外加剂与硫铝酸盐水泥相容性研究

研究了萘系、氨基磺酸盐系和聚羧酸系高效减水剂与硫铝酸盐水泥的相容性问题。利用缓凝剂有效控制了硫铝酸盐水泥的凝结时间；利用浆体稳定剂成功解决了水泥净浆的板结、泌水问题；从浆体流变学角度研究了外加剂-硫铝酸盐水泥浆体体系稳定性。实验证明：3种外加剂与硫铝酸盐水泥都具备了良好的相容性，据此提出了解决外加剂与硫铝酸盐水泥相容性问题的一些方法，为硫铝酸盐水泥的应用提供一些可靠的理论依据。     

关于数字系统设计的研究

阐述了VHDL硬件描述语言与电路设计的关系及设计过程，在此基础上对数字系统设计方法进行了分析与比较。     

层状土中桩体复合地基荷载沉降关系

在假定桩侧摩阻力与该点位移符合纯弹塑模型的基础上，对层状土中桩体复合地基的工程特性进行了研究，分析了桩和桩间土的变形特点。最后，利用复合地基的变形协调条件，推导了层状土中桩体复合地基的荷载一沉降关系及桩土应力比公式，并结合工程实际对其精度进行了验证，表明荷载一沉降的理论关系式具有满足工程实际要求的精度。     

HLZDB-3K型防跑车装置在马兰矿的应用

阐述了HLZDB--3K型防跑车装置的组成功能、工作原理及技术指标，指出HLZDB--3K型防跑车装置能有效地对斜井运输中的失控跑车进行完整的监测、控制、捕捉和制动，工作性能可靠，使用效果较好，给斜巷运输提供了一个安全的工作环境。     

相容关系与相容核

给定论域上的相容关系,本文提出了相容核的概念。较之于相容关系的最大相容类,相容核是一个局部化的相容类。我们还讨论了有关相容核的若干数学性质,并且给出了相容关系与其相应的相容核族之间相互唯一确定的充分必要条件。     

研究生培养方案若干问题的探讨

随着经济的发展，社会对研究生的层次和要求越来越高，如何制定科学、合理、先进的培养方案，培养出适应社会需求的研究生，是教师及管理人员应该深入研究的课题。本文分析了现有研究生培养方案要中存在的问题及局限性，并对其进行了系统研究，提出了制定研究生培养方案应该从适应性、多样化、系统性、先进性和特色性等方面来考虑，以便制定出符合最新质量标准的培养方案。     

A comprehensive review on surface modification,structure interface and bonding mechanism of plant cellulose fiber reinforced polymer based composites

Abstract

Plant cellulose fiber polymer composites are readily applied in wide range of applications due to ecological and economical alternative to traditional materials. The considerable amount of residues and organic wastes from agricultural process are still employed as lower energy resource. Organic materials are generally disposed in composting, landfilling or anaerobic digestion. The utilization of these wastes in plant fiber composites shows significant alternative and environmental friendly in nature. The production of plant cellulose fiber composite with higher structural properties is optimized by interfacial bonding between polymer and reinforced fiber. The interface plays a vital role in regulating mechanical properties by distributing bonds and stress transferring, which is one of least understood element of composites. This paper presents the comprehensive review of fiber structures, different modification techniques to reduce the incompatibility between matrix and fiber, assessment of structure interface and bonding, clarifies the interfacial adhesion of cellulose fiber composites.     

Search for a Steric Penultimate Effect: Copolymerization of 2,3,4-Trimethyl-3-pentyl Methacrylate with Styrene

The hindered monomer, 2,3,4-trimethyl-3-pentyl methacrylate (I), was synthesized for penultimate effect studies. Since it readily homopoiymerized (km¹¹¹≠ 0) and readily copolymerized with styrene, copolymerizations of I with styrene were carried out at 60°C in benzene with AIBN as initiator. The conversion to copolymer and the copolymer composition were determined by using GLC techniques. Composition-conversion data was analyzed by performing a computerized nonlinear least-squares fitting to the integrated form of the penultimate model equation. The experimental design included the use of optimized M¹°/M²° ratios. The penultimate reactivity ratios calculated from these data were r¹′ = 0.23, r¹′= 0.59, r² = 0.59, r²′ = 1.34. Thus, when I is the penultimate unit, a terminal styryl radical prefers to add styrene, whereas when styrene is the penultimate unit, terminal styryl radicals prefer to add I. These results constitute the best evidence for a steric penultimate effect yet available in the literature from composition-conversion studies. However, the case is not yet proved. Further studies to strengthen this conclusion are proposed.     

Selection of hydrogel electrolytes for flexible zinc–air batteries

Flexible zinc–air batteries attract more attention due to their high energy density, safety, environmental protection, and low cost. However, the traditional aqueous electrolyte has the disadvantages of leakage and water evaporation, which cannot meet application demand of flexible zinc–air batteries. Hydrogels possessing good conductivity and mechanical properties become a candidate as the electrolytes of flexible zinc–air batteries. In this work, advances in aspects of conductivity, mechanical toughness, environmental adaptability, and interfacial compatibility of hydrogel electrolytes for flexible zinc–air batteries are investigated. First, the additives to improve conductivity of hydrogel electrolytes are summarized. Second, the measures to enhance the mechanical properties of hydrogels are taken by way of structure optimization and composition modification. Third, the environmental adaptability of hydrogel electrolytes is listed in terms of temperature, humidity, and air composition. Fourth, the compatibility of electrolyte–electrode interface is discussed from physical properties of hydrogels. Finally, the prospect for development and application of hydrogels is put forward.