烧结矿余热回收竖罐内气体流态的实验研究

采用对Ergun型方程无量纲化的方法对气体通过烧结矿床层的流态进行了研究,考察气体表观流速、烧结矿颗粒直径和床层空隙率对床层内气体压力降的影响,进而探讨床层内临界颗粒雷诺数随颗粒直径的变化规律.研究结果表明:当颗粒直径一定时,床层内单位料层高压力降随气体表观流速的增大呈二次方关系增大.当气体表观流速一定时,单位料层高压力降随颗粒直径和空隙率的增大呈指数关系衰减.床层内临界颗粒雷诺数随床层几何因子的增大呈指数关系减小,且临界颗粒雷诺数实验预测公式的平均计算误差在5%以内,显示了良好的预测性能.     

Sorptive elimination of fluoride from contaminated groundwater in a fixed bed column: A kinetic model validation based study

The current investigation involves a continuous adsorption experiment in a packed bed column for the sorptive elucidation of fluoride from contaminated groundwater using an activated soil-clay mixture. Through the combination of naturally accessible laterite soil with silica enriched clay (3:1 ratio), a low-cost Al–Si heterogeneous material has been developed. Following detailed characterization, the developed materials were employed in a long-time column process to achieve a high degree of fluoride separation from real-world groundwater. In a packed bed column investigation, the effect of bed height, initial fluoride concentration, and flow rate on the breakthrough properties of the adsorption system were investigated. By using a non-linear regression equation, three model kinetics, such as the Thomas Model, Adams-Bohart Model, and Yoon-Nelson Model, were fitted to validate the column-based experimental data, by analysing the breakthrough curves profiles, and distinct kinetic parameters. The Bed Depth Service Time Analysis (BDST) model was tested to express the effect of bed height on breakthrough curves, as well as to predict the time for breakthrough, and material depletion under optimal conditions. The Thomas and Yoon-Nelson models were identified to be the most appropriate ones for describing the entire breakthrough curve, whereas the Adams-Bohart model was only utilised to predict the first half of the dynamic process. With correlation coefficients (R²) 0.96, the experimental results were well suited to Thomas, Yoon-Nelson, and Adams-Bohart models. Finally, regeneration assessment was carried out where even after four cycles of operation, regenerated adsorbent showed a rejection efficacy of 78% to fluoride that proves the viability of the material and methodology.     

时滞反应扩散方程组周期解的存在性

利用上、下解方法及不动点理论研究了一类反应项非单调的时滞反应扩散方程组,构造了非单调反应项的上、下控制函数,并证明了所构造的函数满足Lipschitz条件及单调性,克服了反应项非单调无法利用单调迭代方法的局限性,为讨论反应项非单调的微分方程提供了一种有效方法,并获得了此系统边值问题周期解存在性的充分条件,推广了已有的一些结果.     

混沌现象中的定点研究

混沌现象是一种普遍存在的复杂的运动形式,在混沌区似乎没有稳定的状态,事实上仍然存在着一些稳定点;但这些稳定点是暂稳点。对混沌现象中的定点进行了详细的讨论,并分析了这些定点的稳定性。     

改进蚁群PID-神经元解耦的CFB锅炉燃烧系统控制

床温和主汽压都是循环流化床锅炉生产运行中的重要参数,会直接影响机组的安全性和经济性。但由于这两者对象存在非线性、大时延、强耦合等特点,其现场控制效果一直不太理想。本文首先采用自适应神经元将床温和主汽压解耦,再利用具有分工特征的蚁群算法优化参数的PID控制器对两者进行独立控制。采用该算法优化常规PID控制参数,能够实现控制参数的快速寻优。该方案应用于循环流化床锅炉燃烧系统仿真,结果表明能有效实现系统解耦,且具有响应快、超调量小等优点,有效地提高了控制品质。     

Functional Differential Equations With Delay and Random Effects

The authors study the existence of mild solutions to a functional differential equation with delay and random effects. They use a random fixed point theorem with a stochastic domain. An example is included to illustrate their results.     

