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971.
-Butyrolactone (hereafter abbreviated GBL) is produced by the two-stage hydrogenation of maleic anhydride(MAH) in the liquid phase: the hydrogenation of MAH to succinic anhydride(SAH) in the first stage and the subsequent hydrogenation of SAH to GBL in the second stage. A novel ruthenium catalyst system consisting of Ru salts, trialkylphosphine and p-toluene sulfonic acid (p-TsOH) was found very effective for the hydrogenation of SAH affording GBL, which exhibited excellent catalyst performance, exceeding 97% selectivity for GBL and high activity. 相似文献
972.
Tautomerism of Nunsubstituted benzohydroxamic acids and their anions in the gas phase was investigated by the semiempirical AM1 method. The possibility of estimating pK
a in aqueous solutions using calculated characteristics of molecules is demonstrated. 相似文献
973.
Gololobov Yu. G. Petrovskii P. V. Ivanova E. M. Linchenko O. A. Schmutzler R. Ernst L. Jones P. G. Karaçar A. Freytag M. Okucu S. 《Russian Chemical Bulletin》2003,52(2):427-436
The reactions of meta—para-substituted aryl isocyanates with phosphorus-containing 1,3-zwitterions, which proceed with the CN migration of the CO2Et group to form the corresponding carbamates, were extended to ortho-substituted aryl isocyanates. The influence of the steric and electronic effects of the ortho substituents in the aromatic rings of aryl isocyanates on the ease of this rearrangement is qualitatively considered. 相似文献
974.
Vinogradov M. G. Gorshkova L. S. Chel'tsova G. V. Kurilov D. V. Ferapontov V. A. Shishk O. V. Heise G. L. 《Russian Chemical Bulletin》2003,52(8):1841-1846
An improved procedure was developed for asymmetric reduction of acetophenone and propiophenone by the chiral reagent NaAl(IPTOLate)H2. This procedure is based on isolation of the chiral alcohol that formed as a crystalline host—guest complex with the IPTOL ligand. The enantiomeric enrichment of the product was as high as 97% ee. The ability of IPTOL and its analogs to form host—guest complexes with a number of ether-type solvents, 1-phenylethanol, and 1-phenylpropan-1-ol as well as thermal stabilities of IPTOL-containing complexes with these alcohols were studied. 相似文献
975.
976.
Dr. Lin Ren Dr. Masoumeh Dowlatshahi Pour Dr. Per Malmberg Prof. Andrew G. Ewing 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(21):5406-5411
A micromolar concentration of zinc has been shown to significantly change the dynamics of exocytosis as well as the vesicle contents in a model cell line, providing direct evidence that zinc regulates neurotransmitter release. To provide insight into how zinc modulates these exocytotic processes, neurotransmitter release and vesicle content were compared with single cell amperometry and intracellular impact vesicle cytometry with a range of zinc concentrations. Additionally, time-of-flight secondary ion mass spectrometry (ToF-SIMS) images of lipid distributions in the cell membrane after zinc treatment correlate to changes in exocytosis. By combining electrochemical techniques and mass spectrometry imaging, we proposed a mechanism by which zinc changes the fusion pore and the rate of neurotransmitter release by changing lipid distributions and results in the modulation of synaptic strength and plasticity. 相似文献
977.
Kun Wang Xia Guo Chennan Ye Yulong Wang Yuan Meng Xiaojie Li Prof. Maojie Zhang 《Chemphyschem》2019,20(20):2674-2682
To achieve high open-circuit voltage (Voc) and low acceptor content, the molecular design of a small-molecule donor with low energy loss (Eloss) is very important for solution-processable organic solar cells (OSCs). Herein, we designed and synthesized a new coplanar A−D−A structured organic small-molecule semiconductor with non-fused ring structure π-bridge, namely B2TPR , and applied it as donor material in OSCs. Owing to the strong electron-withdrawing effect of the end group and the coplanar π-bridge, B2TPR exhibits a low-lying highest occupied molecular orbital and strong crystallinity. Furthermore, benefiting from the coplanar molecular skeleton, the high hole mobility, balanced charge transport and reduced recombination were achieved, leading to a high fill factor (FF). The OSCs based on B2TPR : PC71BM blend film (w/w=1 : 0.35) demonstrates a moderate power conversion efficiency (PCE) of 7.10 % with a remarkable Voc of 0.98 V and FF of 64 %, corresponding to a low fullerene content of 25.9 % and a low Eloss of 0.70 eV. These results demonstrate the great potential of small-molecule with structure of B2TPR for future low-cost organic photovoltaic applications. 相似文献
978.
