全文获取类型
收费全文 | 9998篇 |
免费 | 767篇 |
国内免费 | 1033篇 |
专业分类
化学 | 4912篇 |
晶体学 | 126篇 |
力学 | 507篇 |
综合类 | 40篇 |
数学 | 353篇 |
物理学 | 1876篇 |
综合类 | 3984篇 |
出版年
2024年 | 25篇 |
2023年 | 95篇 |
2022年 | 195篇 |
2021年 | 219篇 |
2020年 | 219篇 |
2019年 | 215篇 |
2018年 | 207篇 |
2017年 | 267篇 |
2016年 | 306篇 |
2015年 | 338篇 |
2014年 | 440篇 |
2013年 | 588篇 |
2012年 | 517篇 |
2011年 | 578篇 |
2010年 | 422篇 |
2009年 | 538篇 |
2008年 | 526篇 |
2007年 | 661篇 |
2006年 | 565篇 |
2005年 | 515篇 |
2004年 | 493篇 |
2003年 | 416篇 |
2002年 | 696篇 |
2001年 | 347篇 |
2000年 | 336篇 |
1999年 | 249篇 |
1998年 | 266篇 |
1997年 | 225篇 |
1996年 | 186篇 |
1995年 | 173篇 |
1994年 | 164篇 |
1993年 | 152篇 |
1992年 | 122篇 |
1991年 | 100篇 |
1990年 | 82篇 |
1989年 | 87篇 |
1988年 | 59篇 |
1987年 | 42篇 |
1986年 | 37篇 |
1985年 | 28篇 |
1984年 | 19篇 |
1983年 | 11篇 |
1982年 | 18篇 |
1981年 | 15篇 |
1980年 | 8篇 |
1979年 | 10篇 |
1978年 | 7篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1973年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
机械球磨与反应烧结合成Sr2CeO4发光体的研究 总被引:10,自引:0,他引:10
Sr2CeO4 phosphor was synthesized by mechanical milling and reactive sintering in this work. The solid state reaction of SrCO3and CeO2 (2∶1) started at about 850 ℃ and completed at 1 000 ℃ for about 4 h. Two types of formation mechanism of Sr2CeO4 were proposed. When the starting powder mixture was fired above 1 000 ℃, the unstable intermediate phase SrCeO3was developed, which then reacted with SrCO3to form the final product Sr2CeO4, however, SrCO3and CeO2 converted directly to Sr2CeO4 at a lower temperature. The XRD results showed the crystal structure of Sr2CeO4 was orthorhombic. The emission spectra displayed a broad band with maximum at about 465 nm. The mechanical milling of starting power mixture and the sintering temperature had no effect on this emission spectra. 相似文献
82.
有机硅耐磨透明涂层的固化分析 总被引:13,自引:0,他引:13
FTIR、TG、TBA等对有机硅耐磨涂料(有机硅溶胶)的热固化过程研究表明有机硅胶体中缔合羟基间的脱水缩合速率很高;羟基脱水程度与固化温度有关,温度越高,达平衡时羟基的浓度越低,在105~130℃间羟基的浓度变化最大,加入适当的固化剂,对羟基的脱水交联有促进作用,在较高的固化温度下,反应体系中出现了环氧环异构化产生的酮羰基的吸收峰 相似文献
83.
Zdeněk Slanina 《Journal of Cluster Science》2004,15(1):3-11
Computational findings of temperature increase of clustering degree in saturated vapors are analyzed. A thermodynamic proof is presented and a simple criterion derived. Illustrations are based on saturated steam, magnesium and carbon vapor. The results are applicable to synthesis of fullerenes, metallofullerenes, and heterofullerenes, chemical vapor deposition technique, or atmospheric chemistry. 相似文献
84.
Gáti T Simon A Tóth G Magiera D Moeller S Duddeck H 《Magnetic resonance in chemistry : MRC》2004,42(7):600-604
Adducts of four phosphine chalcogenides with the chiral dirhodium complex ([Rh-Rh]) were investigated by variable-temperature 1H and 31P NMR spectroscopy in order to compare their properties as axial ligands. Whereas the selenide (1) and the sulfide (2) are strong ligands with electrostatic attraction and, in addition, a significant orbital (HOMO-LUMO) interaction, the phosphine oxide compounds (P=O) bind primarily via electrostatic attraction and are relatively weak donors. Moreover, the overall bond strength in these adducts depends on steric congestion around the P=O group. 相似文献
85.
P. Etienne J. Denape J. Y. Paris J. Phalippou R. Sempere 《Journal of Sol-Gel Science and Technology》1996,6(3):287-297
Transparent plastics are not scratch resistant. The damage leads to a loss of optical properties. Coatings prepared using either tetraethoxysilane or colloidal silica particles embedded in glymo is a way to avoid these disadvantages. Tribological experiments are carried out to better understand the surface modification due to a sliding friction. It is shown that the wear track is not directly related to usual mechanical properties such as Young's modulus and the hardness of the coating. The different stages leading to material loss are discussed in term of particle removal and debris circulation (accumulation or elimination) through the friction track. The mechanical properties of the film combined with the film to substrate adhesion are expected to play an important role as it can be deduced from results obtained as a function of the coating composition. 相似文献
86.
