全文获取类型
收费全文 | 28022篇 |
免费 | 3663篇 |
国内免费 | 2949篇 |
专业分类
化学 | 9848篇 |
晶体学 | 287篇 |
力学 | 2531篇 |
综合类 | 193篇 |
数学 | 2684篇 |
物理学 | 8076篇 |
综合类 | 11015篇 |
出版年
2024年 | 107篇 |
2023年 | 324篇 |
2022年 | 685篇 |
2021年 | 645篇 |
2020年 | 848篇 |
2019年 | 749篇 |
2018年 | 780篇 |
2017年 | 907篇 |
2016年 | 1064篇 |
2015年 | 1068篇 |
2014年 | 1454篇 |
2013年 | 2125篇 |
2012年 | 1733篇 |
2011年 | 1675篇 |
2010年 | 1315篇 |
2009年 | 1510篇 |
2008年 | 1464篇 |
2007年 | 1759篇 |
2006年 | 1625篇 |
2005年 | 1397篇 |
2004年 | 1307篇 |
2003年 | 1216篇 |
2002年 | 1031篇 |
2001年 | 967篇 |
2000年 | 940篇 |
1999年 | 767篇 |
1998年 | 700篇 |
1997年 | 606篇 |
1996年 | 542篇 |
1995年 | 486篇 |
1994年 | 477篇 |
1993年 | 407篇 |
1992年 | 355篇 |
1991年 | 304篇 |
1990年 | 255篇 |
1989年 | 245篇 |
1988年 | 232篇 |
1987年 | 146篇 |
1986年 | 104篇 |
1985年 | 62篇 |
1984年 | 51篇 |
1983年 | 19篇 |
1982年 | 46篇 |
1981年 | 23篇 |
1980年 | 21篇 |
1979年 | 19篇 |
1978年 | 24篇 |
1977年 | 8篇 |
1976年 | 7篇 |
1973年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 11 毫秒
51.
The formation of the identical slope surface and the method of construction are discussed. On the basement of building the
parameter equation of variable-radius circle family envelope, the frequently used parameter equation of the identical slope
surface of the top of taper moving along column helix, horizental arc and line is built. The equation can be used to construct
the identical slope surface’s contours, gradient lines and three dimensional figures correctly.
Biography: Hu Jian-guo(1953-), male, Professor, research direction: CG and CAD. 相似文献
52.
The period economic fluctuation is vital for an enterprise to exist and further develop,it directly affect the enterprise financial health.So,it is significant to build up financial early-warning index and measure the warning condition that the enterprise faces and take the effective measures to eliminate. We criticize Altman's Z calculating model and build up some new indexes for enterprise financial early-warning condition measuring and making sound decision. 相似文献
53.
A numerical technique is developed for the simulation of free surface flows and interfaces. This technique combines the strength on the finite element method (FEM) in calculating the field variables for a deforming boundary and the versatility of the volume-of-fluid (VOF) technique in advection of the fluid interfaces. The advantage of the VOF technique is that it allows the simulation of interfaces with large deformations, including surface merging and breaking. However, its disadantage is that is solving the flow equations, it cannot resolve interfaces smaller than the cell size, since information on the subgrid scale is lost. Therefore the accuracy of the interface reconstruction and the treatment of the boundary conditions (i.e. viscous stresses and surface tension forces) become grid-size-dependent. On the other hand, the FEM with deforming interface mesh allows accurate implementation of the boundary conditions, but it cannot handle large surface deformations occurring in breaking and merging of liquid regions. Combining the two methods into a hybrid FEM-VOF method eliminates the major shortcomings of both. The outcome is a technique which can handle large surface deformations with accurate treatment of the boundary conditions. For illustration, two computational examples are presented, namely the instability and break-up of a capillary jet and the coalescence collision of two liquid drops. 相似文献
54.
Yabin Zhou Shifeng Wang Yinxi Zhang Yong Zhang 《Journal of Polymer Science.Polymer Physics》2006,44(8):1226-1236
Methacrylic acid (MAA) was used as in situ surface modifier to improve the interface interaction between nano‐CaCO3 particle and ethylene–propylene–diene monomer (EPDM) matrix, and hence the mechanical properties of nano‐CaCO3‐filled EPDM vulcanizates. The results showed that the incorporation of MAA improved the filler–matrix interaction, which was proved by Fourier transformation infrared spectrometer (FTIR), Kraus equation, crosslink density determination, and scanning electron microscope (SEM). The formation of carboxylate and the participation of MAA in the crosslinking of EPDM indicated the strong filler–matrix interaction from the aspect of chemical reaction. The results of Kraus equation showed that the presence of MAA enhanced the reinforcement extent of nano‐CaCO3 on EPDM vulcanizates. Crosslink density determination proved the formation of the ionic crosslinks in EPDM vulcanizates with the existence of MAA. The filler particles on tensile fracture were embedded in the matrix and could not be observed obviously, indicating that a strong interfacial interaction between the filler and the matrix had been achieved with the incorporation of MAA. Meanwhile, the presence of MAA remarkably increased the modulus and tensile strength of the vulcanizates, without negative effect on the high elongation at break. Furthermore, the ionic bond was thought to be formed only on filler surface because of the absolute deficiency of MAA, which resulted in the possible structure where filler particles were considered as crosslink points. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1226–1236, 2006 相似文献
55.
