饱和黏土的一维热固结特性试验研究

通过室内试验,研究了饱和黏土在不同温度作用下的固结效应.结果表明:温度对土颗粒的膨胀作用和孔隙比的收缩作用影响较小;高温作用下发生的热膨胀在一定程度上阻碍了变形的发生,高温条件下压缩指数较低温条件下有减小的趋势.但渗透性的增强使得该现象逐渐减弱.随着温度的升高,先期固结应力均随之减小.通过反分析得到了两种黏土的材料参数γ.材料参数γ越大,相同温度下的归一化先期固结应力越小.温度越高,水溶液的黏度越低,越容易被排出,其渗透系数越大,超静孔隙水压的消散越快,所以超静孔隙水压随着温度的升高而减小.渗透系数随着孔隙比的升高而升高.粒径较大试样的渗透系数大于粒径较小试样的渗透系数.     

Synthesis of attapulgite-MnO2 nanocomposite from manganese complex by ultrasound for hydrogen storage

The research included the synthesis of a new complex of manganese with 3,4,5-tri-methoxybenzoic acid in the presence of triethylamine as a base to which gives the complex with formula [Mn (TMB)₂].2H₂O. This complex was characterized by FTIR, CHN, magnetic susceptibility and thermal analysis. Furthermore, this complex was used as a novel precursor of manganese in preparing the attapulgite-MnO₂ nanocomposite by one-pot addition method using ultrasound. The resulting nanocomposite was characterized by X-ray diffraction and TEM and the results prove that this composite was found as nanochannel of the diameter 45 nm decorated with 26–41 nm of MnO₂ nanoparticles. The attapulgite-MnO₂ nanocomposite was used in the application of hydrogen storage, and the results proved that attapulgite-MnO₂ nanocomposite has the ability to store 3.55 wt% of hydrogen under a pressure of 90 bar and a temperature of 77 K. Furthermore, the measurement demonstrated that increasing the pressure increased the stored hydrogen, implying that the stored gas will be liberated by altering the pressure, implying that the storage will be of the physical kind.     

Micro-CT参数对骨质疏松性椎体压缩性骨折术后复发的预测价值

本研究探讨Micro-CT参数对骨质疏松性椎体压缩性骨折(OVCF)患者术后复发的预测价值。选取OVCF患者127例,根据术后6个月骨折复发情况分为复发组(n=41)与未复发组(n=86)。患者均接受Micro-CT检查,对比两组Micro-CT参数,即骨体积分数(BV/TV)、骨小梁厚度(Tb.Th)、骨小梁间隙(Tb.Sp)、结构模型指数(SMI),以及骨密度(BMD)、骨矿含量(BMC),分析各参数与BMD、BMC及术后复发相关性,并评价各参数对术后复发的预测价值。结果显示,复发组骨体积分数(BV/TV)、骨小梁厚度(Tb.Th)低于未复发组,骨小梁间隙(Tb.Sp)、结构模型指数(SMI)高于未复发组(P<0.05);BV/TV、Tb.Th与骨密度(BMD)、骨矿含量(BMC)呈正相关,Tb.Sp、SMI与BMD、BMC呈负相关(P<0.05);将年龄、BMD、BMC等其他因素控制后,BV/TV、Tb.Sp、Tb.Th、SMI与OVCF术后骨折复发显著相关(P<0.05);BV/TV、Tb.Sp、Tb.Th、SMI联合预测OVCF术后骨折复发的曲线下面积(AUC)最大,为0.888(P<0.05)。提示Micro-CT参数在OVCF患者中呈异常表达,采用Micro-CT检查可为临床预测OVCF术后骨折复发提供科学指导。     

