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991.
In this paper, we prove that a Cayley digraph Γ = Cay(G, S) is a nontrivial lexicographical product if and only if there is a nontrivial subgroup H of G such that S∖H is a union of some double cosets of H in G.
相似文献
992.
The optical symmetry of many crystals is lower than would be expected from their external form and X-ray diffraction data. Recently such optical anomalies have been attributed to nonequilibrium structures resulting from kinetically controlled crystal growth. Impurities are incorporated to different extents at various surface sites that would otherwise have become symmetry-related within the bulk crystal. After their discovery by Brewster in 1815, optically anomalous crystals were the subject of lively debate throughout the 19th century among some of the most distinguished contributors to the development of crystallography including Biot, Berzelius, Herschel, Mitscherlich, Frankenheim, Pasteur, Mallard, Klein, Groth, Wyrouboff, Barlow, Brauns, Rinne, Pockels, and Friedel. From a sea of wild speculation two conflicting postulates emerged: that the symmetric form resulted from accidental twinning of segments with lower symmetry, or that the optical peculiarities resulted from stress due to impurities or external perturbations. Neither postulate expresses the present view. Interest in this research waned at the turn of the century, and after 1917 no one pursued Tammann's alternative correct insight. The problem of anomalous double refraction attracted no attention for more than half a century until its recent solution. This review discusses both mineral and organic systems with particular emphasis on the phyllosilicate apophyllite and on 1,5-dichloro-2,3-dinitrobenzene. These nonequilibrium structures relate to questions of crystal order, crystal growth, molecular recognition, and the design of new materials. The review provides a reminder of the enduring value of the polarizing microscope as a research tool in chemistry. 相似文献
993.
Powder samples of the ternary phosphates A3Lu(PO4)2:Yb3+ (A = Na, Rb) have been synthesised by solid state reactions. The spectroscopic properties of Yb3+ in double phosphate host lattices were investigated using absorption, emission and excitation spectra at 4, 10 and 293 K in the VUV to IR range. The results obtained for both types of phosphates are compared. Together with the fundamental 2F5/2 → 2F7/2 emission in the IR range, a broad band emission with two peaks in the UV region were observed in Yb3+‐activated Na3Lu(PO4)2. The second emission is due to a charge–transfer transition type. The influence of the alkali metal cation site of the host lattice on the luminescence properties was investigated. The tentative energy level scheme of the ground and excited 2FJ (J=7/2, 5/2) levels is described. 相似文献
994.
目的:用廉价物代替抗IgG血清,既能开出有关实验,又减少了实验开支。方法:用硫酸铝钾和碳酸氢钠做琼脂双向扩散、单向扩散以及对流电泳。结果:三项实验分别出现清晰的沉淀线、沉淀环。采用该模拟方法的廉价试剂,可经济、逼真地开出三项凝胶内沉淀反应。 相似文献
995.
康寿万 《北京交通大学学报(自然科学版)》1989,(3)
本文研究了光纤的损耗时双孤子的间隔r的影响。本文导出了r随t变化的公式,通过数值计算表明,当r<10w时,w为孤子的半宽度,损耗对r的变化有明显的影响。 相似文献
996.
997.
Shui Feng ZHANG Li Shi WANG Zhi DANG 《中国化学快报》2006,17(9):1229-1232
This paper reported a compact system of capacitively coupled contactless conductivity detection (C4D) based on the square wave excitation voltage for capillary electrophoresis, and it exhibited excellent sensitivity at the optimal frequency of 198 kHz. The feasibility and sensitivity of this detector was demonstrated by simultaneous detection of thirteen ions including alkali, alkaline earth and heavy metal ions. And the detection limits (S/N 3) were in the range of 0.2-1μmol/L for Mn^2+, K^+, Na^+, Mg^2+, Ca^2+, Li^+, Ba^2+, and 7-25 μmol/L for Ni^2+, Cu^2+, Cd^2+, Pb^2+, Co^2+, Zn^2+. 相似文献
998.
二羰基环戊二烯基(三环己基锡基)铁的晶体结构 总被引:1,自引:0,他引:1
关于(三烃基锡基)二数基环戊二烯基铁类配合物的合成反应已进行了许多研究D',并发现某些这类配合物具有一定的催化聚合作用或抗肿瘤活性['·'j.这类配合物中已见报道晶体结构的只有烃基为三苯基作配体时的配合物CP(CO)。FesnPh。D',为了便于比较及研究结构和性能的关系,我们以三环已基为锡的配体,以与文献['j中近似的方法合成了配合物CP(CO)。Fesfl(C6HI人,并进行了IR、NMR的测定.X光四圆衍射仪对所得单晶的结构测定结果表明,该配合物具有与CP(CO)。F。SnPh。相近的晶体结构.1标题配合物的制备与谱学表征1… 相似文献
999.
1000.
李国富 《宁波大学学报(理工版)》1994,(1)
本文利用FORTRAN语言中不同类型变量的性质及数运算的特点,讨论了一种能将双精度实数运算扩展到整数运算中的方法,使整数运算也能得到接近双精度实数所具有的有效位数的整型结果。 相似文献