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41.
The mid-infrared (1500-3800 cm−1) absorption spectrum of gaseous nitric oxide has been studied at low temperature (99 K) with a long absorption path (160 m) in order to observe weak combination, difference, and overtone bands of the NO dimer. About ten new bands were assigned with greater or lesser certainty. Combined with previous results, they lead to a set of 12 secure and 7 tentative vibrational term values for (NO)2, essentially doubling our knowledge of NO dimer vibrational states. The strongest non-fundamental bands in this region, other than the ν1 (symmetric N-O stretch) + ν5 (asymmetric N-O stretch) overtone, involve combinations of ν5 with ν3 (intermolecular stretch). Excitation of ν5 results in increased frequencies for the intermolecular modes ν2, ν3, and ν4. A new value of 155.5 cm−1 was obtained for ν4, the elusive infrared-inactive out-of-plane fundamental vibration. 相似文献
42.
提出了单层光学薄膜中薄膜与衬底反射光之间的双重干涉效应的理论,实验结果证实了理论分析的正确性。双重干涉效应使薄膜-衬底体系的热致反射调制度高达80%,这一效应可望有极广泛的应用 相似文献
43.
Ronny Kleinhempel Gunar Kaune Matthias Herrmann Hartmut Kupfer Walter Hoyer Frank Richter 《Mikrochimica acta》2006,156(1-2):61-67
Indium tin oxide (ITO) thin films were deposited by mid frequency pulsed dual magnetron sputtering using a metallic alloy
target with 10 wt.% tin in an atmosphere of argon and oxygen. The aim of the work was to study the interdependence of structural,
electrical and optical properties of ITO films deposited in the reactive and transition target mode, respectively. The deposition
rate in the transition mode exceeds the deposition rate in the reactive mode by a factor of six, a maximum value of 100 nm·m min−1 could be achieved. This corresponds to a static deposition rate of 200 nm min−1. The lowest electrical resistivity of 1.1·10−3 Ω cm was measured at samples deposited in the high oxygen flow range in the transition mode. The samples show a good transparency
in the visible range corresponding to extinction coefficients being below 10−2. X-ray diffraction was used to characterise crystalline structure as well as film stress. ITO films prepared in the transition
mode show a slightly preferred orientation in (211) direction, whereas films deposited in the reactive mode are strongly (222)
oriented. Compared to undoped In2O3 all samples have an enlarged lattice. The lattice strain perpendicular to the surface is about 0.8% and 2.0% for films grown
in the transition and the reactive mode, respectively. Deposition in the transition mode introduces a biaxial film stress
in the range of −300 MPa, while stress in reactive mode samples is −1500 MPa. 相似文献
44.
It is well known that porphyrin derivatives play a key role in the primary process of photo-synthesis[1], in which porphyrins directly absorb the sunlight or indirectly acquire excitation en-ergy from light-harvesting antenna system to reach their excited state, and then donate electrons to quinone acceptors to yield a series of charge-separated species. In general, only first singlet ex-cited state of porphyrins is involved in energy transfer process[2]. However, highly excited state (S2 stat… 相似文献
45.
A novel sensitive and simple method for rapid and selective extraction, preconcentration and determination of iron (as its
bathophenanthroline complex) and copper (as its neocuproine complex) using octadecyl silica cartridges and dual wavelength
spectrophotometry is presented. The dual wavelength method (533 nm for the iron-bathophenanthroline and 454 nm for the copper-neocuproine
as the analytical wavelength) is used to eliminate spectral interferences. Extraction efficiency and the influence of flow
rates of sample solution and eluent, pH, amount of neocuproine, bathophenanthroline and hydroxylamine hydrochloride, type
and least amount of eluent for elution of iron and copper complexes from cartridge, break-through volume and limit of detection
are evaluated. The effects of various cationic and anionic interferences on percent recovery of iron and copper are also studied.
Extraction efficiencies >95% are obtained by elution of cartridges with minimal amount of organic solvent. Iron and copper
were determined in the range of 3–100 ng mL−1. The limits of detection are 0.98 and 1.13 ng mL−1 for iron and copper, respectively. The proposed method is applied successfully to the determination of both analytes in river,
tap and well water samples.
Author for correspondence. E-mail: yyamini@modares.ac.ir
Received September 18, 2002; accepted December 12, 2002
Published online May 5, 2003 相似文献
46.
Moonhor Ree Jong-Seong KimJae Jung Kim Byeang Hyean KimJuyoung Yoon Heesoo Kim 《Tetrahedron letters》2003,44(45):8211-8215
The synthesis of novel cavitands containing four fluorophores [tert-butoxycarbonyl protected 2,2′-bis(furyl)benzidine (t-BOC FurylBz) or 5,5′-bis(4-aminophenyl)-2,2′-bifuryl (t-BOC PFDA)] and ionophoric functional groups on the upper rim is reported. The cavitands bearing the four fluorophores emit blue light photoluminescence. In particular, the cavitand containing PFDA moieties exhibits a high photoluminescence quantum yield. 相似文献
47.
Summary The coupling of carbon dioxide supercritical fluid chromatography with Fourier transform infrared spectrometry (SFC-FTIR)
is a powerful tool for the separation and on-line identification of non-volatile compounds. The IR transparency of carbon
dioxide in the Fermi resonance bands region versus its density has been studied. Functional groups with stretching vibrations
outside the transparent window of carbon dioxide are examined. SFC-FTIR separations allow Gram-Schmidt reconstruction chromatograms
or IR window chemigrams with high quality spectra to be obtained. This SFC-FTIR lightpipe (flow cell, beam condensing optics,
narrow band detector) has allowed detection limits of 250ng for benzonitrile and 70ng for methyl benzoate to be reached. The
feasibility of very rapid SFC-FTIR separations is shown along with the subsequent peak spectra. 相似文献
48.
Ben Salem Nejib 《Journal of Theoretical Probability》1994,7(2):417-436
We consider hypergroups associated with Jacobi functions
()
(x), (–1/2). We prove the existence of a dual convolution structure on [0,+[i(]0,s
0]{{) =++1,s
0=min(,–+1). Next we establish a Lévy-Khintchine type formula which permits to characterize the semigroup and the infinitely divisible probabilities associated with this dual convolution, finally we prove a central limit theorem. 相似文献
49.
Haruto Ohta 《Proceedings of the American Mathematical Society》1996,124(3):961-967
Answering a question of Eklof-Mekler (Almost free modules, set-theoretic methods, North-Holland, Amsterdam, 1990), we prove: (1) If there exists a non-reflecting stationary set of consisting of ordinals of cofinality for each , then there exist abelian groups such that and for each . (2) There exist abelian groups such that for each and for each . The groups are the groups of -valued continuous functions on a topological space and their dual groups.
50.
基于语音识别的说话人身份辨识系统 总被引:2,自引:0,他引:2
提出一种在小字库孤立语音条件下,集成语音识别与说话人的识别技术,并进行说话人身份代码(密码)识别、认证.利用语音信号的短时分析技术进行孤立词的单元分割,采用临界带特征矢量作为语音信号特征,分析了经典语音识别算法——动态时间规整算法,提出了对语音模板各帧加权的改进方法.为提高识别响应速度,研究了多门限多轮次的判决方法,在增加多套模板、提高识别率的情况下,降低了系统的响应时间. 相似文献