经济增长与宏观经济运行模型

对国民经济进行宏观调控，如同经济增长问题一样是一个永恒问题，对宏观调控的基本内容，手段，方法，国内外学者已进行了较多的规范性讨论，尤其是在数理分析方面，也已有许多具有普遍意义的成果，但是，要把那些成果转化为“生产力”从而变成清晰的，简明的，可操作的手段和方法，尚需人们不断的探索，本文通过对国民经济运行过程中若干宏观经济变量之间的数量关系分析，并以此建立了的国民经济宏观数量模型，就是尝试性的探索。     

非晶态Te_（81）Ge_（15）Sb_4薄膜材料的电学性能

对用熔体淬火再真空蒸发所制备的非晶态Ｔｅ＿（８ｌ）Ｇｅ＿（１５）Ｓｂ＿４薄膜的伏－安特性，直流电导率及玻璃转变温度等性能进行了研究。结果表明，这种材料具有较好的开关效应及较高的热稳定性，可用作开关器件等。     

Partial molal heat capacities of aqueous tetraalkylammonium bromides as functions of temperature

Enthalpies of solution have been measured from 5 to 85°C for aqueous tetraethyl- and tetrapropylammonium bromides, and the integral heat method is employed to evaluate for these electrolytes over a wide temperature range. Data taken from the literature have been used to evaluate for aqueous Bu₄NBr over a similar temperature range. These data, along with similar data for Me₄NBr, previously reported, have been used to evaluate absolute ionic heat capacities. While the absolute values agree only qualitatively with two other methods of division, the temperature dependences of the three methods essentially agree up to 65°C. Heat capacities due to structural effects on the solvent, obtained by subtracting the inherent heat capacities of the ions, are extraordinarily positive for all four tetraalkylammonium ions and have negative temperature coefficients, indicating that all four ions, including the tetramethylammonium ion, are structure-making ions.     

稀土高碳当量灰口铸铁组织与性能的研究

本文研究了利用稀土合金改善高碳当量灰口铸铁质量的可能性,稀土合金对高碳当 量灰口铸铁组织和性能影响的规律,以及稀土夹杂物在铸铁各相中分布的规律．发现了 稀土合金加入量与铸铁的机械性能之间明显的对应关系——“双峰值效应”。对稀土高 碳当量灰口铸铁的某些高温机械、物理、化学性能进行了研究。结果表明稀土合金加入 到高碳当量灰口铸铁中以后能净化铁水,改善组织,并提高其性能．     

The “Facilitated Transition” hypothesis as an explanation for the gemdialkyl effect

A new technique of searching the conformational space of transition states was used to explore the cause of the rate acceleration in the gem-dialkyl effect in intramolecular cyclization reactions. Several previous hypotheses were discarded and a new hypothesis was advanced based on this new data. This hypothesis, the “Facilitated Transition” hypothesis, states that increased steric hindrance reduces the overall activation energy by facilitating rotation through the transition state. The older “Reactive Rotamer” hypothesis was eliminated by generating all conformations of the starting materials using the and computer programs and demonstrating that no relationship is found between rate increase and a change in the concentration of “reactive rotamers”.     

四磺酸基酞菁锌在水和非水溶剂中的电化学性质研究

在非水溶剂（二甲基亚砜（ＤＭＳＯ）及Ｎ,Ｎ＿二甲基甲酰胺（ＤＭＦ））中的伏安曲线．呈现三对电流峰,表明存在三个可逆或准可逆酞菁配体的单电子转移过程,而在水溶液中则不呈现准可逆行为,且波形改变很大．此外,还比较了四磺酸基酞菁锌的水溶液在自然光和红光（６００～７００ｎｍ）照射下的循环伏安曲线,其氧化还原峰的数目和峰电位基本不变,但在红光照射下比自然光照射下的峰电流明显增大．     

The Substituent Effects of tert-Butyl Radical Addition to 2-Substituted Allyl Chlorides

The relative rates for the addition reactions of tert-butyl radical to 2-substituted ally chlorides I have een determined. The correlation of log k/k₀, vs. σ_m gives a ρ mvalue of 3.59 with correlation coefficient of 0.930. When the substituent CH₂Cl is excluded, correlation coefficient raises to 0.990 and ρ value becomes 3.39. The large p value and the deviation of relative rate of substituent CH₂C1 are discussed.     

Studies of solvent effects

The effect of water on the conformational preferences of acetylcholine has been studied within the discrete, the continuum and the combined discrete-continuum models described in parts I and II of this series. All the models lead to the conclusion that the trans-gauche form which is, following refined quantum-mechanical computations, the intrinsically preferred one and the one observed in the crystal of acetylcholine and of a number of analogues should remain also the preferred conformation in water. This result agrees with NMR studies. The results of the empirical discrete model used here compare favorably to those obtained by an ab initio super-molecule treatment. The continuum model utilized here represents a net improvement above such models utilized in other works.     

分数阶黏弹性饱和地基与板的共同作用

基于层状分数阶黏弹性横观各向同性饱和地基的固结解答,采用边界元法与有限元法耦合的方法,探讨板与黏弹性饱和地基的共同作用。首先基于Mindlin中厚板理论,得到板的总刚度矩阵方程;随后引入分数阶黏弹性饱和地基的精细积分解答,获得地基柔度矩阵方程;最后利用板?土协调条件,得到黏弹性饱和地基与板共同作用的解答。与已有文献对比,验证了本文解的正确性,并讨论黏弹性饱和地基参数和地基加固深度等因素对筏板与地基共同作用的影响。     

高层建筑外附雨篷的表面风压和气动力系数

采用风洞试验方法研究高层建筑外附雨篷的风压特征,分析风压系数、风压相关性、非高斯性和整体升力系数随风向角的变化,给出围护结构的设计风压,最后研究倾角和出挑长度对整体力系数的影响. 研究发现,高层建筑外附雨篷上表面风压系数在正迎风时最大值接近1.4,系气流受到后方高层建筑的阻挡下翻导致;上、下表面的最大整体压力系数出现正迎风情况,最大值分别为1.24和0.76;上、下表面的最大整体升力系数出现侧风面,最大值分别为1.13和1.01;上下叠加后测点风压的非高斯性比单表面增强;上表面和下表面的升力系数在0°~70°风向呈现高斯分布,在80°~180°风向呈现较强的非高斯分布;高层建筑外附雨篷上表面的极值正压大于下表面;雨篷整体升力系数按照倾角-10°、0°、10°依次递增.