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91.
在单粒子势模型的框架下,通过在核中心势中引入l2修正项(l表示核子的轨道角动量),计算了A=11同质异位素核的均方根半径值、能级值和密度分布.理论计算得到的半径值和能级结构与实验结果一致.特别是,理论计算能够同时实现镜像核11Be和11N中251/2-1p1/2能级间的反转,从而解释了11Be和11N的反常的自旋宇称值... 相似文献
92.
用冷冻升华法制备了浓度为1×10-4 和2×10-5 g/mL的单链无规聚苯乙烯(a-PS). 利用FTIR测试方法, 测定a-PS在等温处理时红外吸收峰的时间依赖性与温度依赖性, 研究样品中链缠结和链结构单元的堆积等因素对红外吸收峰的影响, 进而探讨链缠结对a-PS分子运动的影响. 同时, 也通过二维相关分析来研究a-PS等温实验过程中, 链缠结的变化情况以及官能团之间的变化顺序, 推断在a-PS等温时, 与链结构单元的堆积相联系的苯环振动首先发生, 其次才是与链缠结相关联的CH2振动发生变化, 并由此确定缠结对冷冻升华a-PS分子运动的影响. 相似文献
93.
l,l′-dimethylferricinium (DMFe+),a stable and pH-insensitive blue dye, was prepared via enzymatic oxidation of a 1,1′-dimethylferrocene (DMFe):2-hydroxypropyl-β-cyclodextrin
(HPCD) watersoluble inclusion complex, using bilirubin oxidase immobilized onto porous aminopropyl glass beads via glutaraldehyde
activation. In the presence of glucose, DMFe+ was reduced to DMFe by reacting with the reduced glucose oxidase (FADH2), and the absorbance decrease was followed at 650 nm. In acetate pH 5.2 buffer, the response to glucose in blood serum was
nonlinear, especially in the low concentration range, because of a competition for the reduced glucose oxidase between the
DMFe+ dye and oxygen. At this pH, endogenous ceruloplasmin was also observed to oxidize residual DMFe (16%) in the dye preparation,
causing an increase in absorbance at 650 nm. An assay protocol was then developed using maleate buffer, pH 6.5, to overcome
these interferences as well as mutarotation of α-D-glucose. The results obtained for glucose in the blood serum samples agreed
well with those of the reference hexokinase/glucose-6-phosphate dehydrogenase method. 相似文献
94.
95.
Filiz Taneri Tamer Güneri Zolt%aacute;n Aigner Michael Kata 《Journal of inclusion phenomena and macrocyclic chemistry》2002,44(1-4):257-260
Highly-soluble cyclodextrin derivatives, such as hydroxypropyl--cyclodextrin(HP--CD) and methyl--cyclodextrin (MEB), were tested as solubilizingagents for ketoconazole, with the aim of improving the physicochemical andbiopharmaceutical properties of this lipophilic imidazole antifungal agent. Productswere prepared in four molecular ratios by physical mixing, kneading and spray-dryingmethods. The kneaded products in a ratio of 1:2 and the spray-dried products exhibitedthe highest dissolution rates. The phase solubility diagrams of ketoconazole with thesecyclodextrins at 25 °C in water and in simulated intestinal medium wereconstructed. A solubility diagram of AL type was obtained with HP--CD, and one of AP type with MEB. The complexes were characterized by thermal methods(DSC, TG, DTG and DTA). Multicomponent systems were prepared with tartaric acid.The effects of water-soluble polymers, e.g., polyvinylpyrrolidone, on the aqueous solubility of ketoconazole were investigated. Particle size distribution, surface area, partition coefficient, heat of dissolution and wettability studies were also carried out. The formation of inclusion complexes was observed by means of thermoanalytical studies. 相似文献
96.
采用放射性同位素198Au示踪法研究了伯胺N1923和TBP从碱性氰化液中萃取金(Ⅰ),考察了酸化率、水相pH值、萃取剂浓度等对萃取率的影响,以及NaOH对载金有机相的反萃作用。结果表明,TBP含量大于20%,酸化的N1923与KAu(CN)2摩尔比值在1:1时,金能够完全被萃取。载金有机相可采用0.lmol·L-1的Na0H溶液定量反萃。机理研究表明,伯胺和TBP萃取Au(CN)2-,符合BC类协同萃取机理。当金浓度大于10g·L-1时,在萃取有机相中形成纳米级的聚集体。 相似文献
97.
1,5-二(2-羟基苯亚甲基)-二氨基硫脲与银配合物的合成、表征及抗癌活性研究 总被引:9,自引:0,他引:9
近年来,由于缩氨基硫脲类过渡金属配合物具有较高的抗癌、抗菌活性,受到化学界和药学界研究人员的广泛重视。实验证明不同缩氨基硫脲与不同过渡金属形成的配合物其抗癌活性不同。1,5-二(2-羟基苯亚甲基)-二氨基硫脲是一种水杨醛缩氨基硫脲类衍生物,而有关其银配合物的合成及抗肿瘤方面的研究目前尚未见报道。鉴于此,我们在以前工作的基础上合成了标题化合物,通过元素分析、红外光谱、紫外光谱、核磁共振氢谱、摩尔电导和溶解性等测试,对配合物进行了表征。同时测定了配体和配合物的抗肿瘤活性,旨在为开发新的抗肿瘤药物提供理论依据。 相似文献
98.
Let R be a ring with involution *. We consider R as a ring equipped with a new product r s = rs + sr*. The relationship between (ordinary) ideals of R and right ideals of R with respect to the product is studied.AMS Subject Classification (2000): 16W10, 16D25 相似文献
99.
Miscible blends of poly(ethylene oxide) with brush copolymers of poly(vinyl alcohol)‐graft‐poly(l‐lactide)
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Ainhoa Lejardi Jose‐Ramon Sarasua Agustin Etxeberria Emilio Meaurio 《Journal of Polymer Science.Polymer Physics》2016,54(13):1217-1226
Even though poly(ethylene oxide) (PEO) is immiscible with both poly(l ‐lactide) (PLLA) and poly(vinyl alcohol) (PVA), this article shows a working route to obtain miscible blends based on these polymers. The miscibility of these polymers has been analyzed using the solubility parameter approach to choose the proper ratios of the constituents of the blend. Then, PVA has been grafted with l ‐lactide (LLA) through ring‐opening polymerization to obtain a poly(vinyl alcohol)‐graft‐poly(l ‐lactide) (PVA‐g‐PLLA) brush copolymer with 82 mol % LLA according to 1H and 13C NMR spectroscopies. PEO has been blended with the PVA‐g‐PLLA brush copolymer and the miscibility of the system has been analyzed by DSC, FTIR, OM, and SEM. The particular architecture of the blends results in DSC traces lacking clearly distinguishable glass transitions that have been explained considering self‐concentration effects (Lodge and McLeish) and the associated concentration fluctuations. Fortunately, the FTIR analysis is conclusive regarding the miscibility and the specific interactions in these systems. Melting point depression analysis suggests that interactions of intermediate strength and PLOM and SEM reveal homogeneous morphologies for the PEO/PVA‐g‐PLLA blends. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1217–1226 相似文献
100.
邓巧玲 《无锡职业技术学院学报》2012,(2):60-62
合作性学习是一种利用小团队进行学习的教学方法,学生们一起学习使每个人的成绩尽可能地得到提高。合作性学习能让学生之间形成彼此忠诚的关系,实现真正的积极合作,为成功而更加努力地工作,从而使学生的合作能力,沟通能力和口语表达能力得到提高。 相似文献