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101.
Eva Lucaccini Matteo Briganti Dr. Mauro Perfetti Dr. Laure Vendier Dr. Jean‐Pierre Costes Dr. Federico Totti Prof. Dr. Roberta Sessoli Prof. Dr. Lorenzo Sorace 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(16):5552-5562
The magnetic behaviour of a Dy(LH)3 complex (LH? is the anion of 2‐hydroxy‐N′‐[(E)‐(2‐hydroxy‐3‐methoxyphenyl)methylidene]benzhydrazide) was analysed in depth from both theoretical and experimental points of view. Cantilever torque magnetometry indicated that the complex has Ising‐type anisotropy, and provided two possible directions for the easy axis of anisotropy due to the presence of two magnetically non‐equivalent molecules in the crystal. Ab initio calculations confirmed the strong Ising‐type anisotropy and disentangled the two possible orientations. The computed results obtained by using ab initio calculations were then used to rationalise the composite dynamic behaviour observed for both pure DyIII phase and YIII diluted phase, which showed two different relaxation channels in zero and non‐zero static magnetic fields. In particular, we showed that the relaxation behaviour at the higher temperature range can be correctly reproduced by using a master matrix approach, which suggests that Orbach relaxation is occurring through a second excited doublet. 相似文献
102.
There is no universal method to perform dynamic analysis on solid rubber anti-vibration systems. In this article, an equivalent damping ratio is introduced to account for rubber hysteresis using a resilience experiment. A new concept, NFR (Natural Frequency Region), is defined for dynamic evaluation based on natural characteristics of a rubber anti-vibration system itself. Two typical industrial products were selected to verify the proposed NFR approach. The verification procedure involves three parts: natural frequencies, harmonic spectra and impact responses. The dynamic responses from both simulation and experiment have been compared and have not only demonstrated that the proposed approach is reliable but that it could also be used to guide the design of rubber anti-vibration systems in industry. The key points for applying this approach are also presented through the verification procedure. 相似文献
103.
104.
Matthias Ermer Julian Mehler Björn Rosenberger Dr. Marcus Fischer Dr. Peter S. Schulz Prof. Martin Hartmann 《ChemistryOpen》2021,10(2):233-242
Using ionic liquids (ILs) as linker precursors, the well-known metal-organic framework (MOF) UiO-66 (Universitetet i Oslo) and the recently reported MOF hcp UiO-66 (hexagonal closed packed) have been successfully synthesized and characterized. The advantage of the applied novel synthesis approach is an economically and environmentally benign work-up procedure, due to the better solubility of the IL. Additionally, the reactivity of the terephthalate anions is increased compared to terephthalic acid, resulting in faster MOF formation with an increased amount of defects in the MOF structure. In order to explore to the influence of defects on the catalytic performance, the cyclisation of citronellal to isopulegol was employed as test reaction. The activity of hcp UiO-66 and fcc UiO-66 (face centered cubic) is improved compared to other MOF or zeolite based catalysts, while the selectivity is similar. 相似文献
105.
从物理化学的角度分析了日常生活中的返潮现象,以风冷冷冻除湿机、空调、转轮除湿机为例,解析了室内除湿中蕴含的物理化学原理。引导学生利用物理化学的眼光看待生活,有利于学生分析生活现象的本质,提高逻辑分析能力,克服学习物理化学畏难情绪的同时增加学习兴趣。 相似文献
106.
《Journal of computational science》2014,5(3):415-426
Modal analysis of multi-body systems is broadly used to study the behavior and controller design of dynamic systems. In both cases, model reduction that does not degrade accuracy is necessary for the efficient use of these models. Previous work by the author addressed the reduction of modal representations by eliminating entire modes or individual modal elements (inertial, compliant, resistive). In that work, the bond graph formulation was used to model the system and the modal decomposition was limited to systems with proportional damping. The objective of the current work is to develop a new methodology such that model reduction can be implemented to modal analysis of multi-body systems with non-proportional damping that were not modeled using bond graphs. This extension also makes the methodology applicable to realistic systems where the importance of modal coupling terms is quantified and potentially eliminated. The new methodology is demonstrated through an illustrative example. 相似文献
107.
引用两种加速计算PageRank的算法,分别为内外迭代法和两步分裂迭代算法.从这两种方法中,得到多步幂法修正的内外迭代方法.首先,详细介绍了算法实施过程.然后,对此算法的收敛性进行证明,并且将此算法的谱半径与两步分裂迭代算法的谱半径进行比较.最后,数值试验说明该算法的计算速度比两步分裂迭代法要快. 相似文献
108.
We investigate the global existence and asymptotic behavior of classical solutions for the 3D compressible non-isentropic damped Euler equations on a periodic domain. The global existence and uniqueness of classical solutions are obtained when the initial data is near an equilibrium. Furthermore, the exponential convergence rates of the pressure and velocity are also proved by delicate energy methods. 相似文献
109.
A numerical investigation is performed into the nonlinear dynamic behavior of a clamped–clamped micro-beam actuated by a combined DC/AC voltage and subject to a squeeze-film damping effect. An analytical model based on a nonlinear deflection equation and a linearized Reynolds equation is proposed to describe the deflection of the micro-beam under the effects of the electrostatic actuating force. The deflection of the micro-beam is investigated under various actuating conditions by solving the analytical model using a hybrid numerical scheme comprising the differential transformation method and the finite difference approximation method. It is shown that the numerical results for the dynamic pull-in voltage of the clamped–clamped micro-beam deviate by no more than 2.04% from those presented in the literature based on the conventional finite difference scheme. The effects of the AC voltage amplitude, excitation frequency, residual stress, and ambient pressure on the center-point displacement of the micro-beam are systematically explored. Moreover, the actuation conditions which ensure the stability of the micro-beam are identified by means of phase portraits. Overall, the results presented in this study confirm that the hybrid numerical method provides an accurate means of analyzing the complex nonlinear behavior of common electrostatically-actuated microstructures. 相似文献
110.