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151.
Hewen Liu Jan H. Nsman Mikael Skrifvars 《Journal of polymer science. Part A, Polymer chemistry》2000,38(17):3074-3085
Novel hyperbranched polymers were synthesized in a high yield without gelation through the free‐radical alternating copolymerization of an AB/B′ (allyloxy maleic acid/maleic anhydride) system, in which group B and monomer B′ both could only alternately polymerize with group A. The arm number of the produced highly branched polymers was equal to the product of the linear chain length and the probability of pendent B groups being growing centers. The molecular weight of these novel hyperbranched polymers increased with increasing initiator concentration and prolonged polymerization times. The AB/B′ system, used as described, provides a new general methodology for highly branched and functional polymers. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 3074–3085, 2000 相似文献
152.
Koji Takagi Tatsuya Hattori Hideo Kunisada Yasuo Yuki 《Journal of polymer science. Part A, Polymer chemistry》2000,38(24):4385-4395
Two types of dendrimers with a 1,3,5‐triazine ring at the branch point were synthesized by divergent and convergent methods. The divergent method began with 2,4,6‐tris(p‐nitroanilino)‐1,3,5‐triazine as a trifunctional core. Each cycle involved the reduction of the peripheral NO2 group followed by a reaction with 2‐chloro‐4,6‐bis(p‐nitroanilino)‐1,3,5‐triazine. The synthetic cycle was completed by the coupling with 2,4‐dianilino‐6‐chloro‐1,3,5‐triazine (DACT) to eventually accomplish second‐generation dendrimers ([G2]3‐C) bearing 12 benzene rings at their edge. The convergent approach started with the reaction of DACT with p‐nitrophenol to give rise to 2,4‐dianilino‐6‐(p‐nitrophenoxy)‐1,3,5‐triazine. The synthetic cycle consisted of reduction of the NO2 group and coupling with 2,4‐dichloro‐6‐(p‐nitrophenoxy)‐1,3,5‐triazine. The final step was the connection of each monodendron with cyanuric chloride to produce tridendron; in this way, the second‐generation dendrimer ([EG2]3‐C) was obtained. Gel permeation chromatography analyses indicated the aggregation of dendrimers in solution. Ultraviolet spectroscopic analyses revealed that the larger dendrimer had a more conjugated electron system from the core to the periphery. The thermal properties were evaluated by thermogravimetric analysis (TGA); excellent heat resistance was indicated, especially in [G1]3‐C, which included alternately imine‐like nitrogen‐linked 1,3,5‐triazine and benzene rings. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 4385–4395, 2000 相似文献
153.
以Fmoc手工固相合成法合成了以多聚赖氨酸为骨架, 表面结合丝组二肽的四分支和二分支树状多肽, 以高效液相色谱提纯, 电喷雾电离质谱表征, 并通过凝胶电泳法研究了其对λDNA的切割活性. 相似文献
154.
155.
M. Nakano H. Fujita M. Takahata S. Kiribayashi K. Yamaguchi 《International journal of quantum chemistry》2001,84(6):649-659
We investigate the microscopic third‐order nonlinear optical properties, i.e., the second hyperpolarizabilities (γ), of two different sizes of molecular aggregates with a dendritic, i.e., Bethe‐lattice, structure. One possesses a nonfractal structure, while the other has a fractal structure. The aggregate is treated in a two‐exciton model composed of two‐state monomers coupled to each other by the dipole–dipole interaction. The off‐resonant γ of the aggregates are calculated by the numerical Liouville approach, including relaxation effects. The total γ value is partitioned into the contribution of virtual exciton generation, and its spatial contribution to γ is analyzed in relation to the virtual excitation processes in the perturbation theory. It is found that the intermolecular‐interaction effect enhances both one‐ and two‐exciton‐generation contributions, while the relaxation effect reduces those, although the one‐ and two‐exciton‐generation contributions have mutually opposite signs. From the comparison of spatial contributions to γ between the nonfractal and fractal aggregates, an enhancement of the contribution to γ from the periphery to the core is observed in the fractal structure, while such a feature is not observed in the nonfractal structure. © 2001 John Wiley & Sons, Inc. Int J Quantum Chem, 2001 相似文献
156.
The functionalized carbosilane dendrimers can be divided into three categories: surface- functionalization, core-functionalization and focal-point functionalization1-5. The func- tionalized dendrimers can be used as catalyst supporters, medicine control-r… 相似文献
157.
Carbosilane dendrimers with terminal allyl groups were synthesized and used to encapsulate the allyl derivative of fluorescein (allyl-FL) doped in PMMA. The optical property of this system was investigated and the results showed that the concentration of allyl-FL in PMMA could be increased to 4.5 wt% without decrease of the luminescence efficiency by adding the dendrimer into the system. The allyl-FL/dendrimer/PMMA film was embedded into a resonance cavity composed of two pieces of photonic band gap (PBG) materials to form a new-type solid-state laser. A laser emission at 589 nm was obtained when excited with a third harmonic generation (THG) of a pulsed Nd:YAG laser (355 nm) and its full-width at half-maximum of the spectrum was 1.7 nm. 相似文献
158.
Changfeng?Yi Zushun?XuEmail author Warren?T.?Ford 《Colloid and polymer science》2004,282(9):1054-1058
Single state emulsion polymerization of styrene with aggregates of generation 4.5 polyamideamine dendrimer and sodium dodecyl sulfate as templates produces lattices with diameters in the range 33–66 nm and polydispersity indices of less than 10%. 相似文献
159.
多官能团单体对超支化聚酰胺酯光固动力学及其固化膜热性能的影响 总被引:7,自引:0,他引:7
以1,1,1-三羟甲基丙烷为核,4-N,N-(2-羟乙基)-4-酮丁酸为单体,按照 一定比例,合成理论上第二代羟端基超支化聚酰胺酯,再与丙烯酰氯反应获得丙烯 酸化超支化聚酰胺酯预聚物(HAPAE-2-A),它在光引发剂存在下经紫外光辐照可 以快速固化成膜。根据~1H NMR 谱测定所得产物的反应程度为85%。采用凝胶渗透 色谱和气相渗透法测定所得产物的分子量分布和数均分子量分别为2.16和1620 g/mol,与其理论分子量相比,其反应程度为89%,从而估算产物实际端基丙烯酸 酯双键数为10左右。采用光-差热分析仪研究HAPAE-2-A的反应动力学,发现当体系 中加入多官能团单体,如三羟甲基丙烷三丙烯酸酯、己二醇二丙烯酸酯和乙氧基一 缩二乙二醇丙烯酸酯时,多官能团单体的官能度及含量会对体系的最大光聚合反应 速率和不饱和双键的反应程度产生较大的影响。通过动态力学热性能测试发现 HAPAE-2-A光固化膜的玻璃态转化温度随多官能团单体的加入而提高。 相似文献
160.
报道了新化合物含108个丁氧基偶氮基元端基的三代(D3)碳硅烷光致变色液晶树状物在各溶液中的反-顺光异构化(光致变色)反应速率常数kp, 光化学回复异构化正/逆反应速率常数kt和kc, 热回复异构化反应速率常数kH, 光化学回复异构化反应平衡常数kt/kc, 活化能E, 异构化转换率及热回复异构化反应中的反-顺异构体组分比. D3的光致变色反应速率常数为10-1 s-1, 而含偶氮基元的光致变色液晶聚硅氧烷的光致变色反应速率常数为10-8 s-1, 因此, D3的光响应速度比后者快107倍. 相似文献