Synthesis of ABA‐triblock and star‐diblock copolymers with poly(2‐adamantyl vinyl ether) and poly(n‐butyl vinyl ether) segments: New thermoplastic elastomers composed solely of poly(vinyl ether) backbones

ABA‐type triblock copolymers and AB‐type star diblock copolymers with poly(2‐adamantyl vinyl ether) [poly(2‐AdVE)] hard outer segments and poly(n‐butyl vinyl ether) [poly(NBVE)] soft inner segments were synthesized by sequential living cationic copolymerization. Although both the two polymer segments were composed solely of poly(vinyl ether) backbones and hydrocarbon side chains, they were segregated into microphase‐separated structure, so that the block copolymers formed thermoplastic elastomers. Both the ABA‐type triblock copolymers and the AB‐type star diblock copolymers exhibited rubber elasticity over wide temperature range. For example, the ABA‐type triblock copolymers showed rubber elasticity from about ?53 °C to about 165 °C and the AB‐type star diblock copolymer did from about ?47 °C to 183 °C with a similar composition of poly(2‐AdVE) and poly(NBVE) segments in the dynamic mechanical analysis. The AB‐type star diblock copolymers exhibited higher tensile strength and elongation at break than the ABA‐type triblock copolymers. The thermal decomposition temperatures of both the block copolymers were as high as 321–331 °C, indicating their high thermal stability. © 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013     

Extruder‐made TPO nanocomposites. II. Effect of maleated poly(propylene)/organoclay ratio on morphology and thermal expansion behavior

Coefficients of linear thermal expansion (CTE) for poly(propylene)/ poly(propylene)‐grafted‐maleic anhydride/montmorillonite ethylene‐co‐octene elastomer (PP/PP‐g‐MA/MMT/EOR) blend nanocomposites were determined as a function of MMT content and various PP‐g‐MA/organoclay masterbatch ratios. The nanocomposites were prepared in a twin‐screw extruder at a fixed 30 wt % elastomer, 0–7 wt % MMT content, and various PP‐g‐MA/organoclay ratio of 0, 0.5, 1.0, and 1.5. The organoclay dispersion facilitated by the maleated PP helps to reduce the size of the dispersed phase elastomer particles in the PP matrix. The elastomer particle size decreased significantly as the PP‐g‐MA/organoclay ratio and MMT content increased; the elastomer particles viewed // to flow direction (FD) are smaller and less deformed compared to those viewed // to transverse direction (TD). The elastomer particle shape based on the view along the three orthogonal directions of the injection molded sample is similar to a prolate ellipsoid. The CTE decreased significantly in the FD and TD, whereas a slight increase is observed in the normal direction in the presence of MMT and PP‐g‐MA. The Chow model based on a two population approach showed better fit to experimental CTE when the effect of MMT and elastomer are considered individually. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B Polym. Phys. 2013 , 51, 952–965     

轴向冲击圆柱壳动力屈曲与动力失稳的实验及探讨

采用落锤作为加载装置对三种长度的钢质圆管进行了轴向冲击实验,得到了轴对称屈曲模态和整体失稳形式及冲击力时程曲线,讨论了实验中皱折出现在端部附近和较长壳渐近屈曲但较短壳整体失稳可能的原因。     

对柱状声源声辐射逆问题的探讨

对细长柱状声源的声辐射逆问题进行了探讨 其主要思想是 :把柱状声源所产生的声场中的声压表示为一组独立函数的线性组合 ,这样根据声场中声压分布就可以求解细长柱状声源的声辐射逆问题 文中运用无限长脉动圆柱算例进行了验算 结果证明 ,本文进行的探讨是可行的     

Micelles Formed by Cylindrical Brush‐Coil Block Copolymers

Summary: Amphiphilic cylindrical brush‐coil block copolymers consisting of a polystyrene coil and a cylindrical brush block with poly(acrylic acid) side chains are prepared by ATRP of t‐butylacrylate from a block comacroinitiator. Upon acidolysis of the poly(t‐butylacrylate), water‐soluble polymers were obtained that were observed to form micelles consisting of 4–5 block copolymers on average in aqueous solution. The star‐like nature of such micelles was clearly visualized by scanning force microscopy.

Schematic of coil‐cylindrical brush block copolymer PS‐b‐(PⁱBEMA‐g‐PAA), its AFM image clearly showing the main chain and the PAA corona of the cylindrical brush block.     

Analytical solution of radiation sound pressure of double cylindrical shells in fluid medium

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复合材料层合剪切圆柱曲板在侧压作用下的后屈曲

基于Reddy高阶剪切变形理论的Kármám-Donnell型非线性壳体方程,给出复合材料层合剪切圆柱曲板在侧压作用下的后屈曲分析。将壳体屈曲的边界层理论推广到复合材料层合剪切圆柱曲板受侧压作用的情况。相应的奇异摄动法,用于确定圆柱曲板的屈曲荷载和后屈曲平衡路径。分析中同时考虑非线性前屈曲变形和初始几何缺陷的影响。数值算例给出完善和非完善,中等厚度正交铺设层合圆柱曲板的后屈曲荷载-挠度曲线。讨论了横向剪切变形,曲板几何参数,铺层数,铺展方式和初始几何缺陷等各种参数变化的影响。     

Polar Oscillation of Interface and Surface Optical Phonons in Free-Standing Cylindrical Quantum-Well Wires

Under dielectric continuum approximation, interface optical (IO) and surface optical (SO) phonon modes as well as the corresponding Fro^ehlich electron-phonon interaction Hamiltonian in a free-standing cylindrical quantum-well wire (QWW) are derived and studied. Numerical calculations on GaAs/AlzGa1-x As cylindrical QWW are performed. Results reveal that there are two branches of IO phonon modes and one branch of SO phonon mode, and the dispersion frequencies of IO or SO phonon modes sensitively depend on the Al mole fraction x in AlzGa1-x As material and the wavevector in z direction, kz. With the increasing of kz and quantum number m, the frequency of each IO mode approaches one of the two frequency values of the single GaAs/AlxGa1-x As heterostructure, and the electrostatic potential distribution of the phonon mode tends to be more and more localized at a certain interface or surface, meanwhile, the coupling between the electron-IO and -SO phonons becomes weaker.     

大挠度圆柱壳在温度场中的热弹耦合振动分析

对温度场与与应力场耦合时的圆柱壳的非线性热弹耦合的振动问题,推导得到了基本的振动方程,热传导方程和协调方程,对短圆柱壳运用伽辽金(Galerkin)法求解,得出振幅随时间变化的数值解,得到一些有价值的结论．即随着温度幅值和耦合系数的增大,振动衰减的速度变缓,热弹耦合效应减弱．随着长径比、长厚比的增大,振幅衰减的速度变快,同时热振动频率也随之增大,即热弹耦合效应增强．耦合系数越大,轴向应力、轴向力以及轴向弯矩越小．     

圆棒介质波导的电磁波传播特性

通过简单的数学分析,推导圆棒介质波导的导模传播条件及特征方程,讨论电磁波在圆棒介质波导中的传播特性。