Tejal Barkhade Ambadas Phatangare Shailendra Dahiwale Santosh Kumar Mahapatra Indrani Banerjee 《Surface and interface analysis : SIA》2019,51(9):894-905
The advent of nano-biotechnology has inspired the interface interaction study between engineered nanoparticles (NPs) and biomolecules. The interaction between Fe content titanium dioxide (TiO2) NPs and adenosine triphosphate (ATP) biomolecules has been envisioned. The effect of Fe content in TiO2 matrix was studied using X-ray diffraction (XRD) and transmission electron microscopy (TEM). The increase in Fe content caused a decrease in particle size with change in morphology from spherical to one-dimensional rod structure. The Fe incorporation in the TiO2 matrix reduced the transition temperature from anatase to rutile (A-R) phase along with formation of haematite phase of iron oxide at 400°C. The interaction of Fe content TiO2 NPs with ATP molecule has been studied using spectroscopic method of Raman scattering and infrared vibration spectrum along with TEM. Fe content in TiO2 has enhanced the interaction efficiency of the NPs with ATP biomolecules. Raman spectroscopy confirms that the NPs interact strongly with nitrogen (N7) site in the adenine ring of ATP biomolecule. Engineering of Fe content TiO2 NP could successfully tune the coordination between metal oxide NPs with biomolecules, which could help in designing devices for biomedical applications. 相似文献
979.
Bibo WangXiaofeng Wang Yongqian ShiGang Tang Qinbo TangLei Song Yuan Hu 《Radiation Physics and Chemistry》2012,81(3):308-315
Ethylene vinyl acetate copolymer (EVA) flame retarded by ammonium polyphosphate (APP) and pentaerythritol (PER) was cross-linked by electron beam irradiation. The effects of vinyl acetate content and electron beam irradiation on the flame retardancy, mechanical and thermal properties of EVA composites were investigated. The volatilized products of EVA/APP/PER composites were characterized by thermogravimetric analysis/infrared spectrometry. As VA content increased, the volatilized products increased in the second decomposition step, but decreased in the third decomposition step. For all samples, the increase of irradiation dose could improve both the gel content and the Limit Oxygen Index (LOI, the minimum oxygen concentration by volume for maintaining the burning of a material) values of irradiated composites. The mechanical and thermal properties of the irradiated EVA composites were also evidently improved at appropriate irradiation dose as compared with those of unirradiated EVA composites, whereas these properties decrease at higher irradiation dose because of the electron beam irradiation-induced oxidative degradation or chain scission. 相似文献
980.
1 引言 我国耕地严重缺磷的面积所占比例高达2/3,而目前施肥的磷/氮比例又远远低于国际平均水平,如此的比例失调将严重影响农业增产.在当前施用的磷肥中,普钙和重钙占了很大的比例.由于重钙是用磷酸而非硫酸酸解磷矿,所以不含硫酸钙杂质,有效五氧化二磷的含量也由16~21%提高到45~52%,肥效比普钙提高两到三倍.为此国家"八五"重点项目引进了Hy dro GTSP工艺2×40万吨/年重钙装置.该装置于1999年3月试车以来难以达到满负荷生产. 作者通过对生产工艺各环节的分析,指出反应料浆含水量偏高是影响装置生产负荷的主要因素.料浆中水分的重要来源之一是二次球磨. 相似文献