首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   6596篇
  免费   625篇
  国内免费   336篇
化学   432篇
晶体学   48篇
力学   279篇
综合类   96篇
数学   1783篇
物理学   1379篇
综合类   3540篇
  2025年   17篇
  2024年   68篇
  2023年   100篇
  2022年   132篇
  2021年   166篇
  2020年   159篇
  2019年   165篇
  2018年   118篇
  2017年   165篇
  2016年   163篇
  2015年   197篇
  2014年   326篇
  2013年   299篇
  2012年   299篇
  2011年   342篇
  2010年   313篇
  2009年   448篇
  2008年   403篇
  2007年   464篇
  2006年   467篇
  2005年   357篇
  2004年   307篇
  2003年   273篇
  2002年   248篇
  2001年   229篇
  2000年   173篇
  1999年   175篇
  1998年   144篇
  1997年   136篇
  1996年   125篇
  1995年   110篇
  1994年   112篇
  1993年   74篇
  1992年   70篇
  1991年   44篇
  1990年   60篇
  1989年   33篇
  1988年   19篇
  1987年   17篇
  1986年   11篇
  1985年   8篇
  1984年   6篇
  1983年   4篇
  1981年   1篇
  1980年   3篇
  1979年   1篇
  1977年   1篇
  1976年   2篇
  1973年   1篇
  1971年   1篇
排序方式: 共有7557条查询结果,搜索用时 15 毫秒
41.
提出了浓硫酸颜色反应用于甲芬那酸荧光测定的新方法.甲芬那酸为弱荧光物质,与浓硫酸反应后荧光显著增强.体系最大激发波长和最大发射波长分别为385.0和471.9nm,甲芬那酸浓度在9.0×10-9~7.5×10-5 g·mL-1范围内与荧光强度呈良好的线性关系,方法检出限为3.1×10-9 g· mL-1,回收率为99.3% ~ 102%.方法操作简单,灵敏度高,选择性好,用于甲芬那酸胶囊中甲芬那酸含量测定,结果满意.  相似文献   
42.
The pigment, tecophilin, in blue flowers of Tecophilaea cyanocrocus was isolated and the structure was determined to be 3-O-(6-O-α-l-rhamnopyranosyl-β-d-glucopyranosyl)-7-O-(6-O-(4-O-(2-O-(4-O-β-d-glucopyranosyl-(E)-caffeoyl)-6-O-(4-O-β-d-glucopyranosyl-(E)-caffeoyl)-β-d-glucopyranosyl)-(E)-caffeoyl)-β-d-glucopyranosyl)delphinidin. The reproduction experiment of the same color as petals according to the results of chemical analysis and measurement of vacuolar pH of blue cells clarified that the blue color solely develops by tecophilin without interaction of metal ions nor co-pigments. 1H NMR analysis and CD spectrum indicate the co-existence of clockwise intermolecular self-association of the delphinidin nuclei and intramolecular π–π stacking between the chromophore and caffeoyl residues to derive bathochromic shift of the absorption spectrum and stabilize the color by preventing hydration reaction.  相似文献   
43.
    
A flow‐condition‐based interpolation finite element scheme is presented for use of triangular grids in the solution of the incompressible Navier–Stokes equations. The method provides spatially isotropic discretizations for low and high Reynolds number flows. Various example solutions are given to illustrate the capabilities of the procedure. This article and been retracted and replaced. See retraction and replacement notice DOI: 10.1002/fld.1247 . Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
44.
    
In this paper, a robust projection method on a locally refined mesh is proposed for two‐ and three‐dimensional viscous incompressible flows. The proposed method is robust not only when the interface between two meshes is located in a smooth flow region but also when the interface is located in a flow region with large gradients and/or strong unsteadiness. In numerical simulations, a locally refined mesh saves many grid points in regions of relatively small gradients compared with a uniform mesh. For efficiency and ease of implementation, we consider a two‐level blocked structure, for which both of the coarse and fine meshes are uniform Cartesian ones individually. Unfortunately, the introduction of the two‐level blocked mesh results in an important but difficult issue: coupling of the coarse and fine meshes. In this paper, by properly addressing the issue of the coupling, we propose a stable and accurate projection method on a locally refined staggered mesh for both two‐ and three‐dimensional viscous incompressible flows. The proposed projection method is based on two principles: the linear interpolation technique and the consistent discretization of both sides of the pressure Poisson equation. The proposed algorithm is straightforward owing to the linear interpolation technique, is stable and accurate, is easy to extend from two‐ to three‐dimensional flows, and is valid even when flows with large gradients cross the interface between the two meshes. The resulting pressure Poisson equation is non‐symmetric on a locally refined mesh. The numerical results for a series of exact solutions for 2D and 3D viscous incompressible flows verify the stability and accuracy of the proposed projection method. The method is also applied to some challenging problems, including turbulent flows around particles, flows induced by impulsively started/stopped particles, and flows induced by particles near solid walls, to test the stability and accuracy. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
45.
    
