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91.
Masahiro Toyoda Yukio Hamaji Kunisaburo Tomono 《Journal of Sol-Gel Science and Technology》1997,9(1):71-84
The sol-gel processing was applied to the fabrication of PbTiO3 fibers. Pb(CH3COO)2·3H2O and Ti(OC3H
7
i
)4 were refluxed with stirring in 2-methoxyethanol to form Pb-methoxyethoxide and Ti-methoxyethoxide, respectively, followed
by mixing with stirring in 2-methoxyethanol to form Pb−Ti double alkoxide. The hydrolysis and polycondensation reaction of
this double alkoxide gave polymerized products, and as a result the viscosity of the solution increased, suggesting that linear
polymers were produced through the hydrolysis and polycondensation reaction. Homogeneous PbTiO3 gel fibers were drawn from the spinnable viscous solutions, which were wellcrystallized into perovskite type PbTiO3 at 650°C. The heat-treated fibers were a few centimeters long and from 10 to 100 μm in diameter. The fiber was made up of
extremely uniform grains. Electron diffraction revealed a preferred growth of (101) planes along the fiber axis, which might
be due to the linear molecular characteristics of the alkoxide. 相似文献
92.
K. Rossmanith 《Monatshefte für Chemie / Chemical Monthly》1995,126(5):543-547
Summary The Separation Factors for Pr/La, Nd/Pr, and Sm/Nd, characterizing the crystallization of ammonium and magnesium double nitrates under practical conditions, were determined analytically and are discussed. They confirm that La and Pr can be separated better by fractional crystallization of ammonium double nitrates, whereas in the presence of Sm the magnesium double nitrates are preferable. 相似文献
93.
For most oxide/electrolyte systems potentiometric titration curves measured for different ionic strengths have a Common Intersection Point (CIP) which corresponds to the Point of Zero Charge (PZC). However, there are systems where a CIP exists but the surface charge at this point does not equal zero (PZC CIP). In this paper theoretical analysis of the systems in which the PZC and CIP do not coincide is presented. It is based on the well-known 2-pK surface charging approach and Triple Layer Model (TLM) as well as the Four Layer Model (FLM) of the electric double layer. The appropriate mathematical criterion for CIP existence was applied with detailed derivations, both for TLM and FLM. Having determined in this manner the parameter values, one can draw proper conclusions about the features of oxide/electrolyte adsorption systems, in which PZC and CIP do not coincide. The values of adsorption parameters are found by fitting simultaneously the obtained theoretical expressions to both of the experimental titration isotherms, and to the individual isotherms of electrolyte cation adsorption measured using radiometric methods. 相似文献
94.
The melting process of constrained nylon 6 fibers has been studied to estimate the true melting point of its original crystals.
The melting peak became simpler in shape and shifted to higher temperature with increasing fiber-axis restricting force. When
heating rate, β, was increased, the temperature where the melting curve initially departs from its baseline, Tsm, decreased
steeply in the range of 45 to 60°C min-1, and increased linearly with increasing β above 60°C min-1. By linear extrapolation of Tsm to 0°C min-1, the temperature of ca 190°C was obtained for the melting temperature of the original nylon 6 crystals. This seems to correspond
to the zero-entropy-production melting of the most imperfect crystallites of the nylon 6 fabric.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
95.
A differential microcalorimetric study of whey proteins and their behaviour in oil-in-water emulsions 总被引:1,自引:0,他引:1
Oil-in-water emulsions (20% soya oil, 1% protein) have been prepared containing lysozyme or isolates of -lactalbumin and β-lactoglobulin from whey protein. The structural characteristics of these proteins adsorbed at an oil/water interface were determined by following their thermal transitions using differential scanning microcalorimetry. Thermograms of the proteins in the adsorbed state differed markedly from the corresponding transitions seen for the proteins in solution. This suggests that the proteins underwent substantial changes in secondary and tertiary structure upon adsorption. In general, for all the proteins studied, a net decrease in the total energy absorbed during denaturation was found when the proteins were in an adsorbed state. Both lysozyme and -lactalbumin were in part “surface denatured”, and they showed a certain degree of reversibility between solution and the adsorbed state. β-Lactoglobulin showed the highest degree of denaturation upon adsorption and the conformational change was irreversible. 相似文献
96.
刘国华 《辽宁工程技术大学学报(自然科学版)》1991,(1)
本文首先对《微积分解题方法与技巧》一书中某题的解法提出质疑;然后研究了三种不同情形下可以得出不同的结果;进而否定了该书的解法;最后指出,被高等数学广泛采用的“极坐标代换法”不能直接用于二重极限,并给出了理论上的解释和证明。 相似文献
97.
V. R. Kartashov T. N. Sokolova A. Yu. Pavinskii I. V. Timofeev A. B. Radbil' 《Russian Chemical Bulletin》1995,44(12):2375-2381
The kinetics of azidomercuration of alkenes, cycioalkenes, and their derivatives with a Hg(OAc)2-NaN3 system (1 1, 1 2, and 1 3) was studied. Based on the data on the product structure and kinetic results, it was concluded that HgOAcN3 and Hg(N3)2 play the role of azidomercuration reagents. The reactions with alkenes having a strained double bond occur by a concerted scheme. With nonstrained alkenes, a multistep mechanism is realized, its first reversible step involving the formation of a mercurinium intermediate with an ion pair structure.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No.12, pp. 2479–2485, December, 1995. 相似文献
98.
99.
王鲁 《北京理工大学学报》1998,18(4):401-405
研究金属-陶瓷功能梯主材料的基体与颗粒的界面热应力。方法给出功能制备的有限元计算优化设计方案,针对所制备的梯度材料的结构特点,采用双层嵌套模型研究基体与颗粒的界面热应力与两相材料体积分数的变化关系。 相似文献
100.
影响油气运移的应力场地温场渗流场耦合的双重介质模型 总被引:4,自引:0,他引:4
地应力场、地温场和渗流场是影响油气运移的主要因素。以此为基础,研究了含油气盆地双重介质体系内流体与岩体相互的力学作用关系,提出了双重介质体系内渗流场、岩体地应力场和地温场耦合的非线性动力学模型。 相似文献