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121.
L. Sauguet B. Ameduri B. Boutevin 《Journal of polymer science. Part A, Polymer chemistry》2006,44(15):4566-4578
The radical terpolymerization of 8‐bromo‐1H,1H,2H‐perfluorooct‐1‐ene with vinylidene fluoride (VDF) and perfluoro(4‐methyl‐3,6‐dioxaoct‐7‐ene) sulfonyl fluoride is presented. Changing the feed compositions of these three fluorinated comonomers enabled us to obtain different random‐type poly[vinylidene fluoride‐ter‐perfluoro(4‐methyl‐3,6‐dioxaoct‐7‐ene) sulfonyl fluoride‐ter‐8‐bromo‐1H,1H,2H‐perfluorooct‐1‐ene] terpolymers containing various sulfonyl fluoride and brominated side groups. Yields higher than 70% were reached in all cases. The hydrolysis of the sulfonyl fluoride group into the ? SO3Li function in the presence of lithium carbonate was quantitatively achieved without the content of VDF being affected, and so dehydrofluorination of the VDF base unit was avoided. These original terpolymers were then crosslinked via dangling bromine atoms in the presence of a peroxide/triallyl isocyanurate system, which produced films insoluble in organic solvents such as acetone and dimethylformamide (which totally dissolved uncured terpolymers). The acidification of ? SO3Li into the ? SO3H function enabled protonic membranes to be obtained. The thermal stabilities of the crosslinked materials were higher than those of the uncured terpolymers, and their electrochemical performances were investigated. According to the contents of the sulfonic acid side functions, the ion‐exchange capacities ranged from 0.6 to 1.5 mequiv of H+/g, whereas the water uptake and conductivities ranged from 5–26% (±11%) and from 0.5 to 6.0 mS/cm, respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4566–4578, 2006 相似文献
122.
We study zero-dimensional valuations dominating a regular local ring of dimension n≥2. For this we introduce the proximity matrix and the multiplicity sequence (extending classical definitions of the case n=2) that are associated with the sequence of the successive quadratic transforms of the ring along the valuation. We describe the precise relations between these invariants and study their properties. 相似文献
123.
In this paper, we prove a sharpening of large deviation for increments of Brownian motion in (p,r)-capacity and Hölder norm case. As an application, we obtain a functional modulus of continuity for (p,r)-capacity in the stronger topology. 相似文献
124.
Raushan Z. Buzyakova 《Topology and its Applications》2007,154(4):917-924
We describe the structure of spaces of continuous step functions over GO-spaces. We establish a relation between the Dedekind completion of a GO-space L and properties of the space of continuous functions from L to 2 with finitely many steps. We use the established relation to prove that a countably compact GO-space L has Lindelöf Cp(L) iff the Dedekind remainder of L is Lindelöf and every compact subspace of L is metrizable. Or equivalently, a countably compact GO-space L has Lindelöf Cp(L) iff every compact subspace of L is metrizable and a Gδ-set in L. Other results are obtained. 相似文献
125.
Armen Shirikyan 《Probability Theory and Related Fields》2006,134(2):215-247
We consider a class of dissipative PDE's perturbed by an external random force. Under the condition that the distribution
of perturbation is sufficiently non-degenerate, a strong law of large numbers (SLLN) and a central limit theorem (CLT) for
solutions are established and the corresponding rates of convergence are estimated. It is also shown that the estimates obtained
are close to being optimal. The proofs are based on the property of exponential mixing for the problem in question and some
abstract SLLN and CLT for mixing-type Markov processes. 相似文献
126.
Vitalij A. Chatyrko 《Topology and its Applications》2007,154(7):1314-1320
In [J.M. Aarts, T. Nishiura, Dimension and Extensions, North-Holland, Amsterdam, 1993], Aarts and Nishiura investigated several types of dimensions modulo a class P of spaces. These dimension functions have natural transfinite extensions. The small transfinite compactness degree trcmp is such transfinite dimension function extending the small compactness degree cmp. We shall prove that there is no upper bound for trcmp in the class of metrizable spaces, i.e. for each ordinal number α there exists a metrizable space Xα such that trcmpXα=α. We also give a characterization of the dimension dim of a separable (compact) metrizable space in terms of the function cmp of the product of this space with a nowhere locally compact zero-dimensional factor. 相似文献
127.
Kullback-Leibler divergence and the Neyman-Pearson lemma are two fundamental concepts in statistics. Both are about likelihood ratios: Kullback-Leibler divergence is the expected log-likelihood ratio, and the Neyman-Pearson lemma is about error rates of likelihood ratio tests. Exploring this connection gives another statistical interpretation of the Kullback-Leibler divergence in terms of the loss of power of the likelihood ratio test when the wrong distribution is used for one of the hypotheses. In this interpretation, the standard non-negativity property of the Kullback-Leibler divergence is essentially a restatement of the optimal property of likelihood ratios established by the Neyman-Pearson lemma. The asymmetry of Kullback-Leibler divergence is overviewed in information geometry. 相似文献
128.
129.
New tools are introduced for the study of homogeneous continua. The subcontinua of a given continuum are classified into three types: filament, non-filament, and ample, with ample being a subcategory of non-filament. The richness of the collection of ample subcontinua of a homogeneous continuum reflects where the space lies in the gradation from being locally connected at one extreme to indecomposable at another. Applications are given to the general theory of homogeneous continua and their hyperspaces. 相似文献
130.
T. Radul 《Topology and its Applications》2007,154(8):1794-1798
R. Pol has shown that for every countable ordinal number α there exists a universal space for separable metrizable spaces X with trindX?α. W. Olszewski has shown that for every countable limit ordinal number λ there is no universal space for separable metrizable space with trIndX?λ. T. Radul and M. Zarichnyi have proved that for every countable limit ordinal number there is no universal space for separable metrizable spaces with dimWX?α where dimW is a transfinite extension of covering dimension introduced by P. Borst. We prove the same result for another transfinite extension dimC of the covering dimension.As an application, we show that there is no absorbing sets (in the sense of Bestvina and Mogilski) for the classes of spaces X with dimCX?α belonging to some absolute Borel class. 相似文献