全文获取类型
收费全文 | 27071篇 |
免费 | 3511篇 |
国内免费 | 2299篇 |
专业分类
化学 | 14364篇 |
晶体学 | 533篇 |
力学 | 857篇 |
综合类 | 171篇 |
数学 | 660篇 |
物理学 | 9701篇 |
综合类 | 6595篇 |
出版年
2024年 | 52篇 |
2023年 | 173篇 |
2022年 | 470篇 |
2021年 | 499篇 |
2020年 | 645篇 |
2019年 | 663篇 |
2018年 | 668篇 |
2017年 | 840篇 |
2016年 | 1068篇 |
2015年 | 1027篇 |
2014年 | 1158篇 |
2013年 | 2409篇 |
2012年 | 1515篇 |
2011年 | 1545篇 |
2010年 | 1273篇 |
2009年 | 1356篇 |
2008年 | 1432篇 |
2007年 | 1537篇 |
2006年 | 1438篇 |
2005年 | 1334篇 |
2004年 | 1276篇 |
2003年 | 1157篇 |
2002年 | 1298篇 |
2001年 | 941篇 |
2000年 | 959篇 |
1999年 | 847篇 |
1998年 | 709篇 |
1997年 | 601篇 |
1996年 | 542篇 |
1995年 | 548篇 |
1994年 | 460篇 |
1993年 | 377篇 |
1992年 | 374篇 |
1991年 | 303篇 |
1990年 | 242篇 |
1989年 | 207篇 |
1988年 | 208篇 |
1987年 | 154篇 |
1986年 | 135篇 |
1985年 | 99篇 |
1984年 | 83篇 |
1983年 | 37篇 |
1982年 | 55篇 |
1981年 | 29篇 |
1980年 | 31篇 |
1979年 | 37篇 |
1978年 | 13篇 |
1977年 | 10篇 |
1976年 | 7篇 |
1973年 | 17篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
钟凡 《中山大学学报(自然科学版)》1996,(2)
把重正化群理论应用于一受外场驱动而发生一级相变的系统中,结果表明,与有序化过程一样,该系统也由零温不动点所决定,并得到磁化强度及结构函数的新的动力学标度关系.由此可获得滞后回约面积与变场速率的标度关系. 相似文献
22.
Poly (n-butylisocyanate)-benzene solutions prepared by solubilization at 45°C, followed by aging at room temperature were found to be metastable for months, although, eventually, they separated into a birefringent polymer-rich phase and an isotropic solution. These metastable solutions, as well as isothermally phase-separated biphasic samples, flowed and exhibited dynamic moduli indicative of low polymer connectivity. By contrast samples prepared by a freeze-thaw cycle were uniformly and highly birefringent and showed network (gel) behavior at room temperature. The mechanism of gel formation is most likely the exclusion of the polymer from the benzene crystal during crystallization, forcing the polymer to align and exist at grain boundaries. Films formed from solutions have different moduli than those formed from gels, and are consistent with the proposed mechanism. 相似文献
23.
Timur Zharnikov Alexander Yakovlev Semion Kuchanov 《Journal of Polymer Science.Polymer Physics》2003,41(9):892-902
The problem of finding conditions of the loss of thermodynamic stability by the reaction system was solved on the basis of the developed theory of living free‐radical copolymerization. The spinodal's calculations were carried out for a significant number of systems differing in the values of kinetic, stoichiometric, and thermodynamic parameters. Analysis of the results of such calculations revealed some regularities in the spinodal curves' behavior and permitted us to classify their possible topological types. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 892–902, 2003 相似文献
24.
Small‐Angle Neutron Scattering has been performed from poly(ethylene oxide) in deuterated water at temperature ranging from 10 to 80 °C. A simple fitting model was used to obtain a correlation length and a Porod exponent. The correlation length L characterizes the average distance between entanglements in the semidilute region and is proportional to the individual coil sizes in the dilute region. L was found to increase with temperature in the semidilute region but it decreases with temperature in the dilute region. This decrease is the precursor to the single‐chain collapse which applies to very dilute polymer solutions. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2196–2200, 2007 相似文献
25.