中温热解焦油重馏分悬浮床加氢裂化的研究

以中温热解煤焦油为原料,对其性质进行了分析,其中,350℃重质馏分中胶质含量30.88%,沥青质含量37.27%,四氢呋喃不溶物3.36%,属于常规固定床加氢裂化难以直接处理的馏分。合成了一种Mo系超分散催化剂,采用FT-IR、XPS、XRD、SEM和TEM等对催化剂进行了表征,催化剂中含有Mo=O和Mo-S特征结构,活性金属的硫化率为84.34%,在体系中具有优良的分散性,在反应体系内原位分解为超分散MoS_2颗粒;在0.25 t/d连续装置上进行了热解重油悬浮床加氢裂化实验研究,考察了反应条件对产物分布情况和结焦率的影响,得出适宜的反应条件为19 MPa,440℃,催化剂的添加量为300 mg/kg;此条件下石脑油收率24.47%,柴油馏分收率49.71%,结焦率1.32%。     

Effect of Gaussian size distribution width on minimum fluidization velocity in tapered gas–solid fluidized beds

This paper investigated the effect of Gaussian distribution width, average particle diameter, particle loading, and the tapered angle on minimum fluidization velocity (U_mf) by conducting extensive experiments in tapered fluidized beds. Three powders with Gaussian size distribution and different distribution widths were used in the experiments. An increase in U_mf with increasing the average particle diameter, particle loading, and the tapered angle was observed. There was also a nonmonotonic behavior of U_mf as the Gaussian distribution width increased. An empirical correlation including dimensionless groups for predicting U_mf in tapered beds was developed in which the effect of distribution width was considered. The proposed correlation predictions were in good agreement with the experimental data, with a maximum deviation of 16.5% and average and standard deviations of, respectively, 6.4% and 7.4%. The proposed correlation was also compared with three earlier models, and their accuracy was discussed.     

Experimental investigation on the distribution uniformity and pressure drop of perforated plate distributors for the innovative spray-type packed bed thermal storage

As an innovative thermal energy technology, the spray-type packed bed has advantages of high efficiency and low cost. A liquid distributor is the key component for the spray-type packed bed for scattering heat-transfer liquid drops evenly. In this study, the distribution performance and pressure drop of the perforated plate distributors of different orifice diameters were studied experimentally. The experimental results indicate that orifice diameter has a greater effect on the distribution performance compared to flow rate. With an increase in flow rate, the flow pattern through the distributor changes from the uncovered drop to the covered drop and then to the jet flow. The covered drop pattern shows the best performance with a good distribution and a small pressure drop simultaneously, which is the design and optimization principle of the distributor for a spray-type packed bed.     

Numerical investigation on cold flow dynamics of supercritical water fluidized bed reactor with inclined distributor: Design and scale up

Supercritical water fluidized bed reactor (SCWFBR) is a novel concept for the gasification of coal and biomass to produce hydrogen. In this work, to enhance the mixing in the axial direction, an inclined distributor is introduced to optimize the flow dynamics in SCWFBR with partitioned fluid supply. Through numerical simulations based on the two fluid model (TFM), the effects of the inclined distributor structure and operating parameters on the solid distribution and the residence time are evaluated with the optimal values determined. Numerical results show that, area ratio = 2:1, SCW velocity ratio = 3:1, flow ratio = 3.36:1 and inclination angle = 20° are the optimal design in this paper. A predictive correlation of the minimum fluidization velocity for the improved SCWFBR is also proposed based on the numerical data. The average error between the correlation and numerical simulation results is approximately 1.4% which strongly demonstrates its capability. Finally, based on the optimal design, the lab-scale reactor is further scaled up and the studies about two scale-up rules are carried out. Only the cold flow is simulated in this study without considering chemical reaction which would be involved in future work.