Atom transfer radical polymerization directly from poly(vinylidene fluoride): Surface and antifouling properties

The direct preparation of grafting polymer brushes from commercial poly (vinylidene fluoride) (PVDF) films with surface‐initiated atom transfer radical polymerization (ATRP) is demonstrated. The direct initiation of the secondary fluorinated site of PVDF facilitated grafting of the hydrophilic monomers from the PVDF surface. Homopolymer brushes of 2‐(N,N‐dimethylamino)ethyl methacrylate (DMAEMA) and poly (ethylene glycol) monomethacrylate (PEGMA) were prepared by ATRP from the PVDF surface. The chemical composition and surface topography of the graft‐functionalized PVDF surfaces were characterized by X‐ray photoelectron spectroscopy, attenuated total reflectance/Fourier transform infrared spectroscopy, and atomic force microscopy. A kinetic study revealed a linear increase in the graft concentration of poly[2‐(N,N‐dimethylamino)ethyl methacrylate] (PDMAEMA) and poly[poly(ethylene glycol) monomethacrylate] (PPEGMA) with the reaction time, indicating that the chain growth from the surface was consistent with a controlled or living process. The living chain ends were used as macroinitiators for the synthesis of diblock copolymer brushes. The water contact angles on PVDF films were reduced by the surface grafting of DMAEMA and PEGMA. Protein adsorption experiments revealed a substantial antifouling property of PPEGMA‐grafted PVDF films and PDMAEMA‐grafted PVDF films in comparison with the pristine PVDF surface. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3434–3443, 2006     

浅埋煤层开采中的溃沙灾害研究

分析了浅埋煤层开采的水文条件和工程地质条件，得出了浅埋煤层发生渍沙灾害必须具备的4个条件；根据浅埋煤层中组合关键层的一些参数分析了老顶破断岩块的运动规律，判断了浅埋煤层开采中岩块是否发生回转失稳，探讨了岩块回转触矸后发生滑落失稳的可能性，计算了断裂岩块端角接触面高度，得出了满足裂隙滤沙的合理端角接触面高度；大柳塔1203工作面开采只发生了涌水而未溃沙，这和理论计算的结论基本一致．参8．     

A procedure for measuring the flexibility of single wood-pulp fibres

A way of determining the flexibility of wood-pulp fibres is developed, which involves i) a precise measurement of the topology of single-fibres by using a confocal laser scanning microscope and ii) the measurement of the elastic modulus of the fibres by using a single-fibre fatigue cell. Reported in this paper are the initial results of tests carried out on black spruce fibres, which have been subjected to three different levels of mechanical refining energy, namely ∼1100, 2300, and 3500 kWh/t. It is found that the fibre flexibility rises significantly between the first and second energy levels, but it does not change to the same degree between the second and third ones. The described procedure of measuring the flexibility of fibres may be used to establish the appropriate refiner energy necessary for the production of a specific grade of paper. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 42, No. 1, pp. 115–128, January–February, 2006.     

老屋基矿防治煤与瓦斯突出问题的分析和探讨

介绍了老屋基矿采、掘工作面防突措施情况，总结了老屋基矿防治煤与瓦斯突出措施取得的效果。     

浅论煤核的形成及其地质意义

根据煤核的产状与形态，分析了煤核的形成机理及形成条件，研究探讨了煤核形成的地质意义。     

发动机的曲轴转速方程及其近似解

从活塞发动机的动力分析中得到本文中的微分一积分方程(4),其中α为曲轴转角,θ为角速度的平方,而ε<<1为总等效转动惯量的倒数。本文利用压缩映象原理和摄动方法证明了所得方程解的存在性和唯一性,并给出了这个解的渐近展开。     

关于Gerber不等式的一个猜想

本文证明了陈计-单墫关于Ｇｅｒｂｅｒ不等式的一个猜想，作为其应用，导出了单形内一点到顶点的距离与到面的距离的两个不等式．     

双密度层空气重介流化床的研究

对双密度层空气重介流化床的形成和分选过程进行了研究,论证了现有的空气重介流化床难于进行有效的三产品分选,确定了具有锥形过渡段的特殊床型结构,形成了可用于三产品分选的双密度层空气重介流化床.     

SO(n,1) Wigner rotation as an SL(2,R) problem

We show that the composition of not only two SO(3,1) boosts, but also that of two SO(n,1) boosts for anyn 2, is basically an SO(2,1) problem and hence can be analysed completely using SL(2,R) matrices. By computing the expression for the Thomas/Wigner angle directly using SL(2,R) matrices we show that this approach results in considerable economy of algebra.