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51.
为了进一步研究纳米导线阵列的排列形状以及阵列数目对其场发射行为的影响,利用镜像悬浮球模型对正方形以及六边形排列的纳米导线阵列的场发射行为进行计算与模拟,近似的得到纳米导线阵列的场发射增强因子满足如下的变化趋势:β=h/ρ(1/1+W)+1/2(1/1+W)2+3,其中h为纳米导线的高度,ρ为纳米导线的半径,W是以R为自变量的函数,R为纳米导线阵列的间距.结果显示纳米导线阵列的排列形状对其场发射性能的影响较小,而阵列间距则是影响场发射性能的关键因素:当R<R0时,场发射增强因子随着阵列间距的减小而急剧减小;当R>R0时,场发射增强因子基本不变,其中R0为导线阵列场发射的最佳间距.进一步研究表明改变纳米导线阵列的数目基本不会改变阵列的场发射性能随间距的变化趋势,但是随着阵列数目的增加,R0会有一定程度的减小,场发射增强因子也会降低.
关键词:
纳米导线
场发射
增强因子
阵列数目 相似文献
52.
Tenghao Yin Lei Wu Tonghao Wu Guoyong Mao Guodong Nian Zhe Chen Xiaocheng Hu Peng Wang Yuhai Xiang Honghui Yu Shaoxing Qu Wei Yang 《Journal of Polymer Science.Polymer Physics》2019,57(5):272-280
Conductive hydrogels with ionic compounds possess great potential for the development of soft smart devices. A dielectric scarfskin is typically required for these devices to prevent short circuiting, leading to devices with lower stretchability than the hydrogel. Henceforth, commonly used dielectric materials, such as PDMS and Ecoflex, cannot be largely stretched. Hydrogel devices with ultrastretchability are required to accommodate hostile application environments. Herein, we propose a hydrogel fiber coated with a dielectric layer that can be stretched to over 2000% of its initial length. The fiber remains conductive when stretched to ~1300%. In addition, the core/sheath hydrogel fiber can be endowed with a variety of functional properties, such as electroluminescence (EL), photoluminescence (PL), and magnetic‐responsiveness, demonstrating scalability of the resultant fiber. The present work can pave the way for numerous next‐generation soft devices, such as smart textiles and wearable electronics. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 272–280 相似文献
53.
Meng-Meng Zhao Lin Zhou Ping-Ping Shi Xuan Zheng Xiao-Gang Chen Ji-Xing Gao Lei He Prof. Dr. Qiong Ye Prof. Dr. Cai-Ming Liu Prof. Dr. Da-Wei Fu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(25):6447-6454
Organic–inorganic hybrid perovskite-type multiferroics have attracted considerable research interest owing to their fundamental scientific significance and promising technological applications in sensors and multiple-state memories. The recent achievements with divalent metal dicyanamide compounds revealed such malleable frameworks as a unique platform for developing novel functional materials. Herein, two 3D organic–inorganic hybrid perovskites [Et3P(CH2)2F][Mn(dca)3] ( 1 ) and [Et3P(CH2)2Cl][Mn(dca)3] ( 2 ) (dca=dicyanamide, N(CN)2−) are presented. Accompanying the sequential phase transitions, they display a broad range of intriguing physical properties, including above room temperature ferroelastic behavior, switchable dielectricity, and low-temperature antiferromagnetic ordering (Tc=2.4 K for both 1 and 2 ). It is also worth noting that the spontaneous strain value of 1 is far beyond that of 2 in the first ferroelastic phase, as a result of the precise halogen substitution. From the point view of molecular design, this work should inspire further exploration of multifunctional molecular materials with desirable properties. 相似文献
54.
Porous carbon nanospheres with moderately oriented microcrystalline structures were prepared via a relatively simple synthetic route in this article. CTAB acted as a structure‐directing agent to induce small sulfonated pitch (SP) pieces to assemble orderly. By this means, the formation of carbon nanospheres was simultaneous with the moderate orientation of carbon microcrystalline without additional process. Owing to the moderately oriented microcrystalline structures, the resultant sample CNS3 possessed a high e‐conductivity of 62.5 S/m. When used as an electrode material for EDLCs, it showed excellent electrochemical properties even without any conductive agent. In an organic electrolyte, the resultant sample CNS3 possessed a high specific capacitance of 155 F/g at 20 A/g and outstanding cycle life with 94.2% capacity retention after 10,000 cycles. This work puts forward a novel design for carbon nanospheres with moderately oriented domains by a simple and energy‐efficient means. 相似文献
55.