A scratch-resistant single-layer antireflective coating by a low temperature sol-gel route 总被引:1,自引:0,他引:1
A novel quarterwave-thick narrow-bandwidth antireflective coating has been developed for both plastic and vitreous substrates by a sol-gel route. This coating has revealed pronounced scratch- and climatic-resistance under adverse conditions. The single-layer coating consists basically of a composite material made of silica as the discontinuous phase and of a polytetrafluoroethylene-derived (Teflon1) organic polymer as the continuous phase. This leads to fluorine-containing colloidal silica product, or a so-called Flucosil coating. The coating is applied by spinning or dipping from specific solutions at room temperature followed by a mild and short heat treatment. In addition to remarkable abrasion and environmental resistance properties, such coatings have displayed excellent laser-induced damage threshold levels, surpassing uncoated substrates.We hope such a product might open new perspectives concerning household articles, architectural optical thin-films, ophthalmic uses, and so on. 相似文献
87.
Preparation of flame retardant polyamide 6 composite with melamine cyanurate nanoparticles in situ formed in extrusion process 总被引:1,自引:0,他引:1
This paper is focused on in situ preparation of melamine cyanurate (MCA) nanoparticles from reaction of melamine (MEL) and cyanuric acid (CA) and their flame retardant polyamide 6 (PA6) composite in the extrusion process through a novel reactive processing method. Fourier transform infrared (FT-IR), X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and scanning electron microscopy (SEM) were utilized to characterize the in situ formed MCA nanoparticles and their blends with PA6. Introduction of pentaerythritol (LTP) and water-bound plasticizer dioctyl phthalate (DPT) into the extrusion reaction system greatly inhibits the evaporation of water required for melamine and cyanuric acid reaction at high temperature (higher than 180 °C), laying a foundation for successful in situ preparation of MCA through reactive processing. XRD and FT-IR measurements indicate that under the effect of pentaerythritol, dioctyl phthalate and water, melamine really reacts with cyanuric acid to in situ form MCA in extrusion process. The reaction degree is close to 100%. A very important finding through SEM is that the in situ formed MCA particles, which were found to have aspect ratio of about 7.5, radial size in the range of 70-300 nm (mostly 70-90 nm) and crystallite size of less than 22 nm, are uniformly dispersed in the matrix PA6 at nanoscale. The in situ formed MCA nanoparticles greatly improve the flame retardancy and the mechanical properties of flame-retarded PA6 materials, and the introduced plasticizer dioctyl phthalate also ameliorates the related impact property. The obtained flame-retarded PA6 materials have good comprehensive performance with flame retardancy UL-94 V-0 rating at 1.6 and 3.2 mm thickness, tensile strength 48.0 MPa, elongation at break 106.3% and Izod notched impact strength 8.92 kJ/m2. Compared with flame-retarded PA6 material with in situ formed MCA, the one prepared through conventional blending of PA6 with commercial MCA product has improved tensile strength but deteriorated impact strength and flame retardancy. 相似文献
88.
Feng Gao 《Polymer Degradation and Stability》2006,91(6):1295-1299
A novel phosphorus-nitrogen containing intumescent flame retardant (P-N IFR) was prepared via the reaction of a caged bicyclic phosphorus (PEPA) compound and 4,4′-diamino diphenyl methane (DDM) in two steps. The product was added to poly(butylene terephthalate) (PBT) to obtain halogen-free flame retarded polyester. UL-94 test, thermogravimetry and in situ infrared spectroscopy were used to characterize the flammability, thermal degradation properties and the char-forming process. It was shown that the phosphorus-nitrogen containing compound could improve both the flame retardancy and thermal stability more effectively than other P-N flame retardants. Furthermore, it was a good char-forming agent incorporated with the co-addition of polyurethane (PU) when the combustion occurred. The formation of P-N structure was incorporated in the char layer. 相似文献
89.
Jun Shen Tianhe Yang Qinyuan Zhang Jue Wang Qinyao Zhang 《Journal of Sol-Gel Science and Technology》2003,26(1-3):1029-1032
In GaAs based infrared detectors, a considerable part of the incident light will be reflected at the surface, thus it decreases the detectors sensitivity considerably. In this paper, a TiO2 nanoporous coating was prepared successfully on the GaAs substrate by sol-gel method. The optical parameters of the coating were also controlled successfully. It was proved that the coating could greatly improve the transmittance of the incident light, which agrees with the theoretical results quite well. In the 2.5–6.0 m waveband, the maximum transmittance of GaAs substrate is 56%, while the transmittance of the GaAs substrate coated with a nanostructured TiO2 coating is about 94%. 相似文献
90.
利用精密自动绝热热量计直接测定了配合物Zn(Phe)(NO3)2·H2O(s) (Phe:苯丙氨酸)在78-370 K温区的摩尔热容. 通过热容曲线的解析得到该配合物的起始脱水温度为, T0=(324.27±0.37) K. 将该温区的摩尔热容实验值用最小二乘法拟合得到摩尔热容(Cp, m)对温度(T)的多项式方程, 并且在此基础上计算出了它的舒平热容值和各种热力学函数值. 依据Hess定律, 通过设计热化学循环, 选择体积为100 mL浓度为2 mol·L-1 的盐酸作为量热溶剂, 利用等温环境溶解-反应热量计分别测定混合物{ZnSO4·7H2O(s)+2NaNO3(s)+L-Phe(s)}和{Zn(Phe)(NO3)2·H2O(s)+Na2SO4(s)}的溶解焓为, ⊿dH0m,1 =(69.42±0.05) kJ·mol-1, ⊿dH0 m,2 =(48.14±0.04) kJ·mol-1, 进而计算出该配合物的标准摩尔生成焓为, ⊿fH0m =-(1363.10±3.52) kJ·mol-1. 另外, 利用紫外-可见(UV-Vis)光谱和折光指数(refractiveindex)的测量结果检验了所设计的热化学循环的可靠性. 相似文献