This work reports a new synthetic approach for single‐phase TiO2 nanomaterials by solvothermal treatment of titanium tetrachloride in acetone at 80–110 °C. Small, uniform, and yet size‐tunable (5–10 nm) anatase titania nanocrystallites were obtained using a low concentration of TiCl4 in acetone (i.e., at molar ratios of TiCl4/acetone ≤ 1:15) in the temperature range of 80–110 °C, while rutile nanofibers were synthesized using a high concentration of TiCl4 (e.g., TiCl4/acetone = 1:10) at 110 °C. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
26.
27.
对经过分级的六种均齐粉粒状物料进行透气性系数测定。结果表明:球形小米颗粒((?)_p=1.70mm),透气性系数K=1.191×10~(-9)m~2,在整个固定床范围内都符合达西定律;石灰石粉((?)_P=0.900mm),K=5.831×10~(-10)m~2。文中还讨论了达西定律的适用依据和透气性系数的影响因素。 相似文献
28.
Masuhiro Tsukada Giuliano Freddi Nobutami Kasai 《Journal of Polymer Science.Polymer Physics》1994,32(7):1175-1182
The physical structure and compatibility of solution-cast Antheraea pernyi/Bombyx mori silk fibroin blend films were stuided by differential scanning calorimetry (DSC), thermomechanical (TMA) and thermogravimetric (TGA) analysis, dynamic viscoelastic measurement, infrared spectroscopy, and x-ray diffractometry. The DSC curves of the blend films showed independent endotherms at 280 and 358°C, corresponding to the thermal decomposition of B. mori and A. pernyi silk fibroins with random coil conformation. The intensity was roughly proportionate to the amount of each component in the blend. The thermal behavior corresponding to the conformational transitions induced by heating on A. pernyi and B. mori silk fibroins overlapped in the temperature range 190–230°C. Thermal expansion and contraction properties, as well as weight retention behavior of the blend films were intermediate between the pure components, as shown by the TMA and TGA curves. The onset temperature of the storage modulus curve decreased markedly, approaching that of B. mori silk fibroin film when the amount of this component in the blend increased. The loss modulus curve of the blend films showed two peaks at ca. 190 and 210°C, the former corresponding to B. mori, and the latter to A. pernyi silk fibroin. Infrared spectra of the blends exhibited absorption bands characteristic of the pure components overlapping in the spectral region 2000–400 cm?1. The x-ray diffraction peaks at 23 and 21.5°, attributed to the crystalline spacings of A. pernyi and B. mori fibroins, respectively, overlapped in the diffraction curves of the blends, while the peak at 11.4°, of A. pernyi, increased as the content of this fibroin in the blend increased. The degree of crystallinity, calculated from the x-ray diffraction curves, diminished as the amount of B. mori silk fibroin decreased. A low degree of compatibility exists between the two fibroins when they are cast from aqueous solution in the experimental conditions adopted in this work. © 1994 John Wiley & Sons, Inc. 相似文献
29.
对用GDX-102-硅胶G、有机粘合剂研制出的混合薄层板进行性能测试,评价了其在硝基苯胺异构体、酸性食品染料分离测试方面的应用,得到好的结果。 相似文献
30.
XI Zengzhe LI Zhenrong XU Zhuo ZHANG Liangying & YAO Xi . Functional Materials Research Laboratory Tongji University Shanghai China . Key Laboratory of the Ministry of Education Xi抋n Jiaotong University Xi抋n China 《科学通报(英文版)》2003,48(19):2038-2040
It has been reported that the single crystal of relaxor ferroelectrics (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-xPT) with the compositions near the morphotropic phase boundary (MPB, 0.28相似文献