Summary: A series of helix‐coil diblock copolymers based on poly(ethylene oxide) and optically active helical poly{(+)‐2,5‐bis[4′‐((S)‐2‐methylbutoxy)phenyl]styrene} (PMBPS) were synthesized via atom transfer radical polymerization (ATRP). The synthetic methodology permitted straightforward preparation of the diblock copolymers with relatively low polydispersities and a broad range of compositions and molecular weights. Depending on the composing block length and the initial concentration, the copolymers self‐assembled into different supramolecular structures in aqueous solution, including spherical micelles, vesicles, multilamellar vesicles, large compound vesicles, and tubules.
Schematic representation of the synthesis of PEO‐b‐PMBPS block copolymers and their aggregation in aqueous solution. 相似文献
Summary: We have prepared hexa‐p‐phenylene based rod‐coil molecules with identical coil volume fractions, but different poly(propylene oxide) (PPO) coil architectures (linear versus dibranched), and investigated their self‐assembling behavior in the solid state by small angle X‐ray scattering (SAXS) and transmission electron microscopy (TEM) techniques. Rod‐coil molecules with a linear PPO coil showed a honeycomb‐like lamellar assembly of rod segments with hexagonally arrayed PPO coil perforations. In contrast, the rod‐coil molecules with dibranched PPO coils self‐organized into rod bundles with a body centered tetragonal symmetry surrounded by a PPO coil matrix. These results demonstrate that the steric hindrance at the rod/coil interface arising from coil architectural variation is a dominant parameter governing supramolecular rod assembly in the rod‐coil system.
TEM images and schematic illustrations of the self‐assembled structures of rod‐coil molecules with linear (left) and dibranched (right) PPO coils, respectively. 相似文献
A transient multi-physics model incorporated with an electromagneto-thermomechanical coupling is developed to capture the multi-field behavior of a single-pancake (SP) insert no-insulation (NI) coil in a hybrid magnet during the charging and discharging processes. The coupled problem is resolved by means of the finite element method (FEM) for the magneto-thermo-elastic behaviors and the Runge-Kutta method for the transient responses of the electrical circuits of the hybrid superconducting magnet system. The results reveal that the transient multi-physics responses of the insert NI coil primarily depend on the charging/discharging procedure of the hybrid magnet. Moreover, a reverse azimuthal current and a compressive hoop stress are induced in the insert NI coil during the charging process, while a forward azimuthal current and a tensile hoop stress are observed during the discharging process. The induced voltages in the insert NI coil can drive the currents flowing across the radial turns where the contact resistance exists. Therefore, it brings forth significant Joule heat, causing a temperature rise and a uniform distribution of this heat in the coil turns. Accordingly, a thermally/mechanically unstable or quenching event may be encountered when a high operating current is flowing in the insert NI coil. It is numerically predicted that a quick charging will induce a compressive hoop stress which may bring a risk of buckling instability in the coil, while a discharging will not. The simulations provide an insight of hybrid superconducting magnets under transient start-up or shutdown phases which are inevitably encountered in practical applications. 相似文献
Heating-only fan coil(HFC) is one of the suited end users.which is not only compact but also highly efficient.And the major factors affecting the heat dissipation performance of HFC include leakage through coil bypass,distance between fan and coil,fan structure and air inlet type.Under natural air convection or forced,experimental studies were made on the effects of these factors upon the heat dissipation performance of HFC.The results show that:1)After reducing the leakage through coil bypass,the heat dissipation of HFC in-creases 16.9%under natural convection,and increases 8.3%under forced convection.2)After the distance be-tween fan and coil be raised from 23.2cm to 41.7cm.the heat dissipation of HFC decreases 21.3%under natu-ral convection,but increasesl2.8%under forced convection.3)After changing the fan structure,the heat dissi-pation of HFC increases 41.8%under natural convection.and the heat dissipation per motor power increases 96.1%under forced convection.4)The heat dissipations of HFC with round pass,slit and strip type of air inlet are different,whose proportion is about 100%,110%,136%under natural convection,and 100%,105%,116%under forced convection. 相似文献