Determination of the rheological behavior of epoxy–amine thermosets by dynamic mechanical analysis: Isothermal methods versus nonisothermal methods

The reticulation process of an epoxy resin using an amine as a cure agent was studied at different temperatures and concentrations of the cure agent with dynamic mechanical thermal analysis. The study was performed under both isothermal and nonisothermal conditions, and a temperature–time–transformation diagram was obtained. The measurements from the two modes gave similar results, although the nonisothermal mode required fewer experiments. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1965–1977, 2003     

应用测力—落刀装置对积屑瘤、鳞刺的研究

本文研制了一种测力—落刀装置,对积屑瘤和鳞剌的某些问题进行了试验研究。结果表明:在积屑瘤存在的区域内,由于刀具实际前角的增加,以及切屑与积屑瘤的接触长度小于自然接触长度,从而导致了切削力的降低。积屑瘤不是整体稳定不变的,也不是高频地整体脱落后再重新生长。而是基体比较稳定,头部产生高频的分裂、成长,其分裂的部分留在工件表面成为鳞剌,同时,引起了切削力的较大波动。切削力动态分量越大,相应的鳞剌高度越高。     

动态链接方式下基于VB的绿色软件构造

分析了程序在动态链接和静态链接两种模式下的优缺点，以及在动态链接方式下构造绿色软件的困难所在。本文以VB为例，给出了动态链接方式下如何去构造绿色软件的一种方法，由于大多数的可视化开发工具均提供了与VB类似的功能，因此可以用本文类似的方法来解决其它可视化开发软件开发出来的程序的类似问题。     

Basic study of the gelation of dimethacrylate‐type crosslinking agents

An investigation was made of the gelation of dimethacrylate‐type crosslinking agents in view of an application for separation media. The study mainly centered on a crosslinking agent, glycerol dimethacrylate (GDMA), which is relatively hydrophilic because of a hydroxyl group in the middle of its structure. The gelation of GDMA was compared with that of other hydrophobic crosslinking agents such as ethylene glycol dimethacrylate and 1,6‐hexanediol dimethacrylate. The diluents used in the study were toluene, toluene with methanol, and cyclohexanol. The gelation was observed in real time with a charge coupled device camera and dynamic light scattering (DLS). Also, the separated dry gels were extensively characterized with scanning electron microscopy, BET (N₂ absorption and desorption isotherm), and Fourier transform infrared. DLS analysis showed a stronger molecular interaction of GDMA gelation in toluene, whereas this interaction was much weaker in an alcoholic solvent such as toluene with methanol or cyclohexanol. This indicated that GDMA gelation might proceed through hydrogen bonding as well as a crosslinking reaction of vinyl groups. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 949–958, 2006     

Synthesis and micellization of amphiphilic poly(sebacic anhydride)–poly(ethylene glycol)–poly(sebacic anhydride) block copolymers

Amphiphilic biodegradable block copolymers [poly(sebacic anhydride)–poly(ethylene glycol)–poly(sebacic anhydride)] were synthesized by the melt polycondensation of poly(ethylene glycol) and sebacic anhydride prepolymers. The chemical structure, crystalline nature, and phase behavior of the resulting copolymers were characterized with ¹H NMR, Fourier transform infrared, gel permeation chromatography, and differential scanning calorimetry. Microphase separation of the copolymers occurred, and the crystallinity of the poly(sebacic anhydride) (PSA) blocks diminished when the sebacic anhydride unit content in the copolymer was only 21.6%. ¹H NMR spectra carried out in CDCl₃ and D₂O were used to demonstrate the existence of hydrophobic PSA domains as the core of the micelle. In aqueous media, the copolymers formed micelles after precipitation from water‐miscible solvents. The effects on the micelle sizes due to the micelle preparation conditions, such as the organic phase, dropping rate of the polymer organic solution into the aqueous phase, and copolymer concentrations in the organic phase, were studied. There was an increase in the micelle size as the molecular weight of the PSA block was increased. The diameters of the copolymer micelles were also found to increase as the concentration of the copolymer dissolved in the organic phase was increased, and the dependence of the micelle diameters on the concentration of the copolymer varied with the copolymer composition. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1271–1278, 2006     

动态等值论在文学翻译中的应用

美国的尤金·奈达博士(Dr.Eugene A. Nida)的动态等值论(Dynamic Equivalence)被许多学者推崇为评判译文质量优劣的标准以及翻译所追求的最终目标.在运用奈达的"动态等值"论来指导文学翻译时,应注意的问题是,译文如果要准确传递原文信息就要充分体现原作者的美学意图,这样才能使译文受众获得和原文受众基本一致的感觉.     

基于位移的抗震设计中位移模式的确定

根据地震强度、地震波、结构层数与跨度、强柱弱梁系数等影响水平位移模式的主要因素,通过大量算例分析,提出了确定基于位移的抗震设计中水平位移模式的方法.     

钢卷尺刻度在线测量系

本文介绍了一种钢卷尺刻度在线测量系统 ,它采用了高速摄像及计算机数据处理技术 ,文章阐述了系统的非接触动态测量原理 ,描述了光电信号的处理方法 .     

Viscoelasticity and birefringence of polyisoprene

The complex Young's modulus, E^*(ω), and the complex strain-optical coefficient, O^*(ω), which is the ratio of the birefringence to the strain, were measured for polyisoprene (PIP) over a frequency range of 1 ～ 130 Hz and a temperature range of 22 ～ ?100°C. The imaginary part of O^*, O″, was positive at low frequencies and negative at high frequencies. The real part, O′, was always positive and showed a maximum. The complicated behavior of O^* could be understood by the assumption that E^* = E_R^* + E_G^* and O^* = C_RE_R^* + C_GE_G^*, where E_R^* and E_G^* were complex quantities and C_R and C_G were constants. The C_R value, equal to the ordinary stress-optical coefficient measured in the rubbery plateau zone, was 2.0 × 10^?9 Pa^?1. The C_G value, defined as the ratio O″/E″ in the glassy zone, was ?1.1 × 10^?11 Pa^?1. The E_G^*, which was the major component of E^* in the glassy zone, showed almost the same frequency dependence as that of polystyrene and polycarbonate. The E_R^*, which was dominant in the rubbery zone, was described well by the bead-spring theory. The temperature dependence of the E_G^* was stronger than that of the E_R^*. This difference caused the breakdown of the thermorheological simplicity for E^* and O^* around the glass-to-rubber transition zone. © 1995 John Wiley & Sons, Inc.     

螺纹联接动载荷强度计算公式的探讨

该文以柴油机的连杆螺栓联接(非标准件)为例,在微机上用动力有限元方法对螺栓各圈螺牙的载荷分布,螺栓的静、动应力分布进行了计算与研究。提出了较材料力学经验公式精确的既简单又实用的螺纹联接的动载荷强度计算公式。