Quantum-Chemical Evaluation of the Protolytic Properties of Thiophenols

The enthalpies and free energies of proton affinity (PA) were calculated by the PM3 method for 27 thiophenoxide anions. For thiophenols, linear correlation has been found between the PAs and the values of pK _a measured by different authors in aqueous acetone, aqueous ethanol, and methanol media. The dependences found permit one to predict a priori the protolytic properties of thiophenols. The differential effects of aqueous ethanol media with different ethanol contents on thiophenol acidity were evaluated based on quantum-chemical data.Original Russian Text Copyright © 2004 by A. N. Pankratov and A. V. Shalabai__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 800–806, September–October, 2004.     

Stress and heat flux stabilization for viscous compressible medium equations with a nonmonotone state function

We study a system of quasilinear equations describing one-dimensional flow of a viscous compressible heat-conducting medium with a nonmonotone state function and mass force. The large-time behavior of solutions is considered for arbitrarily large initial data. In spite of possible nonuniqueness and discontinuity of the stationary solution, we prove L²-stabilization for the stress and heat flux as t → ∞ along with corresponding global energy estimates for them. The new method of proof utilizes a combination of energy type equalities for the stress and heat flux. Consequently, H¹-stabilization of the velocity and temperature along with global estimates for their derivatives are valid as well.     

视觉与材质——油画颜料的视觉效果

本文通过对佛兰德斯和北欧、意人利和南欧的色层语言的分析,可以看出油画这种艺术形式之所以能长时期吸引人们,与它的材质密切相关。这种由材质形成的色层语言不仅生动地表现了对自然的摹仿,而且体现出它独特的色层美感。     

Radiation Transfer in a Binary, Stochastic Medium with Strongly Fluctuating Parameters

The propagation of radiation in a three-dimensional, inhomogeneous, stochastic, scattering medium and in an equivalent homogeneous medium has been investigated by the small-angle iteration method. The statistical structure of the scattering parameters of a three-dimensional medium has been described within the framework of the two-dimensional Poisson process and the binary Markov process. The analytical data obtained point to the fact that the three-dimensional inhomogeneity of a stochastic medium significantly influences the radiation transfer in it.     

Green chemical synthesis of fluorinated 1,3,5-triaryl-s-triazines in aqueous medium under microwaves as potential antifungal agents

Reasonable pure fluorinated s-triazines were synthesized in quantitative yield (96-99%) in 2-3 min in aqueous medium under microwaves, by reaction of fluorinated anilines and aqueous formaldehyde. All synthesized compounds have been screened in vitro for their antifungal activity against Rhizoctonia solani, Fusarium oxysporum, and Collectotrichum capsici.     

Pattern forming precipitation in gels due to coupling of chemical reactions with diffusion

Precipitate-forming chemical reactions have been studied in chemically cross-linked poly(vinyl alcohol) gel medium. One of the reactive components was incorporated into the gel, the other was allowed to diffuse into it. Depending on the experimental conditions the reaction-diffusion process often results in patterns of different type. Experiments performed in tubes and in thin layers were carried out in order to investigate the effects of various factors (cross-linking density, swelling degree as well as the concentrations of the outer and inner electrolytes) on the morphologies of the precipitate patterns. It was found that precipitation occurs not only in the Liesegang bands, but also between bands. Beside Liesegang-type structures, tree-like patterns have been observed, showing a characteristic periodicity in the density profile obtained by digitalized image analyses.     

试论中小企业在台湾经济发展中的作用

在台湾经济发展过程中，中小企业始终发挥着重要的作用。这不仅是因为台湾中小企业自身具备灵活与弹性的特质，能够适应各种内外经济环境，起着大企业所不能起的填补经济活动中的空缺的作用，而且中小企业之间能自发形成各种协作关系，台湾行政当局加以有组织地推动经济合作，使中小企业始终发挥重要作用。研究中小企业在台湾经济发展中的作用对我们在工业化过程中，如何扶持中小企业，使它促进经济协调发展，有一定的借鉴意义。     

Interactions between kinetic and radiative processes inside moving absorbing fluids

The aim of this paper is to present several features of the couplings occurring between radiative transfer and the kinetics of a moving dielectric. After determining how the velocity field affects the apparent thermo-optical properties of matter, the energy transport problem is investigated in instationary regime and the general form of transient radiative transfer equation inside a moving medium is built. Then, the model is applied to the particular case of turbulent flows: a system of two equations for mean and fluctuating radiative energies is presented, and the resolution of this system is finally carried out.     

校内传媒的育人功能研究

从对校内传媒育人功能的介绍入手，分析了校内传媒育人功能发挥的现状，并就如何强化校内传媒的育人功能提出了宏观和微观对策。