全文获取类型
收费全文 | 13274篇 |
免费 | 815篇 |
国内免费 | 740篇 |
专业分类
化学 | 2298篇 |
晶体学 | 26篇 |
力学 | 699篇 |
综合类 | 108篇 |
数学 | 3400篇 |
物理学 | 1695篇 |
综合类 | 6603篇 |
出版年
2024年 | 26篇 |
2023年 | 91篇 |
2022年 | 129篇 |
2021年 | 147篇 |
2020年 | 203篇 |
2019年 | 188篇 |
2018年 | 218篇 |
2017年 | 260篇 |
2016年 | 274篇 |
2015年 | 299篇 |
2014年 | 498篇 |
2013年 | 612篇 |
2012年 | 597篇 |
2011年 | 685篇 |
2010年 | 635篇 |
2009年 | 737篇 |
2008年 | 832篇 |
2007年 | 978篇 |
2006年 | 838篇 |
2005年 | 815篇 |
2004年 | 650篇 |
2003年 | 636篇 |
2002年 | 687篇 |
2001年 | 503篇 |
2000年 | 408篇 |
1999年 | 368篇 |
1998年 | 337篇 |
1997年 | 270篇 |
1996年 | 277篇 |
1995年 | 238篇 |
1994年 | 225篇 |
1993年 | 191篇 |
1992年 | 154篇 |
1991年 | 131篇 |
1990年 | 103篇 |
1989年 | 111篇 |
1988年 | 76篇 |
1987年 | 72篇 |
1986年 | 56篇 |
1985年 | 48篇 |
1984年 | 32篇 |
1983年 | 18篇 |
1982年 | 35篇 |
1981年 | 42篇 |
1980年 | 23篇 |
1979年 | 25篇 |
1978年 | 19篇 |
1977年 | 5篇 |
1976年 | 9篇 |
1973年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
51.
Govindarajan Sankar A. Sultan Nasar 《Journal of polymer science. Part A, Polymer chemistry》2007,45(8):1557-1570
A series of substituted N‐methylaniline‐blocked polyisocyanates based on 4,4′‐methylenebis(phenyl isocyanate) and poly(tetrahydrofuran) were prepared and characterized thoroughly with FTIR, 1H NMR, and 13C NMR spectroscopy methods. Compared with unsubstituted N‐methylaniline, a blocking agent with an electron‐releasing substituent at the para position took a shorter time, whereas those with an electron‐releasing substituent at the ortho position or an electron‐withdrawing substituent at the ortho and para positions took longer times for the blocking reaction. The thermal dissociation reactions of blocked polyisocyanates were carried out with an FTIR spectrophotometer attached to hot‐stage accessories under dynamic and isothermal conditions. The dynamic method was used to determine the deblocking temperature, and the isothermal method was used to calculate the deblocking kinetics and activation parameters. The cure times of blocked polyisocyanates with hydroxyl‐terminated polybutadiene were also determined. The deblocking temperatures, the results of cure‐time studies, and the kinetic parameters revealed that the thermal dissociation of the N‐methylaniline‐blocked polyisocyanates was retarded by electron‐donating substituents and facilitated by electron‐withdrawing substituents. The action of N‐methylanilines as blocking agents for isocyanate was explained by the formation of a four‐center, intramolecularly hydrogen‐bonded ring structure during the thermal dissociation of the blocked polyisocyanates. The formation of such a hydrogen‐bonded ring structure was confirmed and supported by variable‐temperature 1H NMR studies and entropy parameters, respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1557–1570, 2007 相似文献
52.
针对SR电动机存在的振动和噪声问题,分别应用实验模态分析法和计算模态分析法研究了SR电动机的动力特性,得到了SR电动机定子的固有频率和主振型,计算值与实验测量值吻合较好,所得数据可为制定抑制SR电动机的振动和噪声方案提供参考. 相似文献
53.
无线电波透视法及其应用 总被引:4,自引:0,他引:4
无线电波透视法是利用无线电波在钻孔中的发射和接收来确定地下介质特性和地质构造的一种物探方法,当电磁波在地下有耗介质中传播时,遇到岩性不同的分界面就会产生不同的电磁波反射,折射,透射和频散,吸收等,通过研究接收到的电磁波的性质达到探测地下目标物的目的,本文简述了该方法的理论,描述了方法的分类,概述了目前使用的发射天线,接收天线和常用的仪器,总结了野外工作方法和解释方法,最后给出了应用实例说明其应用效果。 相似文献
54.
We discuss differential equations with nonlinear boundary conditions. We formulate sufficient conditions under which problems
with deviating arguments have quasisolutions or solutions. To obtain the results, we apply the method of monotone iterations. 相似文献
55.
A. V. Gavrilov 《Siberian Mathematical Journal》2007,48(1):56-61
We study the double exponential map which is a composition of a special form of two exponential maps on a manifold with connection. We relate this map and the composition of covariant derivations as well as the composition of pseudodifferential operators on these manifolds. 相似文献
56.
陈明旦 《厦门大学学报(自然科学版)》1996,35(1):86-89
采用快速BASIC及其工具库编写一个用途广泛的引导程序,它具有将各类不同程序的运行或变换溶为一体对用户十分友好的界面,在计算化学和计算机文献检索中得到实际应用. 相似文献
57.
J. Seke 《Il Nuovo Cimento D》1993,15(7):1031-1034
Summary By using a self-consistent projection-operator method, developed recently by the present author, a gauge-invariant Markovian
treatment of the spontaneous decay of an unstable atomic state is presented. Without ignoring retardation and electron-spin
effects a gauge-invariant result for the probability amplitude of finding the atom in the unstable state is obtained. 相似文献
58.
59.
A multidimensional version of the first Darboux problem is considered for a model second-order degenerating hyperbolic equation. Using the technique of functional spaces with a negative norm, the correct formulation of this problem in the Sobolev weighted space is proved. 相似文献
60.
Using the appropriate harmonic oscillator states and reasonable approximations, we construct coherent wavepackets corresponding
to the solutions of the Klein-Gordon equation for the attractive potentialV(r)=−k/r, k>0, in two and three space dimensions. We deduce the corresponding classical limit in two dimension by requiring that the
expectation value 〈r〉 of the radial variable is large. In the case of three dimensions, besides the condition of large 〈r〉, we make the uncertainty Δr=[〈r
2〉 − 〈r〉2]1/2 a minimum with respect to certain parameter of the wavepacket. We then investigate the trajectory traversed by the wavepacket
in the classical limit. We find that the classical limit of this relativistic quantal problem gives, in the leading order,
the same expression for the rate of motion of the perihelion as that given by the solution of the corresponding special relativistic
classical dynamical problem. We also briefly discuss some of the subtle aspects of the classical limit of the relativistic
quantal system, in general. 相似文献