Polynuclear manganese grids and clusters—A magnetic perspective

High nuclearity paramagnetic, spin-coupled transition metal clusters and grids are fascinating chemists and physicists partly because of their structural beauty, and the challenge of creating them, but also because of their novel physical properties. Magnetic interactions between the spin centers are a primary focus. This review will examine a selection of Mn(II) polynuclear grids and clusters, with nuclearities in the range Mn₄ to Mn₉. Theoretical treatments of the magnetic properties are discussed, and approaches to solving the exchange problem for ‘large’ spin systems related to computational difficulties. A freely available software package (MAGMUN4.1) is presented as a means of dealing simply with spin-coupled clusters in general, and symmetry reduction methods are discussed briefly as a means of dealing with ‘large’ spin systems.     

Amide-water interactions in cosolvent systems. I. Solubilities and apparent molar volumes of methyl paraben

Solubility and apparent molar volume data are used to demonstrate effects of amide alkylation on amide-water interactions at 25° C. Precise measurements were made of the apparent molar volumes of the amides in binary amide-water mixtures using a dilatometric technique. The results show that the apparent molar volumes of alkyl-substituted amides in water pass through a minimum at an amide concentration which varies inversely with the degree of alkylation. Further studies showed that the solubilities of methyl paraben (methyl-p-hydroxybenzoate) and naphthalene in various amide-water solvent systems increased in characteristic fashion with amide alkylation.     

宗教文化对泉州古城街道活力的影响分析

以泉州古城为例,利用多源数据构建街道活力与其影响因素的分析框架,建立包含街道物理环境影响因素和宗教文化影响因素的街道活力评价指标体系.分析宗教建筑对街道活力的影响,并进一步分析宗教建筑与街道的空间关系对街道活力的影响.研究结果表明：街道活力与街道两侧的寺庙宗祠的数量呈负相关,香火旺盛的寺庙宗祠会提升附近街道的活力,但与寺庙宗祠距离无显著相关关系;在寺庙宗祠入口设置广场或宽敞的步行区可以集聚人气,并在寺庙宗祠周围布置商业或与其他景点结合以形成连续的活力点,有助于提升街道活力.     

IRS辅助的MISO-SWIPT安全速率最大化算法

为增强系统的稳定性,基于智能反射面（intelligent reflection surface,IRS）辅助安全通信,为用户采用功率分配架构的无线携能传输（simultaneous wireless information and power transfer,SWIPT）技术以提高用户安全速率并降低用户的能量消耗,建立了系统安全速率最大化的目标函数模型;考虑IRS相移约束、基站最大发射功率、功率分配比率约束和用户最低能量采集约束,提出了一种基于交替优化的安全速率最大化算法。利用连续凸近似算法,将目标函数转化为凸的形式;采用交替优化,对耦合变量进行解耦处理;提出一种波束赋形算法以实现安全速率最大化。仿真表明,提出的算法能够有效提升IRS辅助的SWIPT系统的安全速率,至少比其他算法提高了2.63bps/Hz。     

IRS辅助WPCN用户公平性与系统吞吐量优化方案

为了解决无线供电网（wireless powered communication network,WPCN）中用户公平性不足与系统灵活性差的问题,提出一种基于智能反射面（intelligent reflecting surface,IRS）的优化方案。该方案直接将公平指数（fairness index,FI）和系统吞吐量加权相加作为优化目标,建立了用户公平性与系统吞吐量的联合优化问题。由于所建立的优化问题是非凸问题,因此,将优化问题拆分为时隙长度和IRS反射系数优化子问题,然后交替求解。针对时隙长度优化子问题,使用逐次凸逼近（successive convex approximation,SCA）算法求解;针对IRS反射系数优化子问题,使用闭式解、SCA和半定松弛（semi definite relaxation,SDR）算法求解。仿真结果表明,所提方案在用户公平性和系统灵活性方面优于其他方案。     

棉纺厂管理信息系统的研制

本文根据开发CTU-JMS管理信息系统已取得的成功经验,介绍CTU—JMS管理信息系统的运行环境;总体规划中运用的两种设计策略——“由顶向下”分析法和“由下至上”分析法;MIS中建立大型基础数据库采用的主要技术;MIS决策管理层的形成以及生产经营决策子系统的技术特点。为推进我国的纺织企业管理信息系统的开发和实现现代化管理作了探索。     

小型文献资料检索系统

本文介绍的这种情报资料检索系统,采用了数据压缩存贮技术,并使用链表记录的存贮结构解决了变长信息的存贮问题,系统的功能以“菜单”和“快速”两种方式提供给用户,使用方便。     

Comparison of path-complete Lyapunov functions via template-dependent lifts

This paper investigates, in the context of discrete-time switched systems, the problem of comparison for path-complete stability certificates. We introduce and study abstract operations on path-complete graphs, called lifts, which allow us to recover previous results in a general framework. Moreover, this approach highlights the existing relations between the analytical properties of the chosen set of candidate Lyapunov functions (the template) and the admissibility of certain lifts. This provides a new methodology for the characterization of the ordering relation of path-complete Lyapunov functions criteria, when a particular template is chosen. We apply our results to specific templates, notably the sets of primal and dual copositive norms, providing new stability certificates for positive switched systems. These tools are finally illustrated with the aim of numerical examples.     

Moment closure hierarchies for kinetic theories

This paper presents a systematicnonperturbative derivation of a hierarchy of closed systems of moment equations corresponding to any classical kinetic theory. The first member of the hierarchy is the Euler system, which is based on Maxwellian velocity distributions, while the second member is based on nonisotropic Gaussian velocity distributions. The closure proceeds in two steps. The first ensures that every member of the hierarchy is hyperbolic, has an entropy, and formally recovers the Euler limit. The second involves modifying the collisional terms so that members of the hierarchy beyound the second also recover the correct Navier-Stokes behavior. This is achieved through the introduction of a generalization of the BGK collision operator. The simplest such system in three spatial dimensions is a 14-moment closure, which also recovers the behavior of the Grad 13-moment system when the velocity distributions lie near local Maxwellians. The closure procedure can be applied to a general class of kinetic theories.     

一类一阶线性非齐次方程组的解法

利用二阶线性微分方程的可解定理,给出一阶线性非齐次方程组的一种新解法