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The ability to prepare high Tg low shrinkage thiol–ene materials is attractive for applications such as coatings and dental restoratives. However, thiol and nonacrylated vinyl materials typically consist of a flexible backbone, limiting the utility of these polymers. Hence, it is of importance to synthesize and investigate thiol and vinyl materials of varying backbone chemistry and stiffness. Here, we investigate the effect of backbone chemistry and functionality of norbornene resins on polymerization kinetics and glass transition temperature (Tg) for several thiol–norbornene materials. Results indicate that Tgs as high as 94 °C are achievable in thiol–norbornene resins of appropriately controlled chemistry. Furthermore, both the backbone chemistry and the norbornene moiety are important factors in the development of high Tg materials. In particular, as much as a 70 °C increase in Tg was observed in a norbornene–thiol specimen when compared with a sample prepared using allyl ether monomer of analogous backbone chemistry. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5686–5696, 2007  相似文献   
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应用生成函数的方法求出了常系数非齐次线性递推式的显式解。  相似文献   
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由于宪法机制上的含糊性,美国历史上存在对外政策上的“府会”之争。冷战结束以来,国会实现了一种在对外政策上的“复兴”。伴随这一历史背景,国会在美国对华决策机制中所起的作用越来越大。从历史线索整理当代中美关系发展史上国会在不同时期对中美关系的影响,可以概括出美国国会在中美关系中的主要地位作用,进而得出影响美国国会对华政策的关键性原因:国会内部微观因素和外部制约因素。在此基础上,可以预测美国国会对中美关系进一步发挥影响的可能趋势,进而提出中国政府做国会工作的几点对策。  相似文献   
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1977年邓小平复出后十分重视中美关系,在他亲自领导下,中美关系有了很大的发展,其问,也经历了许多波折。邓小平对中美关系的重要性有正确的判断,对存在的问题有清醒的认识,对中美关系的斗争性有充分的准备。回顾邓小平对中美关系的论述,在当前中美关系依然错综复杂的情况下,有助于我们正确把握中美关系的航向,有助于中美关系健康稳定发展。  相似文献   
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The factors affecting pattern‐forming properties in reaction development patterning were examined with polyarylates with various bisphenol moieties. The developability of the photosensitive polyarylates was dependent on the properties of the subtituent (R) in the bisphenol moieties. The development time decreased in the following order: R?C(CH3)2 > fluorenyl unit ? phenolphthalein unit > C(CF3)2 > SO2. This order agreed with that of the reactivity between the polyarylates and ethanolamine, and these orders can be explained by pKa of the bisphenol used to prepare the polyarylates. The development with NH2? R′? OH resulted in successful positive‐tone pattern formation. However, pattern formation with the developers containing NH2? R′? OCH3 was unsuccessful. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2694–2706, 2006  相似文献   
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以晶格自旋体系的Heisenberg模型为依据,计算了大s的极限情况下,一维量子反铁磁链转动生成元l与Neel矢量间的对易关系,求出了以广义坐标和广义动量形式表示的格点自旋间的拉氏函数密度表示。  相似文献   
29.
A forward dispersion calculation is implemented for the spin polarizabilities γ1,,γ4 of the proton and the neutron. These polarizabilities are related to the spin structure of the nucleon at low energies and are structure-constants of the Compton scattering amplitude at . In the absence of a direct experimental measurement of these quantities, a dispersion calculation serves the purpose of constraining the model building, and of comparing with recent calculations in heavy baryon chiral perturbation theory.  相似文献   
30.
The various approaches to nonequilibrium statistical mechanics may be subdivided into convolution and convolutionless (time-local) ones. While the former, put forward by Zwanzig, Mori, and others, are used most commonly, the latter are less well developed, but have proven very useful in recent applications. The aim of the present series of papers is to develop the time-local picture (TLP) of nonequilibrium statistical mechanics on a new footing and to consider its physical implications for topics such as the formulation of irreversible thermodynamics. The most natural approach to TLP is seen to derive from the Fourier-Laplace transform ) of pertinent time correlation functions, which on the physical sheet typically displays an essential singularity at z= and a number of macroscopic and microscopic poles in the lower half-plane corresponding to long- and short-lived modes, respectively, the former giving rise to the autonomous macrodynamics, whereas the latter are interpreted as doorway modes mediating the transfer of information from relevant to irrelevant channels. Possible implications of this doorway mode concept for socalled extended irreversible thermodynamics are briefly discussed. The pole structure is used for deriving new kinds of generalized Green-Kubo relations expressing macroscopic quantities, transport coefficients, e.g., by contour integrals over current-current correlation functions obeying Hamiltonian dynamics, the contour integration replacing projection. The conventional Green-Kubo relations valid for conserved quantities only are rederived for illustration. Moreover, may be expressed by a Laurent series expansion in positive and negative powers ofz, from which a rigorous, general, and straightforward method is developed for extracting all macroscopic quantities from so-called secularly divergent expansions of as obtained from the application of conventional many-body techniques to the calculation of . The expressions are formulated as time scale expansions, which should rapidly converge if macroscopic and microscopic time scales are sufficiently well separated, i.e., if lifetime (memory) effects are not too large.  相似文献   
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