全文获取类型
收费全文 | 14647篇 |
免费 | 627篇 |
国内免费 | 1997篇 |
专业分类
化学 | 7183篇 |
晶体学 | 111篇 |
力学 | 421篇 |
综合类 | 107篇 |
数学 | 378篇 |
物理学 | 1232篇 |
综合类 | 7839篇 |
出版年
2024年 | 42篇 |
2023年 | 128篇 |
2022年 | 454篇 |
2021年 | 429篇 |
2020年 | 324篇 |
2019年 | 351篇 |
2018年 | 311篇 |
2017年 | 413篇 |
2016年 | 513篇 |
2015年 | 547篇 |
2014年 | 656篇 |
2013年 | 872篇 |
2012年 | 836篇 |
2011年 | 775篇 |
2010年 | 586篇 |
2009年 | 637篇 |
2008年 | 705篇 |
2007年 | 953篇 |
2006年 | 844篇 |
2005年 | 738篇 |
2004年 | 698篇 |
2003年 | 652篇 |
2002年 | 598篇 |
2001年 | 517篇 |
2000年 | 485篇 |
1999年 | 456篇 |
1998年 | 342篇 |
1997年 | 317篇 |
1996年 | 327篇 |
1995年 | 254篇 |
1994年 | 240篇 |
1993年 | 191篇 |
1992年 | 223篇 |
1991年 | 166篇 |
1990年 | 158篇 |
1989年 | 162篇 |
1988年 | 119篇 |
1987年 | 69篇 |
1986年 | 50篇 |
1985年 | 41篇 |
1984年 | 23篇 |
1983年 | 27篇 |
1982年 | 23篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1968年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
采用荧光法测定了辽河冷家油田冷47-556井特稠油乳化HLB值,然后以混合型表面活性剂、非离子型表面活性剂为主剂,快速渗透剂为辅剂按一定比例制备了水基降粘剂LJVR-1.实验结果表明,该降粘剂具有良好的乳化降粘性能,开采后易于破乳脱水,是一种较为理想的特稠油降粘剂. 相似文献
72.
Pyridine-based, structurally isomeric two macrocyclic compounds displayed a remarkably different complexation nature. The cage-type compound has an ideal structure for spherical cations, especially for the NH4+ ion, but the reaction with some transition metals and Ln3+ produced its protonated species. On the other hand, its isomer formed complexes with alkali metals and lanthanides (1:1) and also with transition metals. Some structures of the complexes were clarified by crystallographic analyses. 相似文献
73.
The polycrystalline sample of layered compound FePS_3 has been investigated by using M?ssbauer spectroscopy (12K to 300K), magnetic susceptibility measurements, x-ray diffraction and FTIR spectroscopy. The antiferromagnetic order exists below T_N=120.5±1K. The M?ssbauer spectra below T_N indicate that the magnetization axis is perpendicular to the layer of FePS_3, and the divalent iron cations are in their high spin configurations. By fitting the hyperfine field parameters near the Néel temperature, we obtain information on the nature of magnetic interactions in the material. The results show that the magnetic coupling can be treated by the two-dimensional Ising model, and it can be interpreted on the basis of a crystal-field effect. 相似文献
74.
Leda M. F. Gottschalk Ronaldo Nobrega Elba P. S. Bon 《Applied biochemistry and biotechnology》2003,108(1-3):799-807
The effect of aeration on lignin peroxidase production by Streptomyces viridosporus T7A was studied in a bench-scale bioreactor using a previously optimized growth medium (0.65% yeast extract and 0.1% corn
oil, pH7.0) at 37°C and natural pH. Airflow rates of 0.3, 1.0, and 1.5 vvm and a fixed agitation of 200 rpm were initially
studied followed by 1.0 vvm and 200, 300, 400, and 500 rpm. The use of 1.0 vvm and 400 rpm increased enzyme concentration
1.8-fold (100–180 U/L) and process productivity 4.8-fold (1.4–6.7 U/[L·h]) in comparison with the use of 200 rpm and 0.3 vvm.
The inexpensive corn oil, used as carbon source, besides its antifoam properties, proved to be nonrepressive for enzyme production. 相似文献
75.
Summary A new gas chromatographic method using an automatic purge-and-trap system coupled to a GC with mass selective detection to analyze styrene at the parts-per-trillions (ng kg–1) level is described. The method shows a good sensitivity and the detection limit is 10 ng kg–1 with a relative standard deviation (RSD) of 4.7% for 164 ng kg–1 styrene in olive oil. This analytical method has been successfully applied to the analysis of styrene in extra-virgin olive oil from the European market. 相似文献
76.
磺化法生产优级溶剂油的实验研究 总被引:2,自引:0,他引:2
考察了溶剂油磺化过程中芳烃含量的变化。结果表明,溶剂油中的芳烃在30~50℃时与磺化剂反应,并且随着磺化剂加入量的增加,溶剂油中的芳烃逐渐降低,从而达到了溶剂油脱芳烃的目的。 相似文献
77.
陈华 《湖南理工学院学报:自然科学版》1996,(1)
本文研究了淬火工艺对低和中碳铬钢的显微组织,冲击韧性和断裂机制的影响,得出了无论是低碳,还是中、高碳钢,当奥氏体长大倾向稍大时,采取提高加热温度进行淬火的工艺均为不可取的结论。 相似文献
78.
79.
Mitsuru Ueda Tetsuya Abe Mitsuo Oda 《Journal of polymer science. Part A, Polymer chemistry》1992,30(9):1993-1998
Aromatic poly(thioether ketone)s were prepared by the direct polycondensation of aromatic dicarboxylic acids with aryl compounds containing ether or sulfide structures using phosphorus pentoxide/methanesulfonic acid (PPMA) as a condensing agent and solvent. Polycondensation proceeded smoothly and produced aromatic poly(thioether ketone)s with inherent viscosities up to 0.73 dL/g. The synthesis of substituted aryl ketones by the reaction of substituted benzoic acids with aryl compounds in PMMA was studied in detail to demonstrate the feasibility of the reaction for polymer formation. The thermogravimetry of the aromatic poly(thioether ketone)s showed a 10% weight loss in air and nitrogen at around 450 and 460°C, respectively. © 1992 John Wiley & Sons, Inc. 相似文献
80.
杨慧 《原子与分子物理学报》2002,19(4):411-416
以二维复式晶格作为有限系统的集团模型,在紧束缚近似下,计算了π电子在最近邻及次近邻跳跃集团的态密度.讨论了不同结构参数对态密度及带宽的影响. 相似文献