The growth rate of isotactic polypropylene is deduced from microscopic observations during isothermal crystallizations. A change in the growth regime is observed at 138 C and interpreted as a Regime III Regime II transition, according to Hoffman's kinetic theory of polymer crystallization. A Regime II Regime I transition is also theoretically predicted at 155 C, i. e. at a temperature outside the investigated temperature range. The Regime III Regime II transition is related to the positive to negative change in the spherulite birefringence, which is generally attributed to a change in the organization of crystalline lamellae: quadritic arrays of intercrossing lamellae atT
c < 138 C (Regime III) and preferentially radiating lamellae atT
c > 138 C (Regime II). It is suggested that such a morphological change could be interpreted using the concept of non-adjacent re-entry introduced in Hoffman's kinetic theory. This interpretation could also explain the interspherulitic ruptures observed in negative spherulites. 相似文献
56.
Shujun Su 《Journal of Molecular Structure》1998,430(1-3):137-148
The potential energy hypersurface of the ground triplet states of the BNO-BON-NBO system has been investigated using traditional ab initio electronic structure theory. The molecules studied have the molecular formula BON and include three linear and three angular species, and two transition states for the isomerization of an angular N-B-O to an angular B-O-N and a linear B-NO, respectively. All stationary points on the BNO-BON-NBO isomerization potential energy surface have been characterized employing UMP2, UMP4, and Gaussian-2 (G2) theory with the 6-311G(d), 6-311G(2d), and TZ2P basis sets. The isomerization for an angular N-BO to the linear B-NO has a lower energy barrier than that of the former to an angular B-ON. Energetics are presented with G2 energies. Two sets of resonance structures for both bent B-NO (boron nitrosyl) and B-ON (boron isonitrosyl) were proposed and the bonding in the two species was analyzed. For the purpose of comparison, the density functional theory based hybrid methods B3LYP/6-311G(d) and B3LYP/TZ2P have also been applied to both geometry optimization and single-point calculations. It is found that the B3LYP prediction of the nature of the linear B-O is contradictory to that made by all MPn(n = 2 and 4) calculations. The cause for this contradiction is discussed. 相似文献
57.
E. U. Franck 《Journal of solution chemistry》1973,2(2-3):339-356
A survey is given of recent experimental results obtained from high-temperature, high-pressure investigations with water, aqueous solutions, and ionic fluids. Data on the static dielectric constant of water to 550°C and 5 kbar are given and discussed with respect to their relation to water structure. Infrared and Raman spectra of HDO in pure water have been obtained to 400°C and 4 kbar, which give information on hydrogen bonding. Xe–H2O and CO2–H2O mixtures were investigated in the infrared. Ni(II) and Cu(II) complexes were investigated by absorption spectroscopy in aqueous solutions of high chloride content to 350°C and 2–6 kbar. The gas-liquid critical point of ammonium chloride was found at 880°C and 1635 bars. This fluid appears to be predominantly ionic even in the critical region. The possibility of converting pure polar fluids such as ammonia and water into concentrated ionic solutions by self-ionization at very high pressures is mentioned.This paper was presented at the symposium, The Physical Chemistry of Aqueous Systems, held at the University of Pittsburgh, Pittsburgh, Pennsylvania, June 12–14, 1972, in honor of the 70th birthday of Professor H. S. Frank. 相似文献
58.
M. Paluch 《Colloid and polymer science》1998,276(7):648-652
The results of experimental studies of the adsorption at the solution/air interface from an aqueous mixture: 2,4,6-trimethylphenol–2,4,6-trichlorophenol
are presented. The surface properties of the above-mentioned mixture were studied by surface potential and surface tension
measurements. These measurements were carried out as a function of the concentration of 2,4,6-trimethylphenol aqueous solution
at a constant concentration of 2,4,6-trichlorophenol.
Using the results obtained and based on the Gibbs equation, Helmholtz formula and Motomura’s method the relative surface excesses
of adsorbed substances, effective dipole moments, surface molar fractions of solutes and miscibility of adsorbed films were
determined.
Received: 7 November 1997 Accepted: 26 February 1998 相似文献
59.
研究Kirchhoff型Schrödinger-Bopp-Podolsky系统,考虑位势函数V不定的情况。此时Schrödinger算子-Δ+V具有有限维负空间。利用Morse理论,得到Kirchhoff型Schrödinger-Bopp-Podolsky系统非平凡解的存在性。 相似文献
60.
为增强系统的稳定性,基于智能反射面(intelligent reflection surface,IRS)辅助安全通信,为用户采用功率分配架构的无线携能传输(simultaneous wireless information and power transfer,SWIPT)技术以提高用户安全速率并降低用户的能量消耗,建立了系统安全速率最大化的目标函数模型;考虑IRS相移约束、基站最大发射功率、功率分配比率约束和用户最低能量采集约束,提出了一种基于交替优化的安全速率最大化算法。利用连续凸近似算法,将目标函数转化为凸的形式;采用交替优化,对耦合变量进行解耦处理;提出一种波束赋形算法以实现安全速率最大化。仿真表明,提出的算法能够有效提升IRS辅助的SWIPT系统的安全速率,至少比其他算法提高了2.63bps/Hz。 相似文献