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11.
本文根据两步递归插补的思想,导出了任意三维椭圆弧高速插补的公式和算法.它是空间圆弧高速插补方法在三维椭圆弧的情况下进一步推广应用.本文最后还对插补算法进行了稳定性分析和误差分析. 相似文献
12.
Franck D'Agosto Marie‐Thrse Charreyre Christian Pichot Robert G. Gilbert 《Journal of polymer science. Part A, Polymer chemistry》2003,41(9):1188-1195
A method is described for synthesizing latex particles with anchored hairs by the grafting of hydrophilic chains, synthesized by reversible addition–fragmentation chain transfer, onto functionalized latex particles. These have the potential to bind biologically active species. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1188–1195, 2003 相似文献
13.
校园网终端网络节点自治性的探讨 总被引:1,自引:0,他引:1
讨论了校园网终端网络节点自治性的建设,给出了开通另一通信出口,电子邮局及实时在线通信等问题的设计与实现的方法,并指出终端网络节点信息化建设的优劣决定校园网的网络性能。 相似文献
14.
Md. Nur Alam Per B. Zetterlund Masayoshi Okubo 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4995-5004
Bimolecular termination in nitroxide‐mediated radical polymerization in miniemulsion has been investigated through the heating of a polystyrene–2,2,6,6‐tetramethylpiperidinyl‐1‐oxy macroinitiator and its 4‐hydroxy‐2,2,6,6‐tetramethylpiperidinyl‐1‐oxy analogue in an aqueous toluene dispersion with sodium dodecyl benzenesulfonate as a surfactant at 125 °C. The level of bimolecular termination by combination, evaluated from the high‐molecular‐weight shoulder, was higher in miniemulsion than in solution and increased with decreasing particle size. Quantitative analysis revealed that these results cannot be rationalized solely by nitroxide partitioning to the aqueous phase. The results are explained by an interface effect, by which nitroxide is adsorbed or located at the aqueous–organic interface. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4995–5004, 2007 相似文献
15.
Hiroshi Ito Masaki Okazaki Dolores C. Miller 《Journal of polymer science. Part A, Polymer chemistry》2004,42(6):1478-1505
Radical copolymerizations of electron‐deficient 2‐trifluoromethylacrylic (TFMA) monomers, such as 2‐trifluoromethylacrylic acid and t‐butyl 2‐trifluoromethylacrylate (TBTFMA), with electron‐rich norbornene derivatives and vinyl ethers with 2,2′‐azobisisobutyronitrile as the initiator were investigated in detail through the analysis of the kinetics in situ with 1H NMR and through the determination of the monomer reactivity ratios. The norbornene derivatives used in this study included bicyclo[2.2.1]hept‐2‐ene (norbornene) and 5‐(2‐trifluoromethyl‐1,1,1‐trifluoro‐2‐hydroxylpropyl)‐2‐norbornene. The vinyl ether monomers were ethyl vinyl ether, t‐butyl vinyl ether, and 3,4‐dihydro‐2‐H‐pyran. Vinylene carbonate was found to copolymerize with TBTFMA. Although none of the monomers underwent radical homopolymerization under normal conditions, they copolymerized readily, producing a copolymer containing 60–70 mol % TFMA. The copolymerization of the TFMA monomer with norbornenes and vinyl ethers deviated from the terminal model and could be described by the penultimate model. The copolymers of TFMA reported in this article were evaluated as chemical amplification resist polymers for the emerging field of 157‐nm lithography. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1478–1505, 2004 相似文献
16.
Xiao‐Hui Liu Yan‐Guo Li Ying Lin Yue‐Sheng Li 《Journal of polymer science. Part A, Polymer chemistry》2007,45(7):1272-1281
The reversible addition–fragmentation chain transfer (RAFT) polymerization of acrylonitrile (AN) mediated by 2‐cyanoprop‐2‐yl dithiobenzoate was first applied to synthesize polyacrylonitrile (PAN) with a high molecular weight up to 32,800 and a polydispersity index as low as 1.29. The key to success was ascribed to the optimization of the experimental conditions to increase the fragmentation reaction efficiency of the intermediate radical. In accordance with the atom transfer radical polymerization of AN, ethylene carbonate was also a better solvent candidate for providing higher controlled/living RAFT polymerization behaviors than dimethylformamide and dimethyl sulfoxide. The various experimental parameters, including the temperature, the molar ratio of dithiobenzoate to the initiator, the molar ratio of the monomer to dithiobenzoate, the monomer concentration, and the addition of the comonomer, were varied to improve the control of the molecular weight and polydispersity index. The molecular weights of PANs were validated by gel permeation chromatography along with a universal calibration procedure and intrinsic viscosity measurements. 1H NMR analysis confirmed the high chain‐end functionality of the resultant polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1272–1281, 2007 相似文献
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18.
多变量系统最小能量终端控制 总被引:1,自引:0,他引:1
刘轩黄 《华中师范大学学报(自然科学版)》2002,36(1):11-16
以广义逆矩阵的理论和Bellman最优性原理为基础,给出了MIMO系统的状态反馈型的闭型解,对最优终端控制问题作了进一步的详细研究,且通过具有零初始状态的线性定常系统的研究,导出了终端控制误差和控制能量与控制时间的关系。 相似文献
19.
张永清 《南京理工大学学报(自然科学版)》1994,(4)
该文介绍一种采用Motorola公司MC145146和MC12017/18蕊片构成的短波电台频率合成器的硬件电路实现方案。频率合成器的输出频率范围2~29.9999MHz,频率间隔100Hz,换频时间小于0.01s。文中论述了这种多环数字式频率合成器工作原理,各环路之间对应的频率关系和电路参数的选择,给出了频率合成器的试验结果. 相似文献
20.
对交通隧道防排水原则的探讨 总被引:3,自引:0,他引:3
从保护地下水环境和隧道防排水的技术经济效果两个方面,阐述了隧道工程控制型防排水的必然性和必要性,并建议了两种模型。 相似文献