Rational Design of Microporous MOFs with Anionic Boron Cluster Functionality and Cooperative Dihydrogen Binding Sites for Highly Selective Capture of Acetylene

Separation of acetylene (C₂H₂) from carbon dioxide (CO₂) or ethylene (C₂H₄) is important in industry but limited by the low capacity and selectivity owing to their similar molecular sizes and physical properties. Herein, we report two novel dodecaborate‐hybrid metal–organic frameworks, MB₁₂H₁₂(dpb)₂ (termed as BSF‐3 and BSF‐3‐Co for M=Cu and Co), for highly selective capture of C₂H₂. The high C₂H₂ capacity and remarkable C₂H₂/CO₂ selectivity resulted from the unique anionic boron cluster functionality as well as the suitable pore size with cooperative proton‐hydride dihydrogen bonding sites (B?H^δ????H^δ+?C≡C?H^δ+???H^δ??B). This new type of C₂H₂‐specific functional sites represents a fresh paradigm distinct from those in previous leading materials based on open metal sites, strong electrostatics, or hydrogen bonding.     

Enhancement of Ion Pairing of Sr(II) and Ba(II) Salts by a Tritopic Ion-Pair Receptor in Solution

Tritopic ion-pair receptors can bind bivalent salts in solution; yet, these salts have a tendency to form ion-pairs even in the absence of receptors. The extent to which such receptors can enhance ion pairing has however remained elusive. Here, we study ion pairing of M²⁺ (Ba²⁺, Sr²⁺) and X⁻ (I⁻, ClO₄⁻) in acetonitrile with and without a dichlorooxacalix[2]arene[2]triazine-related receptor containing a pentaethylene-glycol moiety. We find marked ion association already in receptor-free solutions. When present, most of the MX⁺ ion-pairs are bound to the receptor and the overall degree of ion association is enhanced due to coordinative, hydrogen-bonding, and anion-π interactions. The receptor shows higher selectivity for iodides but also stabilizes perchlorates, despite the latter are often considered as weakly coordinating anions. Our results show that ion-pair binding is strongly correlated to ion pairing in these solutions, thereby highlighting the importance of taking ion association in organic solvents into account.     

Predictable site-selective radical fluorination of tertiary ethers

In this communication,we disclose the first example of metal-free and site-selective radical fluorination of readily available tertiary alkyl ethers,enabled by synergistic photocatalysis and organocatalysis.This catalytic combination allows for exclusive fluorination of tertiary C–O bonds under mild conditions even in the presence of competing reaction sites.The excellent functional group tolerance affords valuable access to sterically hindered alkyl fluorides through late-stage modification of complex molecules.The successful use of tertiary alkyl ethers in radical fluorination enhances the structural diversity of aliphatic fluorides that can be derived from naturally abundant alcohols.     

全分集协作系统C-HARQ方案的设计及性能

为了进一步提高全分集协作(FDC)系统的可靠性和有效性,提出了两种协作混合自动请求重传(C-HARQ)方案.定长帧协作混合重传(FFC-HARQ)方案在不改变全分集协作系统原有帧结构的基础上,使用一定的检错重传策略提高系统吞吐量;变长帧协作混合重传(VFC-HARQ)方案则改变原有帧结构,进一步提高系统吞吐量.利用马尔...     

n斑块内非自治L-V互惠扩散系统的概周期解和全局稳定性

考虑在n个斑块中,两个互惠物种的非自治L-V模型,并且两个物种中每个物种都能在自己的斑块内部和外部独立地扩散,利用构造Liapunov函数,在适当的条件下得到了该系统存在唯一一个全局渐近稳定的概周期解,推广了已有的结果.     

一种CSCD系统的角色委托授权模型

结合计算机支持的协同设计(CSCD)系统的具体特点,对角色委托授权(RDA)特征进行分析和归纳,并给出CSCD系统的RDA特征集表示·由于不同系统具有不同的RDA特征集,导致不同系统的RDA模型也具有各种不同形态·在介绍RBAC基本模型的基础上,归纳出几种基本的RDA特征,并根据CSCD系统的具体特点对RDA特征进行组合,从而建立起适合CSCD系统的RDA模型·与传统的RBAC角色授权模式不同,该模型将权限的集中方式管理分散实施,使权限管理更加灵活方便·最后通过CSCD系统实例对上述RDA模型进行了验证·     

具有饱和项的互惠系统的分歧与稳定性

运用谱分析和分歧理论的方法,在齐次Dirichlet边界条件下,对具有饱和项的互惠系统的非负定态解的分歧及其稳定性进行研究.一方面,分别以生长率作为分歧参数,讨论了发自半平凡解的分歧;另一方面,以两物种的生长率作为分歧参数,利用Liapunov-Schmidt过程,研究了在二重特征值处的分歧;同时判定了这些分歧解的稳定性.     

电动车I-AMT挡位切换电机-离合器协同控制

纯电动汽车匹配两挡变速箱能够改善整车动力性和经济性,由于其具有结构精简和无动力中断的优越性,因此高挡位摩擦离合器与低挡位单向离合器组合的传动构型成为电动汽车两档变速器的主流方案。然而,车辆在倒挡行驶时,需要挂入牙嵌离合器才能克服单向离合器只能传递单方向扭矩的问题。本文以一款基于牙嵌式离合器的新型无动力中断两挡自动变速器（I-AMT）为研究对象,协同控制驱动电机和倒挡执行机构电机使牙嵌式离合器平稳快速结合。针对驱动电机系统响应延时问题,使用史密斯预估器算法对控制系统进行预估补偿,并通过实验对控制策略进行验证。结果表明,该控制策略可有效避免牙嵌式离合器挂入时的冲击,保证了变速器可在短时间内在各个挡位之间平顺切换。     

多agent协同强化学习算法SE-MACOL及其应用

针对多agent团队中各成员之间是协作关系且自主决策的学习模型,在此对Q学习算法进行了适当扩充,提出了适合于多agent团队的一种共享经验元组的多agent协同强化学习算法。其中采用新的状态行为的知识表示方法,采用相似性变换和经验元组的共享,能够提高多agent团队协同工作的效率。最后将该算法应用于猎人捕物问题域,实验结果表明该算法能够明显加快多个猎人合作抓捕猎物的进程。     

广域保护系统研究

随着计算机技术和通信技术的发展,基于广域测量系统的广域保护技术不断发展。文章讨论了广域保护的概念以及与传统继电保护的区别、广域保护系统的结构和功能、通信网络的配置以及广域保护的应用前景,尤其是在自适应保护中的应用。基于广域测量系统的广域保护对级联跳闸将起到免疫作用,对电力系统的安全稳定运行有重要的意义。