A new and general synthesis of chiral β-ketosulfoxides by reaction of (+)-(R)-methyl p-tolyl sulfoxide with nitriles

The nitrile functional group is efficiently transformed into the β-ketosulfoxide moiety by reaction with the anion formed from (+)-(R)-methyl p-tolyl sulfoxide and aqueous acidic work-up of the reaction.     

伪极谱法对镉氟配合物积累稳定常数的测定

研究了用伪极谱法测定镉在氟化物体系中与氟形成配合物的积累稳定常数 .结果表明 :Cd( )在氟化物体系中的伪极谱行为符合可逆电极反应伪极谱理论 .在镉浓度为 2× 1 0 -7mol· L-1、p H=8的条件下 ,测得镉与氟形成配合物的组成分别为 Cd F 、Cd F2 ,其积累稳定常数分别为 2 .95和 3.4 2 ,与文献值基本一致     

The mechanism of formation of copper aluminide in the thermal explosion mode

The mechanism of formation of copper aluminides in the thermal explosion mode was studied. A molded mixture of copper and aluminum powders was heated to the self-ignition temperature by the radiation of a tungsten heater. The phase transformations were detected by time-resolved X-ray diffraction (TRXRD). The kinetics of heat release due to the chemical reaction was studied by measuring the temperature of the sample. The macrokinetic stages of the process were revealed, and the apparent activation energy of each stage was estimated.     

储层潜在敏感性B-P网络快速预测方法研究

对神经网络算法以及利用神经网络进行敏感性预测中经常出现的问题进行了探讨。着重介绍了合理网络结构的确定方法、学习样本的搜集与处理以及学习算法的改进等 ,并建立了改进的B P算法。通过水敏性预测 ,介绍了神经网络在敏感性预测中的具体应用过程 ,并对其在实际生产中的应用效果进行了验证。结果表明 ,利用改进后的神经网络对储层敏感性进行预测的方法 ,具有预测精度高、自适应好、容错能力强等优点。为了便于使用 ,编制了功能完备的敏感性预测软件 ,现场使用效果良好。     

Regio- and stereoselective synthesis of 1-aryl-1-thio-2-thiophosphinylethene derivatives via a radical process

Radical additions of S-thiophosphinyl dithiocarbonate to terminal aromatic alkynes afford (E)-1-aryl-1-thio-2-thiophosphinylethene derivatives regio- and stereoselectively in high yields. The transformations of the products are also described.     

旋流扩散燃烧中旋流数对热NO生成的影响

本文对旋流扩散燃烧进行了数值模拟，研究旋流数对热ＮＯ生成的影响，其中对湍流采用Ｒｅｙｎｏｌｄｓ应力方程模型，对燃烧采用ＥＢＵ－Ａｒｒｈｅｎｉｕｓ模型，对热ＮＯ生成采用设定ＰＤＦ的模型。预报了不同旋流数下轴向和切向的平均和脉动速度、温度和ＮＯ浓度，指出随着旋流数的增大，计算得到的出口平均ＮＯ浓度首先升高然后下降。这一趋势和本文作者最近的实验结果的趋势一致．随着旋流数的增大，湍流脉动首先下阵然后升高，而进口附近的温度上升，二者综合效果造成上述趋势、因此在实际燃烧器中，完全靠改变族流数来控制ＮＯ生成是不现实的。应该采取其他方法来降低ＮＯ的生成。     

谈汉语书面歧义结构的形成

从语言系统的内部来看，现代汉语书面歧义结构的形成可分为语言，语义，语法三个平面，语音平面的因素有轻声，重音，停顿，声调，同音词等；语法平面的因素有兼类词，语法结构层次，语法结构关系等，语义平面的因素有词的多义，语义结构关系等。     

Concurrent formation of two different type precipitation-free zones during the initial stage of homogenization

Transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy were used to study the microstructure evolution of Al–Cu–Mg alloy during the initial stage of homogenization. It was found that two types of precipitation-free zones (PFZs) can form concurrently: one near grain boundaries and the other at the grain centres. Depth profile analyses of solute concentrations and dislocation-loop distributions strongly suggested that the formations of the two type of PFZs are different, due solely and exclusively to solute and vacancy depletion, respectively. A mechanism model was proposed to explain the concurrent formation of the two different type of PFZs during the initial stage of homogenization.     

Persistent oscillations in a threshold adjustment model

In this paper we present a simple time-continuous behavioural model of habit formation. Addictive behaviour is damped by a threshold which adapts itself to the habit. This adaptive behaviour of the threshold may lead to periodic fluctuations of the consumption rate, the habit and the threshold. It turns out that both a low adjustment rate of the threshold as well as a steep consumption function favour oscillatory patterns.