Nanocomposite Polymer Electrolytes of Sodium Alginate and Montmorillonite Clay

Nanocomposite polymer electrolytes (NPEs) were synthesized using sodium alginate (Alg) and either sodium (SCa-3-Na⁺)- or lithium (SCa-3-Li⁺)-modified montmorillonite clays. The samples were characterized by structural, optical, and electrical properties. SCa-3-Na⁺ and SCa-3-Li⁺ clays’ X-ray structural analyses revealed peaks at 2θ = 7.2° and 6.7° that corresponded to the interlamellar distances of 12.3 and 12.8 Å, respectively. Alg-based NPEs X-ray diffractograms showed exfoliated structures for samples with low clay percentages. The increase of clay content promoted the formation of intercalated structures. Electrochemical Impedance Spectroscopy revealed that Alg-based NPEs with 5 wt% of SCa-3-Na⁺ clay presented the highest conductivity of 1.96 × 10⁻² S/cm², and Alg with 10 wt% of SCa-3-Li⁺ showed conductivity of 1.30 × 10⁻² S/cm², both measured at 70 °C. From UV-Vis spectroscopy, it was possible to infer that increasing concentration of clay promoted a decrease of the samples’ transmittance and, consequently, an increase of their reflectance.     

Chemical Composition,Antioxidant and Antimicrobial Activity of Raspberry,Blackberry and Raspberry-Blackberry Hybrid Leaf Buds

In our investigation, the chemical composition and bioactive potential of leaf buds of raspberry, blackberry, and a raspberry-blackberry hybrid were determined. Antioxidant and antimicrobial properties were tested in water (W), ethanol-water (EW), and glycerol-water (GW) extracts from the buds. These plant organs contain relatively large amounts of minerals, especially Fe. The total antioxidant capacity (TAC) measured by the ABTS and DPPH methods ranged from 2.86 to 12.19 and 6.75 to 24.26 mmol per 100 g fresh weight (FW) of buds, respectively. TAC values were generally higher in the raspberry than in the case of blackberry and raspberry-blackberry hybrid extracts. The antioxidant properties of the extracts were strongly positively correlated with their content of total phenolic (TP). No such relationship was noted for ascorbic acid (AA), whose concentration in all extracts was at a similarly low level. Antioxidant properties determined in vitro were confirmed for the GW extract from raspberry leaf buds in biological test based on the growth parameters of Δsod1 Saccharomyces cerevisiae mutant cells in hypertonic medium. The extracts also exhibited strong antibacterial properties against Staphylococcus aureus and Enterococcus faecalis and weaker against Enterobacter aerogenes. The studied leaf buds could be therefore an unconventional source of minerals, natural antioxidants and antibacterial compounds with potential applications in the food, pharmaceutical, and cosmetics industries.     

黄河山陕峡谷保德-克虎段高阶地砾石层的初步研究

野外考察发现山西黑峪口地区存在七级阶地序列,其中上覆红粘土的T6、T7阶地为晚第三纪阶地.对该区阶地上砾石的岩性和粒径进行了研究,岩性对比表明,T6、T7阶地上砾石的岩性与黄河低阶地上砾石的岩性相似,而与东西向的蔚汾河阶地岩性差别较大;上下游之间对比发现,灰岩砾石岩性由保德地区占主导地位到克虎地区退居次要地位,灰岩砾石的粒径也从上游向下游变小,说明该区晚第三纪阶地并非东西向河流形成的,而是古黄河或古南北向水系的产物.T7阶地上覆盖厚度70m以上的粉、细砂层和晚第三纪红土层,磁性地层研究表明,该层的底部时代在6.8Ma左右,T6阶地上覆红粘土的底部年龄在3.3Ma左右,山陕峡谷由北向南流的古河流在6.8Ma之前已经形成,T6阶地的形成时代与青藏运动A幕相对应.青藏运动A幕以来河流在该区下切了160m,平均下切速率约为青藏运动A幕以前平均下切速率的5倍以上.     

宁波市北仑区普通建筑石料矿产资源开发利用研究

针对宁波市北仑区矿产资源规划实施过程中存在的问题展开调查,调查包括议定方案、矿山实地调查、了解市场需求、综合分析资料。并对各种有待完善和需要调整、补充的问题提出应采取的对策和可操作性的建议。     

论卤盐养生（10）

卤盐（包括食盐）是中国矿物药的重要组成部分。从文化价值、临床应用和情志调摄3个方面诠释了卤盐的养生学意义,并全面、详细地阐述了食盐对中国古代文化的四大贡献、6种盐类的现代临床应用价值以及盐湖旅游的6项要素;列举了160多个盐湖卤水的主要化学成分、矿化度或微量元素;摘录了论述卤盐主治功用的古今文献。本文分期刊出。