硅铝比对完全液相法制备的一步法二甲醚合成催化剂反应性能的影响

采用完全液相法制备了不同Si/Al摩尔比的浆状一步法二甲醚合成催化荆,在搅拌式反应釜中对其催化性能进行了评价.通过XRD,NH3-TPD-MS,H2-TPR和XPS等方法表征了催化剂的体相结构和表面性质.结果表明,完全液相法制备的CuZnSiAl催化剂在反应前其活性组分Cu主要以低价态存在,Cu晶粒大小是影响其活性的主...     

天然纤维预处理技术研究进展

天然纤维预处理是影响天然纤维强化生物复合材料的关键因素。文章首先从天然纤维的物理特性、化学成分和吸湿特性三方面对纤维性能进行了陈述,针对这些性能综述了国内外常用的天然纤维预处理方法,重点介绍了碱化处理、硅烷处理、高锰酸盐处理和过氧化物处理等化学方法,并对比了天然纤维经常用化学改性方法处理后产生的结果;其次介绍了机械加工...     

3D打印技术制备生物医用高分子材料的研究进展

3D打印技术能够根据不同患者需要,快速精确制备适合不同患者的个性化生物医用高分子材料,并能同时对材料的微观结构进行精确控制.因此,这种新兴的医用高分子材料制备技术在未来生物医学应用(尤其是组织工程应用)中具有独特的优势.近年来,对于3D打印技术制备生物医用高分子材料的研究开发受到了越来越多的关注.不同的生物相容高分子原料被应用于3D打印技术,而这些3D成型高分子材料被用于体外细胞培养,或动物模型的软组织或硬组织修复中.本文主要介绍了近年来3D打印技术在生物医用高分子材料制备中的研究进展,并对该领域的未来应用和挑战进行了展望.     

Natural deep eutectic solvents as new potential media for green technology

Developing new green solvents is one of the key subjects in Green Chemistry. Ionic liquids (ILs) and deep eutectic solvents, thus, have been paid great attention to replace current harsh organic solvents and have been applied to many chemical processing such as extraction and synthesis. However, current ionic liquids and deep eutectic solvents have still limitations to be applied to a real chemical industry due to toxicity against human and environment and high cost of ILs and solid state of most deep eutectic solvents at room temperature. Recently we discovered that many plant abundant primary metabolites changed their state from solid to liquid when they were mixed in proper ratio. This finding made us hypothesize that natural deep eutectic solvents (NADES) play a role as alternative media to water in living organisms and tested a wide range of natural products, which resulted in discovery of over 100 NADES from nature. In order to prove deep eutectic feature the interaction between the molecules was investigated by nuclear magnetic resonance spectroscopy. All the tested NADES show clear hydrogen bonding between components. As next step physical properties of NADES such as water activity, density, viscosity, polarity and thermal properties were measured as well as the effect of water on the physical properties. In the last stage the novel NADES were applied to the solubilization of wide range of biomolecules such as non-water soluble bioactive natural products, gluten, starch, and DNA. In most cases the solubility of the biomolecules evaluated in this study was greatly higher than water. Based on the results the novel NADES may be expected as potential green solvents at room temperature in diverse fields of chemistry.     

钛材化学清洗工艺综述

介绍了钛材碱洗脱脂除油和酸洗除去氧化皮的原理和方法,重点阐述了钛材碱洗除油和酸洗除去氧化皮的工艺条件、工艺流程和设备.     

纳米颗粒透明分散体及其高性能有机无机复合材料

纳米颗粒分散是无机纳米材料在有机体系中应用的关键.本文提出了采用纳米颗粒液相分散体制备高度分散纳米透明有机无机复合材料的新方法,发明了超重力反应-萃取相转移方法制备纳米颗粒液相透明分散体技术,介绍了其制备原理和实施效果,以及其在纳米复合节能膜、纳米润滑油脂和高固含量光学材料等有机无机纳米复合材料中的最新研究进展.     

一种基于MEMS技术的PDMS微型分流器的研制

本文采用三层光刻工艺制作了基于聚二甲基硅氧烷(Polydimethylsiloxane,PDMS)的V形微分流器。引入牺牲层技术,解决了不同胶层间的界面互融问题,讨论了不同胶层间显影液对图形质量的影响。所制得的分流器工艺简单,结构形貌良好,具有良好的微流控制作用,满足器件使用要求。