Prof. Dr. Qian Miao Dr. Farzaneh Rouhani Dr. Hamed Moghanni-Bavil-Olyaei Dr. Kuan-Guan Liu Xue-Mei Gao Jing-Zhe Li Xiu-De Hu Prof. Dr. Zhi-Min Jin Prof. Mao-Lin Hu Prof. Ali Morsali 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(43):9518-9526
As redox-active based supercapacitors are known as highly desirable next-generation supercapacitor electrodes, the targeted design of two ferrocene-functionalized (Fc(COOH)2) clusters based on coinage metals, [(PPh3)2AgO2CFcCO2Ag(PPh3)2]2 ⋅ 7 CH3OH (SC1: super capacitor) and [(PPh3)3CuO2CFcCO2Cu(PPh3)3] ⋅ 3 CH3OH (SC2), is reported. Both structures are fully characterized by various techniques. The structures are utilized as energy storage electrode materials, giving 130 F g−1 and 210 F g−1 specific capacitance at 1.5 A g−1 in Na2SO4 electrolyte, respectively. The obtained results show that the presence of CuI instead of AgI improves the supercapacitive performance of the cluster. Further, to improve the conductivity, the PSC2 ([(PPh3)2CuO2CFcCO2]∞), a polymeric structure of SC2, was synthesized and used as an energy storage electrode. PSC2 displays high conductivity and gives 455 F g−1 capacitance at 3 A g−1. The PSC2 as a supercapacitor electrode presents a high power density (2416 W kg−1), high energy density (161 Wh kg−1), and long cycle life over 4000 cycles (93 %). These results could lead to the amplification of high-performance supercapacitors in new areas to develop real applications and stimulate the use of the targeted design of coordination polymers without hybridization or compositions with additive materials. 相似文献
56.
57.
Dr. Kalaiselvi Natarajan Daniel Müller-Klieser Stefan Rubner Prof. Dr. Thorsten Berg 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(1):148-154
We present a new approach for the identification of inhibitors of phosphorylation-dependent protein–protein interaction domains, in which phenolic fragments are adapted by in silico O-phosphorylation before docking-based screening. From a database of 10 369 180 compounds, we identified 85 021 natural product-derived phenolic fragments, which were virtually O-phosphorylated and screened for in silico binding to the STAT3 SH2 domain. Nine screening hits were then synthesized, eight of which showed a degree of in vitro inhibition of STAT3. After analysis of its selectivity profile, the most potent inhibitor was then developed to Stafia-1, the first small molecule shown to preferentially inhibit the STAT family member STAT5a over the close homologue STAT5b. A phosphonate prodrug based on Stafia-1 inhibited STAT5a with selectivity over STAT5b in human leukemia cells, providing the first demonstration of selective in vitro and intracellular inhibition of STAT5a by a small-molecule inhibitor. 相似文献
58.
Dr. Hiromichi Nakahara Dr. Marie Pierre Krafft Prof. Osamu Shibata 《Chemphyschem》2020,21(17):1966-1970
We found that monolayers of dipalmitoylphosphatidylcholine (DPPC) and semi-fluorinated tetrablock di(F10H16) self-assemble to form a new type of large, complex flower-like patterns on the surface of water and on solid substrates. The hierarchical organization of these unusual self-assemblies was investigated using compression and surface potential isotherms, in situ fluorescence and Brewster angle microscopies, and atomic force microscopy after transfer. 相似文献
59.
D.E. Edmunds R. Hurri-Syrjnen 《Journal of Mathematical Analysis and Applications》2005,310(2):424-435
For bounded Lipschitz domains D in it is known that if 1<p<∞, then for all β[0,β0), where β0=p−1>0, there is a constant c<∞ with for all . We show that if D is merely assumed to be a bounded domain in that satisfies a Whitney cube-counting condition with exponent λ and has plump complement, then the same inequality holds with β0 now taken to be . Further, we extend the known results (see [H. Brezis, M. Marcus, Hardy's inequalities revisited, Dedicated to Ennio De Giorgi, Ann. Scuola Norm. Sup. Pisa Cl. Sci. (4) 25 (1997–1998) 217–237; M. Hoffmann-Ostenhof, T. Hoffmann-Ostenhof, A. Laptev, A geometrical version of Hardy's inequality, J. Funct. Anal. 189 (2002) 537–548; J. Tidblom, A geometrical version of Hardy's inequality for W1,p(Ω), Proc. Amer. Math. Soc. 132 (2004) 2265–2271]) concerning the improved Hardy inequality c=c(n,p), by showing that the class of domains for which the inequality holds is larger than that of all bounded convex domains. 相似文献
60.
积域上一类奇异积分算子的L~p有界性 总被引:1,自引:0,他引:1
本文证明,对于Ω∈(1)∩L(log~+L)~2(S~(n-1)×S~(m-1)),h(r,s)∈L~∞(R_+~1×R_+~1)和P_(N_1),P_(N_2)∈(2),带粗糙核的奇异积分算子为L~p有界。 相似文献