全文获取类型
收费全文 | 188434篇 |
免费 | 10111篇 |
国内免费 | 12713篇 |
专业分类
化学 | 34871篇 |
晶体学 | 387篇 |
力学 | 7959篇 |
综合类 | 1394篇 |
数学 | 33155篇 |
物理学 | 30254篇 |
综合类 | 103238篇 |
出版年
2024年 | 306篇 |
2023年 | 1216篇 |
2022年 | 2186篇 |
2021年 | 2553篇 |
2020年 | 2858篇 |
2019年 | 2943篇 |
2018年 | 2674篇 |
2017年 | 3202篇 |
2016年 | 3583篇 |
2015年 | 4164篇 |
2014年 | 7319篇 |
2013年 | 9148篇 |
2012年 | 8976篇 |
2011年 | 10285篇 |
2010年 | 8504篇 |
2009年 | 10345篇 |
2008年 | 11161篇 |
2007年 | 13101篇 |
2006年 | 12302篇 |
2005年 | 11353篇 |
2004年 | 9692篇 |
2003年 | 9239篇 |
2002年 | 8088篇 |
2001年 | 6832篇 |
2000年 | 6212篇 |
1999年 | 5230篇 |
1998年 | 4515篇 |
1997年 | 3919篇 |
1996年 | 3599篇 |
1995年 | 3249篇 |
1994年 | 3036篇 |
1993年 | 2691篇 |
1992年 | 2535篇 |
1991年 | 2214篇 |
1990年 | 2016篇 |
1989年 | 1923篇 |
1988年 | 1630篇 |
1987年 | 1078篇 |
1986年 | 777篇 |
1985年 | 640篇 |
1984年 | 570篇 |
1983年 | 284篇 |
1982年 | 445篇 |
1981年 | 501篇 |
1980年 | 384篇 |
1979年 | 383篇 |
1978年 | 293篇 |
1977年 | 275篇 |
1976年 | 218篇 |
1973年 | 160篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
41.
42.
43.
44.
针对“剥岩高峰”对矿山生产带来的不利影响,研究了设备配置更新策略与露天开采外委剥离的优化问题.基于铲运设备的运营成本与生产能力随设备役龄变化的关系,建立了决策单台设备退役时间的动态经济寿命计算模型,并根据此模型给出了具体的设备配置算法步骤.设置一系列不同的矿山自剥离量与外委剥离量的分界水平,计算各分界水平条件下的外委单价可行区间,然后在区间内确定外委商谈价格并分析得出与之对应的总成本净现值最低的外委方案.实例计算证明,采用该方法减少设备投资的成本要高于外委岩石剥离成本. 相似文献
45.
46.
It is known that under resonance conditions, a group of strongly interacting bosonic atoms, trapped in a double-well potential, mimics a single particle, performing Rabi oscillations between the wells. By implication, all atoms need to tunnel at roughly the same time, even though the Bose–Hubbard Hamiltonian accounts only for one-atom-at-a-time transfers. The mechanism of this collective behavior is analyzed, the Rabi frequencies in the process are evaluated, and the limitation of this simple picture is discussed. In particular, it is shown that the small rapid oscillations superimposed on the slow Rabi cycle result from splitting the transferred cluster at the sudden onset of tunnelling, and disappear if tunnelling is turned on gradually. 相似文献
47.
Synthesis of diisocyanides with phenolic groups and their polymerization to helically chiral poly(quinoxaline‐2,3‐diyl)s
下载免费PDF全文
![点击此处可从《Journal of polymer science. Part A, Polymer chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Johannes Scholz Michael Reggelin 《Journal of polymer science. Part A, Polymer chemistry》2015,53(11):1320-1329
The development of synthetic routes which lead to five new diisocyanide monomers with one or two phenolic groups is described. Their polymerization behavior is studied with Pd‐ and Ni‐based initiators, as well as under microwave irradiation. The polymerizability is mainly dominated by steric effects as is concluded from experiments using different protecting groups. Chiroptical properties of these new polymers are studied by CD‐spectroscopy. After deprotection, helically chiral poly(quinoxalin‐2,3‐diyl)s are obtained which display a Brønsted function attached to a stereolabile biaryl axis whose configuration should be influenced by the chiral polymer backbone. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1320–1329 相似文献
48.
49.
We proposed an electro-optic modulator with two-bus one-ring (TBOR) structure to improve the extinction ratio and reduce insert loss. It has a dual output compared with one-bus one-ring structure. In addition, double-layer graphene makes it possible for the modulation in the visible to mid-infrared wavelength range. It shows that this new electro-optic modulator can present two switching states well with low insertion loss, high absorption and high extinction ratio. At , when the switching states are based on the chemical potential, and , the insertion losses of both output ports are less than 2 dB, the absorption of the output port coupled via a micro-ring reaches 45 dB and the extinction ratio reaches 14 dB. When the refractive index of the dielectric material is 4.2, the applied voltage will be less than 1.2 V, thus can be used in low-voltage CMOS technology. 相似文献
50.
Inflation of balloons provides a straightforward way of achieving large biaxial deformations. Previous studies have shown that when a balloon bursts, crack propagation occurs at very high speed – much higher than would be expected from the low strain modulus and elastic wave velocity of the rubber. The present paper is concerned with studies of the deformation and fracture of cylindrical balloons. On inflation, the deformations of such a balloon pass through an unstable region but subsequently increase monotonically with pressure. In this relatively high pressure region, the ratio of the longitudinal and circumferential extension ratios is broadly in accord with expectations from high-strain elasticity theory when the ratio of the corresponding stresses is taken into account. On bursting, crack speeds up to around 300 m/s in this region. It is shown that these speeds are in accord with large increase in incremental moduli for the highly-strained rubber. Marked changes in crack tip profile observed at very high crack speeds are consistent with control of the rate of growth by inertia rather than by the viscoelastic properties of the rubber (as is believed to be the case at lower speeds). Consistent with this, various elastomers having different glass transition temperatures show similar crack growth behaviour in the very high speed region. 相似文献