An empirical investigation is made of AMG solver performance for the fully coupled set of Navier–Stokes equations. The investigation focuses on two different FV discretizations for the standard driven cavity test problem. One is a collocated vertex‐based discretization; the other is a cell‐centred staggered‐grid discretization. Both employ otherwise identical orthogonal Cartesian meshes. It is found that if mixed‐order interpolation is used in the construction of the Galerkin coarse‐grid approximation (CGA), a close‐to‐optimum mesh‐independent scaling of the AMG convergence is observed with similar convergence rates for both discretizations. If, on the other hand, an equal‐order interpolation is used, convergence rates are mesh‐dependent but the scaling differs in each case. For the collocated‐grid case, it depends both on the mesh size, h (or bandwidth Qh?1) and on the total number of grids, G, whereas for the staggered‐grid case it depends only on Q. Comparing the two characteristics reveals that the Q‐dependent parts are very similar; it is only in the G‐dependent convergence for the collocated‐grid case that they differ. This takes the form of stepped reductions in the AMG convergence rate (implying step reductions in the quality of the Galerkin CGA that correlate exactly with step increases in G). These findings reinforce previous evidence that, for optimum mesh‐independent performance, mixed‐order interpolations should be used in forming Galerkin CGAs for coupled Navier–Stokes problems. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
46.
    
A new interface reconstruction method in 3D is presented. The method involves a conservative level‐contour reconstruction coupled to a cubic‐Bézier interpolation. The use of the proposed piecewise linear interface calculation (PLIC) reconstruction scheme coupled to a multidimensional time integration provides solutions of second‐order spatial and temporal accuracy. The accuracy and efficiency of the proposed reconstruction algorithm are demonstrated through several tests, whose results are compared with those obtained with other recently proposed methods. An overall improvement in accuracy with respect to other recent methods has been achieved, along with a substantial reduction in the central processing unit time required. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
47.
    
A methodology is proposed for the calculation of the truncation error of finite volume discretizations of the incompressible Navier–Stokes equations on colocated grids. The truncation error is estimated by restricting the solution obtained on a given grid to a coarser grid and calculating the image of the discrete Navier–Stokes operator of the coarse grid on the restricted velocity and pressure field. The proposed methodology is not a new concept but its application to colocated finite volume discretizations of the incompressible Navier–Stokes equations is made possible by the introduction of a variant of the momentum interpolation technique for mass fluxes where the pressure part of the mass fluxes is not dependent on the coefficients of the linearized momentum equations. The theory presented is supported by a number of numerical experiments. The methodology is developed for two‐dimensional flows, but extension to three‐dimensional cases should not pose problems. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
48.
    
Taking place within more extensive work that focuses on hybrid methods in aeroacoustics, the present study is devoted to the data transfer operations that are to be performed between two stages of a hybrid calculation. More precisely, the article focuses on two typical operations that usually accompany such data transfer, which are (i) the sampling rate reduction and (ii) the interpolation of the unsteady perturbations to be transmitted from one stage to the other. First part of the paper analyzes the two main issues of such operations, which are the spuriousing and the aliasing phenomena. For doing so, the usual notions of the interpolation theory are revisited before they are synthesized within an original approach. The here proposed formalism allows to understand better both the spuriousing and the aliasing phenomena, as well as to accurately predict the impact of the latter on the data to be transmitted in terms of signal degradation. Second part of the paper provides an illustration and a validation of these theoretical developments via a direct application to a typical aerodynamic noise problem (aeroacoustic emission by a 2D cylinder cross flow). There, it is further shown how the here proposed formalism can help in improving aeroacoustics hybrid calculations by predicting (and thus possibly minimizing) the bias to be induced on the acoustic extrapolation stage because of the aliasing and/or spuriousing effects inherited from the sampling rate reduction and/or interpolation of CFD data—which is likely to occur in any hybrid scenario. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
49.
    
Gravity‐driven Stokes flow down an inclined plane over and around multiple obstacles is considered. The flow problem is formulated in terms of a boundary integral equation and solved using the boundary element method. A Hermitian radial basis function (RBF) is used for the interpolation of the free surface, generation of the unit normal and curvature, and to prescribe the far‐field conditions. For flow over an obstacle, hemispheres are taken. For flow around an obstacle, circular cylinders are modelled and the contact angle condition on the obstacle/free surface intersection specified using the RBF formulation. Explicit profiles are produced for flow over and around two obstacles placed in various locations relative to one another. Interaction due to two obstacles is given by comparisons made with the profiles for flow over and around individual obstacles. In general, when the obstacles are separated by a sufficiently large distance the flow profiles are identical to a single obstacle analysis. For flow over and around two obstacles in‐line with the incident flow, effects of the governing parameters are examined, with variations in plane inclination angle, Bond number, obstacle size, and in the case of obstacles intersecting the free surface, static contact angle is considered. Finally flows over and around three obstacles are modelled. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
50.
    
In this paper, we consider a nonlinear finite volume method to solve the steady‐state diffusion equation in nonhomogeneous and non‐isotropic media. The method is nonlinear even if the original problem is linear. In its original form, the scheme is monotone, because the coefficient matrix is monotone under certain assumptions and, as a consequence, whenever the analytic operator demands, it preserves the positivity of numerical solutions. On the other hand, the scheme is unable to reproduce piecewise linear solutions exactly. In order to recover this interesting feature, we use two different interpolation strategies. In this case, even though we are unable to prove monotonicity, we show some numerical evidences that the combined method has an improved behavior, producing second order accurate solutions, even for nonhomogeneous and strongly anisotropic media. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号