全文获取类型
收费全文 | 6270篇 |
免费 | 491篇 |
国内免费 | 711篇 |
专业分类
化学 | 2834篇 |
晶体学 | 28篇 |
力学 | 872篇 |
综合类 | 58篇 |
数学 | 659篇 |
物理学 | 370篇 |
综合类 | 2651篇 |
出版年
2024年 | 18篇 |
2023年 | 89篇 |
2022年 | 141篇 |
2021年 | 176篇 |
2020年 | 199篇 |
2019年 | 197篇 |
2018年 | 156篇 |
2017年 | 202篇 |
2016年 | 240篇 |
2015年 | 218篇 |
2014年 | 304篇 |
2013年 | 348篇 |
2012年 | 282篇 |
2011年 | 357篇 |
2010年 | 254篇 |
2009年 | 361篇 |
2008年 | 311篇 |
2007年 | 401篇 |
2006年 | 393篇 |
2005年 | 348篇 |
2004年 | 329篇 |
2003年 | 346篇 |
2002年 | 213篇 |
2001年 | 184篇 |
2000年 | 165篇 |
1999年 | 157篇 |
1998年 | 151篇 |
1997年 | 162篇 |
1996年 | 118篇 |
1995年 | 124篇 |
1994年 | 110篇 |
1993年 | 73篇 |
1992年 | 67篇 |
1991年 | 62篇 |
1990年 | 63篇 |
1989年 | 45篇 |
1988年 | 32篇 |
1987年 | 24篇 |
1986年 | 15篇 |
1985年 | 9篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 7篇 |
1981年 | 2篇 |
1979年 | 5篇 |
1972年 | 3篇 |
1971年 | 1篇 |
1957年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有7472条查询结果,搜索用时 593 毫秒
11.
Kurt Majewski 《Queueing Systems》2005,50(2-3):199-230
We consider multiclass feedforward queueing networks under first in first out and priority service disciplines driven by long-range dependent arrival and service time processes. We show that in critical loading the normalized workload, queue length and sojourn time processes can converge to a multi-dimensional reflected fractional Brownian motion. This weak heavy traffic approximation is deduced from a deterministic pathwise approximation of the network behavior close to constant critical load in terms of the solution of a Skorokhod problem. Since we model the doubly infinite time interval, our results directly cover the stationary case.AMS subject classification: primary 90B15, secondary 60K25, 68M20 相似文献
12.
Hans R. Kricheldorf Lali Vakhtangishvili Gert Schwarz 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5725-5735
Poly(pyridine ether)s were prepared in two ways: the polycondensation of silylated 1,1,1‐tris(4‐hydroxyphenyl)ethane (THPE) with 2,6‐difluoropyridine (method A) and the polycondensation of free THPE with 2,6‐dichloropyridine (method B). With method A, the THPE/difluoropyridine feed ratio was varied from 1.0:1.0 to 1.0:1.6. Cycles, bicycles, and multicycles were the main reaction products, and crosslinking was never observed. When ideal stoichiometry was used exclusively, multicycles free of functional groups were obtained. These multicycles were detectable in matrix‐assisted laser desorption/ionization time‐of‐flight (MALDI‐TOF) mass spectra up to B38C76 with a mass of approximately 32,000 Da. With method B, the reaction conditions were varied at a fixed feed ratio to achieve an optimum for the preparation of multicyclic polyethers, but because of the lower reactivity of 2,6‐dichloropyridine, a quantitative conversion was not achieved. The reaction products were characterized with MALDI‐TOF mass spectrometry, viscosity measurements, and size exclusion chromatography. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5725–5735, 2004 相似文献
13.
Introduction In the previous studies on the oxidation reaction,peroxydisulfate was widely used as an oxidizingagent.1-5 One of the advantages of this oxidant lies in itsstability in a wide range of pH values. The reaction be-tween Fe(CN)5L3- (L=N-aromatic heterocyclic li-gands) and S2O8 2- has been proved to proceed throughan outer-sphere electron transfer mechanism.5 For a re-action [(Eq. (1)] to be under an outer-sphere mechanismthe steps involved are the formation of a reactant … 相似文献
14.
Jérôme Le NôtreAna Acosta Martinez Pierre H DixneufChristian Bruneau 《Tetrahedron》2003,59(47):9425-9432
Enyne rearrangement of silylated modified terpenoids has been used as the key step for the synthesis of new terpenes and terpenoids. The catalytic system generated in situ from [RuCl2(p-cymene]2, 1,3-bis(mesityl)imidazolinium chloride and cesium carbonate is able to perform the transformation of silylated 1,7-enynes into cyclic siloxanes. Selective cleavage of the silicon-carbon and silicon-oxygen bonds by simple reactions has been performed to afford new terpenes and terpenoids by formal addition of a C5 unit. 相似文献
15.
Tsonka Stefanova Baicheva 《Designs, Codes and Cryptography》1998,13(3):223-227
The covering radius of all ternary cyclic codes of length up to 25 is given. Some of the results were obtained by computer
and for others mathematical reasonings were applied. The minimal distances of all codes were recalculated. 相似文献
16.
研究了环氧乙烷与四氢呋喃的共聚.使用BF_3络合物为催化剂,1,4-丁二醇为共催化剂.找到了溶液聚合和本体聚合适宜的工艺条件.在此条件下,环齐聚物的生成量为8%左右.找到了方便易行的纯化方法,通过纯化可把聚醚的环齐聚物含量降到1%以下,有效地提高了产品的质量。 相似文献
17.
In this paper we describe the design and manufacture of an axial-torsion test specimen, and provide relationships needed when
conducting stress-strain characterization experiments with the specimen. The specimen is a short hollow cylinder of rubber
bonded between two steel mounting rings, in which simultaneous axial and shear strains are produced via independently controlled
axial and twist displacements. We present calculations for the strain-displacement and stress-load relationships, and strain
energy density. These relationships have been established and validated via a combination of analytical and experimental techniques,
and finite element analysis. We have investigated the extent and effects of strain and stress field non-uniformity in the
test specimen. The specimen design is sufficiently simple that a closed-form expression for the strain-displacement relationship
has been successfully developed. 相似文献
18.
用边界积分方法分析了表面裂纹在接触载荷作用下的张开位移和应力强度因子,该方法将埋在无穷大弹性介质中裂纹模拟为连续分布的位错环,根据两个位错环之间的相互作用能可以得到弹性体的应变能,对弹性体的势能取极值,可以得到关于裂纹张开位移的边界积分方程,通过把半空间的边界模拟成一个包含在无穷大弹性介质中大裂纹,该方法能用已有的边界积分方法很好的处理具有任意表面形状的表面裂纹,文中算例分析了不同倾角的表面裂纹在法向和切向接触载荷作用下,裂纹尖端的应力强度因子,其结果对于分析路面表面裂纹的扩展具有重要意义。 相似文献
19.
20.
In this article, a kind of auxiliary design BSA* for constructing BSAs is introduced and studied. Two powerful recursive constructions on BSAs from 3‐IGDDs and BSA*s are exploited. Finally, the necessary and sufficient conditions for the existence of a BSA(v, 3, λ; α) with α = 2, 3 are established. © 2006 Wiley Periodicals, Inc. J Combin Designs 15: 61–76, 2007 相似文献