国产滤纸室温燐光背景的考察和降低背景方法的研究

固体基质室温燐光法(SS-RTP)的检出限依赖于固体基质的RTP背景的高低。本文考察了七种国产滤纸在重原子存在时和不存在时的RTP背景。研究了各种降低滤纸背景的处理方法。研究结果表明,采用NaOH、β-环糊精、EDTA、乙醇和丙酮浸泡或煮沸滤纸,都能不同程度的降低滤纸背景,最大降低率为88％。KI、NaAc、Pb(Ac)_2、TlNO_3和Cscl等重原子可使滤纸背景有较大幅度的增强,而经处理的滤纸,RTP背景较未处理滤纸背景降低一倍以上,最大可降低94.5％。用NaOH溶液处理滤纸,不仅能有效地降低背景,而且能提高分析物的RTP信号。研究表明纤维素伴生物质——木素,可能是产生燐光背景的杂质之一。     

NANOMECHANICAL MAPPING OF CARBON BLACK REINFORCED NATURAL RUBBER BY ATOMIC FORCE MICROSCOPY

Atomic force microscopy （AFM） has the advantage of obtaining mechanical properties as well as topographic information at the same time. By analyzing force-distance curves measured over two-dimensional area using Hertzian contact mechanics, Young＇s modulus mapping was obtained with nanometer-scale resolution. Furthermore, the sample deformation by the force exerted was also estimated from the force-distance curve analyses. We could thus reconstruct a real topographic image by incorporating apparent topographic image with deformation image. We applied this method to carbon black reinforced natural rubber to obtain Young＇s modulus distribution image together with reconstructed real topographic image. Then we were able to recognize three regions; rubber matrix, carbon black （or bound rubber） and intermediate regions. Though the existence of these regions had been investigated by pulsed nuclear magnetic resonance, this paper would be the first to report on the quantitative evaluation of the interfacial region in real space.     

磁场对微乳液法合成聚苯胺结构及其电化学行为的影响

在不同磁场强度下,采用微乳液聚合法合成导电聚苯胺(PANI),以碳纸负载PANI为工作电极,通过循环伏安测试方法,探讨了磁场、氧化剂浓度和聚合时间对微乳液聚合法合成PANI电化学性能的影响;并通过X射线衍射(XRD)、四探针电导率测试和傅立叶红外光谱(FTIR)对产物结构和性能的表征分析,印证了循环伏安分析结果的可靠性.实验结果表明,与无磁条件下制备的PANI相比,磁场条件下制备的PANI具有较高的导电性和规整度;FTIR谱图分析表明,由于磁场的取向作用使分子间相互作用力降低,分子链离域程度增大,使磁场条件下合成PANI的主要特征峰有向低频方向移动的趋势,但分子的基本结构单元没有发生变化.研究结果显示,利用负载PANI的碳纸为工作电极,能够对微乳液法合成PANI的电化学行为进行有效的实时表征.     

Triclosan‐based antibacterial paper reinforced with nano‐montmorillonite: a model nanocomposite for the development of new active packaging

In this study, a suitable method is reported to produce reinforced antibacterial paper packaging using the antimicrobial triclosan (TC) and organically modified montmorillonite (OMMT) as “model” compounds. Direct incorporation of TC at a concentration of 1 wt% and OMMT at concentrations of 1, 4, 7, and 10 wt% into papers was performed via coating process, and the resulting materials were characterized by in vitro antimicrobial assays, thermogravimetric analysis, scanning electron microscopy, mechanical tests, and water vapor transmission rate determinations. It was demonstrated that the presence of 1% TC in the coated papers exhibited inhibitory effects against Staphylococcus aureus and Escherichia coli. It was also pointed out that increases of approximately 30% in the tensile strength of commercial paper are obtained by using the OMMT at a concentration of 1 wt%. Water barrier property and thermal stability of paper were also enhanced because of the coating process and the incorporation of OMMT. The results from this study demonstrate that OMMT has a great potential to be incorporated into coating formulations to obtain antibacterial‐coated papers with improved properties for various packaging applications. Copyright © 2011 John Wiley & Sons, Ltd.     

基于篇章结构相似度的复制检测算法

学术论文的复制检测研究对于知识产权保护和抑制抄袭侵权等行为有重要意义.国内外主要用数字指纹及关键词匹配等技术进行论文的复制检测.为解决目前中文复制检测难题,给出了一种基于篇章结构相似度的中文学术论文复制检测算法及其问题的数学模型.在分析论文篇章结构的基础上,利用数字指纹和词频统计等技术,经编程实现,用于论文的全抄、部分抄袭和拼抄等抄袭现象的初步检测.与基于全文数字指纹和基于全文词频统计的检测方法相比较,更适用于要求较准确的论文复制检测.     

MULTILINEAR CALDER(O)N-ZYGMUND OPERATOR ON MORREY TYPE SPACES——In Memory of Professor Yongsheng Sun

In this paper, the authors study the boundedness of a class of multi-sublinear operators on the product of Morrey, Herz-Morrey and generalized Morrey spaces, respectively. As their special cases, the corresponding results of multilinear Calderón-Zygmund operator can be obtained.     

基于博弈论的融资租赁保证金确定方法研究

针对融资租赁中租金偿还违约风险的防范问题,研究了如何合理设置租赁保证金来防范违约风险.运用博弈理论建立了租金偿还的动态博弈模型,采用逆向归纳法求解该博弈模型并推导出了预防性保证金确定方法及其适用条件,通过边界条件的改变继而推导出了补偿性保证金确定方法及其适用条件.算例分析表明,运用两种方法来计算租赁保证金时,只需已知租赁项目各期租金和租赁资产的价值而无需知道租赁项目的各期收益,仅以出租人预期租赁项目在各期的收益与租金之间的大小作为判据来选择保证金确定方法.两种保证金确定方法具有较高的实用性和可操作性,是出租人合理地确定租赁保证金的有效方法.     

基于改进自适应遗传算法的组卷研究

针对遗传算法容易出现早熟和收敛速度慢的问题,根据群体适应值分布的变化特点,启发性地提出了一种新的基于小生境技术的自适应遗传算法（ANGA）。根据群体中各个个体的适应值分布情况加以启发,引入了一个自适应的常数Cmin,通过白适应调整Cmin以适时改变群体适应值的分布,优化了各个个体被选择的概率。详细介绍了ANGA应用于组卷问题的步骤。涵盖了其中的各项关键技术：组卷策略、编码方案、适应值函数的确定、选择交叉变异箅子的实现。并以目前的计算机等级考试三级信息管理技术的组卷为例,采用ANGA算法进行了仿真计算。仿真结果表明,ANGA算法能够成功地应用于自动组卷。算法能够以100％的概率在较短的时问内完成组卷,组卷效率高、成功率高;且算法对初值不敏感．具有较好的鲁棒性。     

深化管理提高纸质图书利用率

结合大理学院图书馆的管理实践,提出了提高纸质图书利用率的一些方法和措施。     

Ranking Related Research Papers Based on Citation Graph

Research papers are of great importance for researchers to record and share their ideas, studies and results. Meanwhile, they are the bases for further research work. Finding related research papers is the preliminary of good research. A new method for ranking related research papers is introduced in this paper. Given a set of interested papers, the method proposed in this paper may rank related papers just based on a citation graph by constructing the minimal Steiner trees. The method can work with the existing keyword based methods. Intensive experiments on a specific research topic show that the proposed method provides a different ranking criterion to existing ones, and can effectively retrieve those highly related papers.