Etching and dielectric studies on L‐lysine monohydrochloride dihydrate single crystal

The nonlinear optical single crystals of L‐Lysine monohydrochloride dihydrate (L‐LMHCl) have been grown and examined by High‐resolution X‐ray diffraction and etching studies for their perfection. The vibrational frequencies have been identified by the micro‐Raman studies and the dielectric behaviour has been studied and the results are presented in detail. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Ab initio Calculations of Curie Temperatures in GdM Compounds

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.     

Preparation of the Ultra‐Low Dielectric Constant Polyimide Fiber Membranes Enabled by Electrospinning

In this article, electrospinning technique has been demonstrated for the synthesis of ultra‐low dielectric constant polyimide fiber membranes. Poly(amic acid) fiber membranes have been prepared as precursor. After the treatment of thermal imidization, ultra‐low dielectric constant polyimide fibers membranes can be obtained. The morphologies and structures of precursors and products are characterized by scanning electron microscopy (SEM), Fourier transmission infrared (FTIR) spectra, and a radio frequency (RF) impedance/capacitance material analyzer. The DK of the as‐prepared polyimide membrane ranges from 1.53 to 1.56, which could be applied in the electronic packaging industry.

     

Controlling optical responses through local dielectric resonance in nanometre metallic clusters

Optical responses in dilute composites are controlled through the local dielectric resonance of metallic clusters. We consider two located metallic clusters close to each other with admittances \varepsilon₁ and \varepsilon₂. Through varying the difference admittance ratio \eta [ = (\varepsilon₂- \varepsilon ₀) / (\varepsilon₁- \varepsilon₀)], we find that their optical responses are determined by the local resonance. There is a blueshift of absorption peaks with the increase of \eta. Simultaneously, it is known that the absorption peaks will be redshifted by enlarging the cluster size. By adjusting the nano-metallic cluster geometry, size and admittances, we can control the positions and intensities of absorption peaks effectively. We have also deduced the effective linear optical responses of three-component composites \varepsilon_e= \varepsilon₀ \bigl(1 + \sum_n=1^{n_s} [(\gamma_n2+ \eta \gamma_n2)/({\varepsilon₀(s - s_n))]} \bigr), and the sum rule of cross sections: \sum_n=1^{n_s} {(\gamma_n2+ \eta \gamma_n2 ) = N_h1+ N_h2, where N_h1and N_h2 are the numbers of \varepsilon₁ and \varepsilon₂ bonds along the electric field, respectively. These results may be beneficial to the study of surface plasmon resonances on a nanometre scale.     

Effect of electrohydrodynamic interaction on the stability of a flat plate laminar boundary layer

The stability of a unipolarly charged electrohydrodynamic boundary layer on a flat dielectric plate along which an electric current flows between electrodes located on the plate is investigated within the framework of the linear theory. The solution of the steady-state problem is obtained on the basis of methods developed earlier for conditions typical of aerodynamical experiments and various electric currents and electrode voltages. The effect of the interaction between perturbations of the electric and hydrodynamic flow parameters on the flow stability is estimated within the framework of the locally homogeneous approximation. This effect turns out to be insignificant under the conditions considered. It is shown that steady-state electrohydrodynamic action on the main flow makes it possible to obtain “accelerating” velocity profiles with increased absolute values of the second derivative in the transverse direction. This ensures a significant increase in the critical Reynolds numbers of loss of stability and a narrowing of the growing perturbation wavenumber range.     

Model of explosive pulsed vaporization of dielectric liquids by intense laser irradiation of their surfaces

The mechanism of explosive vaporization interaction of laser radiation with matter is studied theoretically. It is shown that, in dielectric liquids with a free surface, periodic explosive boiling is possible if the laser radiation intensity exceeds the rate of heat transfer from the region of laser radiation absorption. Analytical expressions are obtained to estimate the pulsating boiling period and the thickness of the surface liquid layer dispersed by fluctuation vapor bubbles during each boiling. The degree of absorption of laser radiation by the aerosol formed above the liquid surface is estimated. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 49, No. 6, pp. 17–24, November–December, 2008.     

按增益体积缩放全金属环状波导CO2激光器研究

介绍全金属环状波导CO2激光器,并提出了器件的设计思路,运用电磁场理论详细分析了环状波导管内电磁场各分量方程、模式特征及其强度分布,对波导谐振腔的耦合损失也进行了简要的分析。     

含氟聚酰亚胺1,3-BPA-6FDA-DR1的合成及其热光性能

用1,3-双(3-氨基苯氧基)苯(1,3-BPA)、4,4′-(六氟异丙基)-苯二酸酐(6FDA)和分散红1(DR1)合成了含氟聚酰亚胺,采用示差扫描量热(DSC)、热失重分析(TGA)和紫外、红外吸收光谱等测试技术对该聚酰亚胺的热稳定性和结构进行了表征。结果显示,该聚酰亚胺的玻璃化转变温度(Tg)和在5%的质量损失温度分别为238和287℃,表明具有较好的热稳定性。不同浓度的材料在自然光下的热光系数(dn/dT)值为(-2.31～-3.04)×10-4/℃,体积热膨胀系数变化率(dβ/dT)为(2.56～4.32)×10-7/℃;一定浓度的材料在436nm单波长光照射下的热光系数(dn/dT)值为-3.08×10-4/℃,体热膨胀系数变化率(dβ/dT)为4.72×10-7/℃,表明该聚合物在低驱动功率的新型数字热光开关、光通信器件等领域具有潜在的应用前景。     

超低频介电谱测量

研制了频率可低至10-6Hz的复介电谱测量设备.在30℃和60℃测量了3.3×10-4～104Hz范围的(BaxSr1-x)TiO3陶瓷的复介电常数.实验证明,在稳态电路中正弦电压引起的慢介电效应提供的电流仍可以是正弦的.     

镧掺杂对PMN—PT陶瓷结构与性能的影响

采用熔盐法制备了0．82MN－0．28PT－xLa陶瓷,研究了掺镧离子对0．82PMN－0．18PT陶瓷相结构、显微结构以及介电性能的影响。结果表明,随着掺镧含量的增加,不仅预烧粉体和陶瓷的焦绿石相含量逐渐增加,而且在显微结构中逐渐出现了小颗粒,气孔增多,陶瓷的致性逐渐下降,严重恶化了介电性能,导致介电常数急剧下降,但蛤电温度稳定性却大幅度提高。