算法相比,应用于电力行业目标检测的孪生网络小样本模型,在极端小样本情况下性能优良,同时具有更加轻量化的优势,可为电力检测新方法研究提供参考。 相似文献