Cellulose-based fibers from liquid–crystalline solutions. II. Processing and morphology of acetate/butyrate esters

Fibers were spun from isotropic and anisotropic dimethylacetamide solutions of cellulose esters. Take-up speeds of the dry jet/wet spinning process varied. Water served as the coagulant. The mechanical properties of the fibers increased as spinning progressed from the isotropic to the anisotropic state of the solution. A trade-off in solubility and fiber properties was noted as the butyryl acetyl ratio decreased. Whereas high butyryl content enhances both overall solubility and the formation of liquid–crystalline solutions at lower concentration, it results in lower fiber modulus and strength. Morphology of the fibers depended on the coagulation rate which was influenced by the concentration of the sppinning solution. The level of orientation and crystallinity of the fibers increased somewhat when they were spun from liquid-crystalline solutions. © 1993 John Wiley & Sons, Inc.     

关于无界无限维商品空间上的生产经济均衡

本文研究了无界无限维商品空间上的生产经济均衡的存在性．虽然我们把商品空间看成是Ｒｉｅｓｚ空间，但并没有在它的正锥上作任何内部假设．同时我们的结果也为现代企业或公司从事经济预测、制订生产计划、改善经营管理、提高劳动生产率以及优化经济机制提供了理论依据．     

Excess enthalpies of mixing tetrahydrofuran and tetrahydropyran with some chloroalkanes at 26.9°C

Excess enthalpies of mixing H _m ^E of tetrahydrofuran and tetrahydropyran with trichloromethane, tetrachloromethane, 1,2-dichloroethane, 1,1,2-trichloroethane and 1,1,2,2-tetrachloroethane have been determined at 26.9°C and are found to be negative over the entire composition range for both sets of the ether mixtures. H _m ^E decreases in the sequence; dichloroethane > tetrachloromethane > trichloroethane > trichloromethane > tetrachloroethane. The results are explained on the basis of strong O...H-C and weak Cl...O specific interactions. Flory's theory has been used to correlate the experimental data with good agreement found between the theoretical and experimental values of H _m ^E .     

Critical evaluation of gas standards based on hydrogen

Summary Six commercial hydrogen standards containing helium, oxygen, nitrogen, methane and carbon dioxide at trace levels were analyzed by gas chromatography, for periods up to 105 days. The concentrations, in the range of 0–120 μmol mol⁻¹, were stable (with the exception of oxygen) but often significantly different from the certified values provided by the suppliers, especially for helium, oxygen and nitrogen. Concurrently, some experiments were carried out to verify the stability of gas mixtures based on hydrogen stored in cylinders submitted to different chemical and physical treatments. The causes that led to the deviations observed, as well as the decreases in oxygen, are discussed. Presented at the 21^st ISC held in Stuttgart, Germany, 15^th–20^th September, 1996.     

NOTE ON THE OSCILLATION OF THE SOLUTION FOR GENERALIZED LIENARD EQUATIONS

Ｃｏｎｓｉｄｅｒｉｎｇｓｙｓｔｅｍ：ｘ＝φ（ｙ）－Ｆ（ｘ），ｙ＝－ｇ（ｘ）｛（Ｅ）ｉｎｗｈｉｃｈＦ（ｘ）＝∫ｘ０ｆ（ｔ）ｄｔ，ｆ（ｘ），ｇ（ｘ），φ（ｙ）ａｒｅｃｏｎｔｉｎｕｏｕｓ，ａｎｄｓａｔｉｓｆｙｔｈｅｃｏｎｄｉｔｉｏｎｓｗｈｉｃｈｅｎｓｕｒ...     

具有两台专用机,两台通用机的Q4／／Cmax问题的近似算法

本文讨论具有两台专用机、两台通用机的两组工件的同种类平行机的Q4／／Cmax问题，对这类特殊的排序问题，提出一种启发式算法，得到了最差情况下性能指标的严格的界．     

Estimates for the Rapid Decay of Concentration Functions of n-Fold Convolutions

We estimate the concentration functions of n-fold convolutions of one-dimensional probability measures. The Kolmogorov–Rogozin inequality implies that for nondegenerate distributions these functions decrease at least as O(n ^–1/2). On the other hand, Esseen⁽³⁾ has shown that this rate is o(n ^–1/2) iff the distribution has an infinite second moment. This statement was sharpened by Morozova.⁽⁹⁾ Theorem 1 of this paper provides an improvement of Morozova's result. Moreover, we present more general estimates which imply the rates o(n ^–1/2).     

转动系统的相对论性分析力学理论

本文讨论了转动相对论力学理论，主要是建立转动系统的相对论性分析力学理论·构造转动系统的相对论性广义动能函数Ｔｒ＝∑ｎｉ＝１Ｉ０ｉΓｉ２（１－１－θ·２ｉ／Γｉ２）和广义加速度能量函数Ｓｒ＝１２∑ｎｉ＝１Ｉｉ（θ·ｉ·θ¨ｉ）２Γｉ２－θ·２ｉ＋θ¨２ｉ，给出其Ｈａｍｉｌｔｏｎ原理和三种不同形式的Ｄ′Ａｌｅｍｂｅｒｔ原理；对于完整约束系统，建立了转动系统的相对论性Ｌａｇｒａｎｇｅ方程、Ｎｉｅｌｓｅｎ方程、Ａｐｐｅｌ方程和Ｈａｍｉｌｔｏｎ正则方程；对于非完整约束系统，建立了转动系统的相对论性Ｒｏｕｔｈ方程、Чаплыгин方程、Ｎｉｅｌｓｅｎ方程和Ａｐｐｅｌ方程；并给出转动系统的相对论性Ｎｏｅｔｈｅｒ守恒律     

Bellman最优性原理——论动态规划(Ⅰ)

对于Bellman最优性原理,本文举出实例表明:(1)策略不一定有(合理的)子策略;(2)子策略不一定存在最优子策略;(3)最优策略不一定有最优子策略;(4)用最短路与反证法来论述最优性原理的正确性,不能肯定成立;(5)Bellman最优性原理与其递推公式并不等价。 讨论四类最优策略之后,给出最优性原理与递推公式等价的一个充分性定理。     

甲酸甲酯水解固体超强酸催化剂的研究

固体超强酸作甲酸甲酯水解转化率和对甲酸的催化剂、进料速度、反应温度对甲酸甲酯水解转化率和对甲酸出口浓度的影响，当原料水与酯的摩尔比为１、反应温度１００℃、原料与催化剂的接触时间为１６ｍｉｎ时，甲酸甲酯的转化率为２４．６％（甲酸的出口浓度达１４．５％）。