The survival probability of a particle which moves according to a biased random walk in a one-dimensional lattice containing randomly distributed deep traps is studied at large times. Exact asymptotic expansions are deduced for fields exceeding a certain threshold, using the method of images. In order to cover the whole range of fields, we also derive the behavior of the survival probability below this threshold, using the eigenvalue expansion method. The connection with the continuous diffusion model is discussed. 相似文献
Calcium sulphate phosphors activated with samarium as an impurity with various percentage composition have been prepared and
their fluorescence rise and phosphorescence decay behaviours have been studied. The growth curve is investigated to study
the density of traps. The process of filling of traps during x-ray excitation is revealed. The decay curves are analysed to
study the distribution of traps, the nature of decay and kinetics involved in the luminescence process. The concentration
dependence of fluorescence emission of the phosphors is also discussed. 相似文献
We report a rigorous computational treatment of quantum dynamics of cold ions in a double-well trap using the time-dependent Schrödinger equation. Our method employs a numerically accurate approach that avoids approximations, such as assumption of weak coupling between the wells; normal mode nature of vibrations; or harmonic approximation for energy spectrum of the double-well system. Our goal is to reproduce, from first principles, the process of energy swaps between the wells observed in the experiments at NIST [Nature 471, 196 (2011)] and Innsbruck [Nature 471, 200 (2011)]. The model parameters and the initial conditions are carefully chosen to mimic experimental conditions. We obtain accurate energies and wave functions of the system numerically, and study the evolution of motional wave packets to provide new insight. This model reproduces experimental results obtained by NIST and Innsbruck in detail. We explain the energy transfer in terms of wave packet dynamics in the asymmetric potential energy well. We also show that, for a localised initial wave packet, this phenomenon can be interpreted using the terms of classical dynamics, such as trajectory of motion governed by the well-known simple principle: the angle of reflection equals the angle of incidence. 相似文献
Ni/SiO2/Si MOS structures were fabricated on n-type Si wafers and were irradiated with 50 MeV Li3+ ions with fluences ranging from 1×1010 to 1×1012 ions/cm2. High frequency C–V characteristics are studied in situ to estimate the build-up of fixed and oxide charges. The nature of the charge build-up with ion fluence is analyzed. Defect levels in bulk Si and its properties such as activation energy, capture cross-section, trap concentration and carrier lifetimes are studied using deep-level transient spectroscopy. Electron traps with energies ranging from 0.069 to 0.523 eV are observed in Li ion-irradiated devices. The dependence of series resistance, substrate doping and accumulation capacitance on Li ion fluence are clearly explained. The study of dielectric properties (tan δ and quality factor) confirms the degradation of the oxide layer to a greater extent due to ion irradiation. 相似文献
Substitution reactions between gaseous ions and neutral substrate molecules are of ongoing high interest. To investigate these processes in a qualitative and quantitative manner, we have constructed a device, with which a defined amount of a volatile substrate can be mixed with a defined amount of helium gas and added into a three‐dimensional quadrupole ion trap. From the known inner volume of the device, the known ratio nsubstrate:nHe of the mixture, and the determined absolute partial pressure of helium in the ion trap, we can derive the partial pressure of the substrate in the ion trap and, thus, convert the directly observable pseudo–first‐order rate constants of the substitution reactions into absolute bimolecular rate constants. We have tested the device by investigating a series of SN2 reactions of Br ? and CF3CH2O ? anions as well as ligand exchange reactions of ligated Na+ cations. As the obtained results suggest, the described device makes it possible to determine the bimolecular rate constants of substitution reactions as well as other ion‐molecule reactions with satisfactory accuracy and reliability. 相似文献
In this communication, γ‐phenyl‐γ‐butyrodithiolactone (DTL1) is presented as the first example of a new type of control agent. The styrene polymerization carried out at 60 °C in the presence of DTL1 exhibits living characteristics, without consuming DTL1 during the process. This unprecedented behavior was explained by a mechanism based on the reversible formation of a persistent radical adduct between the DTL1 and the polystyrene macroradicals.