锌掺杂二氧化钛对含酚废水的降解作用的研究

以钛酸四丁酯为主要原料,氯化锌溶液为掺杂剂,采用超声分散法制备了含锌的二氧化钛光催化剂.并采用X射线衍射(XRD),透射电镜(TEM)对产品进行了表征.同时研究了不同影响因素对苯酚去除率的影响.结果表明,焙烧温度为500℃,锌掺杂量r(Zn∶Ti)=0.01,催化剂的最佳投加量为2 g/L光催化性最好.     

Fabrication of Tiron Doped Poly-Pyrrole/Carbon Nanotubes on Low Resistance Monolayer-Modified Glassy Carbon Electrode for Selective Determination of Dopamine

In this paper, we described a novel sensor based on tiron-doped polypyrrole and carbon nanotubes (CNTs) fabricated on low resistance monolayer-modified glassy carbon electrode. First, the dodecylamine monolayer was chemically modified. Second, CNTs were controllably adsorbed onto dodecylamine. Then, tiron doped polypyrrole was electro-deposited on the CNTs film. The layer-by-layer modified electrode was sensitive to dopamine, while it made no response to even high concentration of ascorbic acid. Parameters influencing the dopamine response were optimized. High performance of the sensor was obtained, such as wide concentration range, low detection limit (3 nM), low background current, high stability, and reproducibility.     

Li‐doped nanosized TiO2 powder with enhanced photocalatylic acivity under sunlight irradiation

This work reports on the synthesis of Li‐doped TiO₂ nanoparticles using the sol–gel process and solid‐state sintering, and investigates their potential use as a photocatalyst for degradation under sunlight excitation of different organic model compounds in aqueous solution. The structure of the nanocrystals was examined by X‐ray diffraction, UV‐vis ground state diffuse reflectance absorption spectra and X‐ray photoelectron emission spectroscopy. Results showed that samples prepared by sol–gel process and calcined at 400 °C are composed of a mixture of anatase and rutile phases, in contrast to the one prepared by solid‐state sintering, which exhibits an anatase phase with Li being involved in a spinel phase. The photocatalytic degradation of aqueous solutions of different aromatic compounds was successfully achieved under sunlight excitation in presence of Li‐doped TiO₂ prepared via sol–gel process. It was shown that the calcination temperature and the preparation mode greatly affect the photocatalytic efficiency. Copyright © 2010 John Wiley & Sons, Ltd.     

Er3+-doped phosphor-tellurite glass for broadband short-length Er3+-doped fiber amplifier

ErS+-doped phosphor-tellurite glass for broadband short-length Er3+-doped fiber amplifier (EDFA) is fabricated and characterized. The differential value (△T) of onset crystalline temperature (Tx) and glass transition temperature (Ts) is 206°C.     

掺杂稀土元素对改善氧化铝热稳定性机理的探讨

从阻抑氧化铝的相变、表面化合物的生成和延缓氧化铝的烧结三个方面探讨了氧化铝掺杂镧后改善热稳定性的机理。     

Theoretical study of the polarized electronic absorption spectra of vanadium-doped zircon

The polarized electronic absorption spectra of a blue vanadium-doped zircon single crystal, grown by the flux method, has been studied by quantum chemical (CI) calculations in order to determine the position of the V⁴⁺ dopant in the zircon host structure. Particularly, the excitation energies and polarizations of V⁴⁺ occupying alternate positions, either the zirconium or silicon position or the interstitial site 16g, have been considered. It is concluded that the observed electronic absorption spectra and the color of zirconblue can only be explained if the V⁴⁺ chromophore is placed on the respective interstitial position.     

一种掺钕光纤激光器与倍频技术实现的数值模拟

从双包层光纤激光器的速率方程和光传输方程出发，建立数学模型，进行数值计算并对掺钕光纤激光器输出功率沿光纤的分布以及不同光纤长度下抽运功率和输出功率沿光纤的分布进行了数值模拟。以808nm半导体激光器为抽运源，掺钕双包层光纤为增益介质，并以KTP作为倍频晶体，计算并模拟其倍频效率和相位匹配角。最后，对光纤激光器及其倍频的实现进行了模拟研究。结果表明，该光纤激光器能够高效率地实现可见光输出。     

掺杂钨丝中钾泡形成的动力学研究

本文利用透射和扫描电镜研究了掺杂钨丝退火时钾泡形成的机理和动力学,探讨了用微扰动理论处理钾泡形成过程的可能性。结果表明,冷拨掺杂钨丝中钾管分裂的必要条件是钾管长宽比≥9,在考虑钾泡形成热力学条件后,可导出几个有意义的钾泡分布参数,并发现对于同一丝径的掺杂钨丝,在同一温度退火,形成粗细不同的钾管,比较细的钾管分裂受表面扩散所控制,反之则主要受外部体扩散所控制,与实验结果相符。     

Asymptotics of the Interband Light Absorption Coefficient near the Band Edge for an Alloy-Type Model

We find the asymptotics of the interband light absorption coefficient of an alloy-type model in the case when the ground-state energies of the electron and the hole Hamiltonians are finite.     

Optical Characterization of Eu3+ Ions in CdSe Nanocrystal Containing Silica Glass

Silica glass samples containing CdSe/Eu3+ ions were prepared by sol-gel route. Size distribution and optical band gap of the nanoparticles were calculated from absorption spectrum. It is observed that the presence of CdSe nanocrystallites enhances the fluorescence of europium in silica glass. The phonon sideband spectrum associated with the excitation transition 7F0-5D2 is used to analyze the electron-phonon coupling and nonradiative deexcitiation of the rare earth ions in the glass host, The observed fluorescence enhancement is discussed on the basis of phonon assisted energy transfer from electron-hole recombination of the CdSe nanocrystallites to the rare earth ion and multiphonon relaxation.