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61.
Aji P. Mathew Gabriel Groeninckx G. H. Michler H. J. Radusch Sabu Thomas 《Journal of Polymer Science.Polymer Physics》2003,41(14):1680-1696
The effects of the blend ratio and initiating system on the viscoelastic properties of nanostructured natural rubber/polystyrene‐based interpenetrating polymer networks (IPNs) were investigated in the temperature range of ?80 to 150 °C. The studies were carried out at different frequencies (100, 50, 10, 1, and 0.1 Hz), and their effects on the damping and storage and loss moduli were analyzed. In all cases, tan δ and the storage and loss moduli showed two distinct transitions corresponding to natural rubber and polystyrene phases, which indicated that the system was not miscible on the molecular level. However, a slight inward shift was observed in the IPNs, with respect to the glass‐transition temperatures (Tg's) of the virgin polymers, showing a certain degree of miscibility or intermixing between the two phases. When the frequency increased from 0.1 to 100 Hz, the Tg values showed a positive shift in all cases. In a comparison of the three initiating systems (dicumyl peroxide, benzoyl peroxide, and azobisisobutyronitrile), the dicumyl peroxide system showed the highest modulus. The morphology of the IPNs was analyzed with transmission electron microscopy. The micrographs indicated that the system was nanostructured. An attempt was made to relate the viscoelastic behavior to the morphology of the IPNs. Various models, such as the series, parallel, Halpin–Tsai, Kerner, Coran, Takayanagi, and Davies models, were used to model the viscoelastic data. The area under the linear loss modulus curve was larger than that obtained by group contribution analysis; this showed that the damping was influenced by the phase morphology, dual‐phase continuity, and crosslinking of the phases. Finally, the homogeneity of the system was further evaluated with Cole–Cole analysis. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1680–1696, 2003 相似文献
62.
In this paper, we exhibit a unified treatment of the mixed initial boundary value problem for second order (in time) parabolic linear differential equations in Banach spaces, whose boundary conditions are of a dynamical nature. Results regarding existence, uniqueness, continuous dependence (on initial data) and regularity of classical and strict solutions are established. Moreover, several examples are given as samples for possible applications.
63.
It has been shown that the kinetics of intramolecular processes and time-resolved spectra with allowance for the quantum beats of the resonant states of isomers or isolated subsystems of levels of one isomeric form can be described with the use of a molecular model interpreting the effect of beats as a nonradiative transition. We have obtained an expression for the nonradiative transition probability, which is directly proportional to the beat frequency and depends oscillatorily on time, thus modeling the effect of beats. The parameter of the molecular system model is the beat frequency directly related to the parameter characterizing the intramolecular interisomeric interactions (the corresponding nondiagonal element of the energy matrix) rather than the value of the nonradiative transition probability. The character of the change in the level populations and, accordingly, in the band intensities in the spectra in the proposed model is in good agreement with the experiment, including the fine structure of the time dependences — oscillations of the line intensities. In analyzing the temporal experiment with a high resolution, it is necessary to take into account the instrument function leading to quantitative and qualitative changes in the time dependences. The traditional model of nonradiative transitions with a constant probability value has a very limited range of applicability — very high beat frequencies compared to the probability of optical transitions. 相似文献
64.
65.
低压电力线通信的应用 总被引:2,自引:0,他引:2
石硕 《安徽工程科技学院学报:自然科学版》2004,19(1):52-57
综述了低压电力线通信(Power Line Communication,PLC)的技术特点、有关技术标准以及其产品和市场应用的情况,以使读者全面了解其发展现状;介绍了其作为接入网的应用框架,给出了小区(包括底层住宅、高层住宅和商用写字楼)低压PLC接入网的典型解决方案,以供有相关组网需求的读者参考.通过对比其他接入网方式,表明低压PLC具有覆盖面广、成本低廉、带宽较宽和安装容易的优点.结论是,低压PLC的应用必将越来越广泛. 相似文献
66.
极低硫钢的精炼脱硫动力学模型 总被引:2,自引:1,他引:1
通过对影响脱硫反应限制性环节的分析,将持续接触和瞬时接触两种反应模式综合考虑,建立了精炼脱硫动力学模型,并通过实验室"极低硫钢精炼脱硫"实验数据对模型进行验证.结果表明,本模型的预测结果与实验结果比较吻合. 相似文献
67.
李英 《四川师范大学学报(自然科学版)》2003,26(1):86-89
探讨了我国高等师范化学教育专业的《化学教学论》课程内容体系演变发展的特点和改革的经验,并对一些典型教材的编写特点进行了分析,提出了值得研究的问题。 相似文献
68.
地基基础-坝体体系动力特性及地震反应分析的有限元与无限元耦合法 总被引:2,自引:0,他引:2
编制了有限元及有限元—无限元耦合计算程序,利用其分析了广西源口拱坝在有限域及无限域地基下的动力特性与动力响应,并与常规刚性地基下坝体的动力特性、动力响应进行比较,得出结论:1.弹性地基下拱坝自振频率减小、动位移最大值增大;2.耦合分析法具有较高的精度和显著的经济性,是工程应用中值得推广的一种分析方法。 相似文献
69.
介绍转炉烟气分析控制系统,研究转炉烟气和炉气在冶炼过程中的变化规律,并开发烟气定碳模型。结论表明,在转炉冶炼过程中利用烟气成分的变化规律,可进行转炉炉况判断、终点判断和了解炉内反应过程。开发的烟气定碳模型对于含碳量低于0.12%的炉次,其控制精度为±0.02%,命中率为90%。 相似文献
70.