Continuous flow electrolytic cold vapor generation atomic fluorescence spectrometric determination of Hg in water samples

The determination of trace concentrations of Hg in water samples by the use of electrolytic cold vapor generation (ECVG) system and AFS was studied. Several buffer solutions were used and the detection limits with these systems were found to be by a factor of 1–2 lower than in the conventional electrolytic cold vapor generation system. Comparing with the traditional inorganic acid, phosphate buffer solution (PBS) increased the signal intensity of Hg vapor from electrolytic generation on Pt cathode and reduced the impact of cathode erosion on the stability of signal intensity. Moreover, buffer solution has better interference tolerance. The effects of the electrolytic conditions and interference ions on the ECVG have been studied. Under optimized conditions and with PBS as catholyte the detection limit for Hg was found to be 0.27 ng L⁻¹. The relative standard deviation was 2.8% for 11 consecutive measurements of 1 μg L⁻¹ Hg. This method has been applied in the determination of inorganic Hg in Yangtze River water.     

寒地保障性住宅外部空间设计

针对寒地城市保障性住宅项目的自身特点以及居住主体的心理行为特征,提出了低收入住宅外部空间设计的经济实用性、行为心理适应性以及地域文化适应性的原则,并根据住区外部空间中存在的问题提出了相应的设计策略,以期对保障性住宅项目的开发建设有借鉴意义。     

剖面不变性与非局部扰动电子温度响应

在ＴＦＴＲ及ＴＥＸＦ等装置上观测到的边界电子冷脉冲的输运现象是通常基于局部热导的瞬态输运理论所无法解释的。利用一个与电子温度剖面不变性相「容的且与在ρ＝ρＬ（ρＬ≈０．７～０．８）处的局部电子热导相关的非局部电子热导模型来描述边界冷脉冲引起的电子温度变化的瞬态过程，发现此模型可定性地解释边界冷脉冲实验现象的几乎所有主要特征。     

Cold Molecules: Preparation,Applications, and Challenges

Research with cold molecules has developed rapidly in recent years. There is now a variety of established methods for cooling molecules into the millikelvin range. Nevertheless, a focal point of current research is directed toward finding new ways to bring the temperature of molecules even closer to absolute zero. Samples of cold molecules offer not only important applications for high‐resolution spectroscopy, which benefit from the increased interaction time of slow molecules with electromagnetic radiation; they also promise access to an exotic regime of chemical reactivity, in which phenomena such as quantum tunneling and quantum resonances predominate. This review begins with an introduction to the methods by which cold molecules can be prepared, with special emphasis on Stark deceleration and traps. In addition to applications of cold molecules that have already been partially achieved, an important focus of the review concentrates on possible future applications, and both aspects are illustrated with selected examples.     

The selective introduction of organometallic markers into estrogens. A-ring propargylation of β-estradiol

Introduction of the propargyl dicobalt hexacarbonyl moiety onto the estradiol A ring as a potential probe in receptor studies requires protection of the ring phenolic group, and the regio-selectivity of the attack (2- versus 4-position) depends on the bulkiness of the organometallic carbenium ion.     

High oven temperature — cold on-column injection for the automated CGC analysis of high molecular weight compounds such as triglycerides

Modification of the Carlo-Erba cold on-column injector for (automated) analysis of high molecular compounds at high oven temperature is described. The secondary cooling tube of the cold on-column injector is replaced by a lengthened tube through which a high air flow is directed. The injection site is maintained at 65–70 °C while the oven is at high temperature (? 300 °C). For automated injection, a short deactivated precolumn of 22 to 30 cm × 0.53 mm i.d. is coupled to the analytical column via a butt connector with make-up gas supply. For a triglyceride mixture, automatically injected at 300 °C, the mean % deviation for all peak areas was 1.8% and the mean % deviation for all retention times was 0.09 % for five consecutive runs.     

Quantum phase transitions of fermionic atoms in an anisotropic triangular optical lattice

The effect of anisotropy caused by a confining potential on the properties of fermionic cold atoms in a triangular optical lattice is systematically investigated by using the dynamical cluster approximation combined with the continuous time quantum Monte–Carlo algorithm.The quantum phase diagrams which reflect the temperature–interaction relation and the competition between the anisotropic parameter and the interaction are presented with full consideration of the anisotropy of the system.Our results show that the system undergoes a transition from Fermi liquid to Mott insulator when the repulsive interaction reaches a critical value.The Kondo effect also can be observed in this system and the pseudogap is suppressed at low temperatures due to the Kondo effect.A feasible experiment protocol to observe these phenomena in an anisotropic triangular optical lattice with cold atoms is proposed,in which the hopping terms are closely related to the lattice confining potential and the atomic interaction can be adjusted via the Feshbach resonance.     

Investigation of the deformation of homogeneous poly(ethylene‐co‐1‐octene) by wide‐ and small‐angle X‐ray scattering using synchrotron radiation

The deformation behavior of homogeneous ethylene‐1‐octene copolymers was investigated as a function of the crystallinity and the crystal size and perfection, respectively, by wide‐ and small‐angle X‐ray scattering using synchrotron radiation. The crystallinity and the crystal size and perfection, respectively, are controlled by the copolymer composition and the condition of melt crystallization. The deformation includes rotation of crystals, followed by plastic deformation and complete melting of the initial crystal population, and final formation of microfibrils. The process of rotation, plastic deformation, and melting of crystals of the initial structure is completed at lower strain if the size and perfection of the crystals, respectively, decrease, that is, if crystals thermally melt at lower temperature. The kinetics of the fibrillation of the initial structure seems independent of the crystal symmetry, that is, rotation and melting of pseudohexagonal and orthorhombic polyethylene crystals (as evident in low‐crystalline specimens) are similar. The structure of the microfibrils, before and after stress release, is almost independent of the condition of prior melt crystallization, which supports the notion of complete melting of the initial crystal population. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 1919–1930, 2002     

深冷处理对金属材料性能的影响及机理探讨

本文主要根据对部分金属材料的深冷处理实验所得的结果,分析和探讨了深冷处理对金属材料性能的影响及机理.     

过氧化物酶同工酶E-酶的变化和棉苗抗寒力的关系

为了提高棉苗抗寒力以抵抗晚霜危害,用给棉苗喷施化学药品的方法在光、暗条件下研完了过氧化物酶同工酶E-酶的变化和棉苗抗寒力的关系。发现棉苗在5℃黑暗下:脱落酸组E-酶活性低,伤害重;添加胆固醇后,E-酶活性提高,伤害减轻.棉苗在27℃下:脱落酸加光各组,E-酶活性高于相应的具有胆固醇的各组,伤害加重。添加胆固醇后,E-酶活性相对降低,伤害减轻;在脱落酸加光各组和胆固醇加脱落酸加光各组,随着光强度降低,叶绿素a/b比值均降低,但E-酶活性在前者降低,棉苗伤害加重,在后者升高,棉苗伤害减轻。光强度的变化在二者中起着相反的调节作用。500lx加脱落酸加胆固醇处理的棉苗健壮无伤害。