Cold crystallization behavior of polyamide 6 in PS‐g‐PA6 graft copolymers

TEM micrographs show that the PA grafts of PS‐g‐PA6 graft copolymers, which are obtained directly by extracting homo‐PA6 out from the homo‐PA6/PS‐g‐PA6 blends, are in the form of wormlike structure. The wormlike PA6 domains can shrink into droplets after annealing at 250 °C for 15 min. The diameter of the droplet determined by TEM and SAXS is in the range of 50–60 nm. This article reports on a unique crystallization behavior of the PA6 grafts in PS‐g‐PA6 graft copolymers. In a DSC cooling scan, PA6 grafts do not crystallize from the melt with a cooling rate of 10 °C/min. However, there is a cold crystallization peak around 65 °C in the subsequent heating scan. This cold crystallization phenomenon, which has not yet been reported in the literature till now, follows well the homogeneous nucleation mechanism and is depressed at relatively slow cooling rates (2 °C/min) or even completely eliminated after annealing within a specific temperature range. It may be caused by the slow diffusion or transport rate of the less flexible PA6 grafts to the crystal fronts when crystallization takes place around its glass transition temperature. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 65–73, 2010     

Effects of cold rolling on the microstructure and mechanical properties of Fe-Ni-Mn-Mo-Ti-Cr maraging steels

Effects of cold rolling on the microstructure and mechanical properties of Fe-Ni-Mn-Mo-Ti-Cr maraging steels were studied.To investigate the microstructure and mechanical properties,optical microscopy,scanning electron microscopy,X-ray diffraction,tensile test,and hardness test were used.The results show that the solution-annealing treatment in the cold-rolled steel redounds to the formation of sub-microcrystalline Fe2(Mo,Ti) Laves phase particles,which are stable at high temperatures.These secondary Laves phase particles prevent from recrystallization at high temperatures and correspond to semi-brittle fracture in the subsequent aging treatment.     

冷轧带材前张力分布及板形与横向厚差关系的研究

本文以现场实测前张力分布为依据，考虑了前张力对板形的影响，建立起板形与横向厚差的关系．定量地解决了前张力分布对板形的影响，对于提高板形控制的计算精度很有实际意义     

用铁塔资料研究地面冷锋的结构

利用铁塔的梯度观测资料研究夜间干冷锋过境进时的边界层结构和部分地面锋面和特征。资料表明近地面，锋面与地表面近于垂直，同附近垂直运动很强，只比水平风速小一个量级，表征湍流变换强度的总体拖是曳系数ＣＤ和热量输送系数ＣＨ在锋面过境前后有明显的响应。并存在着明显的日变化，陆面上白天的ＣＤ和ＣＨ值较海面上大一个量级。     

冷轧带钢计算机厚度自动控制系统

本文介绍４５０三机架冷连轧机计算机厚度自动控制系统的工艺要求、控制决策、硬件设计、数字仿真、软件设计及其运行情况。     

异种钢接头中氢扩散行为及冷裂纹特征

本文采用氚自射线照相法及接头充氢后释放规律的观察，研究了用Ｃｒ２０Ｎｉ１０Ｍｎ６型焊条焊接珠光体类钢时氢的扩散及分布规律。利用高碳钢淬火试样及淬火后充氢试样的拉伸试验，研究了高碳钢淬硬组织对氢和应力的敏感性。探讨了Ｃｒ２０Ｎｉ１０Ｍｎ６／高碳钢接头中不同部位形成裂纹的性质、产生原因和防止措施。所得结论，为正确选用焊条及制定高碳钢的焊接工艺提供了试验和理论依据。     

铈对Ni_3Al性能的影响

在含２０．５ａ％Ａｌ的Ｎｉ３Ａｌ合金中加入铈的研究结果表明：（１）含饰量大约高于０．０４ｗｔ％合金的冷轧性能很差，无法轧成薄材；（２）含铈量为０．０１１ｗｔ％的Ｎｉ３Ａｌ合金，在５５０℃等温１２０ｈ和１２００℃等温０．５ｈ的室温延伸率可达１６％，σｂ为９００ＭＰａ左右，断口为穿晶断裂形貌，综合机械性能好；而７５０℃等温４０ｈ和１０００℃等温１ｈ的室温延伸率仅为３％，σｂ为５００ＭＰａ左右，断口为沿晶形貌，综合机械性能差。     

有蓄冷器冰箱冻室的温度特征

用双集总热容和双等效热阻的模型，讨论了放有蓄冷器的冰箱冷冻室在保冷期的温度特性，给出了蓄冷器温度Ｔｂ，冷冻室壁温Ｔｗ以及冷冻室温度Ｔａ随时间变化的具体关系式，算值与实验作了比较，吻合良好．理论分析的结果，为蓄冷器设计及其与冰箱的良好匹配提供了科学依据．     

自适应控制在冷连轧张力厚控系统中的应用

本文分析了冷连轧机张力厚控系统,表明该系统是时变动态系统,从而确定使用最小方差自校正调节器应用于该系统。对实际系统进行了辨识模型并在此基础上进行了仿真研究。结果表明了自校正调节器控制效果优于PID调节器,而渐消记忆的递推最小二乘法是一种较好的在线辨识算法。将自校正调节器应用于实际张力厚控系统,使得带铜厚差得到明显改善。     

深冷处理工艺对高速钢刀具切削性能的影响

对W_(18)Gr_4V钢制刀具进行不同方式的淬火、回火及深冷处理,凡经深冷处理的刀具,切削寿命均得到提高.其中淬火、三次回火后再进行深冷处理的工艺,切削寿命提高最显著.