全文获取类型
收费全文 | 19521篇 |
免费 | 2554篇 |
国内免费 | 3060篇 |
专业分类
化学 | 13850篇 |
晶体学 | 189篇 |
力学 | 390篇 |
综合类 | 108篇 |
数学 | 642篇 |
物理学 | 2991篇 |
综合类 | 6965篇 |
出版年
2024年 | 87篇 |
2023年 | 309篇 |
2022年 | 806篇 |
2021年 | 706篇 |
2020年 | 919篇 |
2019年 | 702篇 |
2018年 | 656篇 |
2017年 | 753篇 |
2016年 | 945篇 |
2015年 | 1027篇 |
2014年 | 1152篇 |
2013年 | 1705篇 |
2012年 | 1373篇 |
2011年 | 1392篇 |
2010年 | 1110篇 |
2009年 | 1146篇 |
2008年 | 1090篇 |
2007年 | 1195篇 |
2006年 | 1048篇 |
2005年 | 1017篇 |
2004年 | 958篇 |
2003年 | 817篇 |
2002年 | 655篇 |
2001年 | 509篇 |
2000年 | 467篇 |
1999年 | 391篇 |
1998年 | 347篇 |
1997年 | 308篇 |
1996年 | 252篇 |
1995年 | 217篇 |
1994年 | 217篇 |
1993年 | 184篇 |
1992年 | 114篇 |
1991年 | 116篇 |
1990年 | 97篇 |
1989年 | 80篇 |
1988年 | 73篇 |
1987年 | 52篇 |
1986年 | 33篇 |
1985年 | 18篇 |
1984年 | 20篇 |
1983年 | 10篇 |
1982年 | 13篇 |
1981年 | 10篇 |
1980年 | 8篇 |
1979年 | 14篇 |
1977年 | 3篇 |
1975年 | 2篇 |
1972年 | 4篇 |
1955年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
对影响作物高产的光合作用碳同化的生理限制因子进行了分析,提出内外因子结合考虑是提高作物的光合效率和产量的关键. 相似文献
82.
研究了耦合效应对多壁纳米碳管非线性光致发光的影响.采用π 轨道紧束缚模型,从理论上得到了层间耦合会减小多壁碳纳米管的带隙和电子跃迁几率.从而说明了多壁碳纳米管的荧光很难观察到的原因. 相似文献
83.
常华 《辽宁大学学报(自然科学版)》2004,31(2):160-162
通过ASP与HTML页、脚本命令和ActiveX组件组合,创建交互的Web页的应用程序,实现了网上作文栏目管理. 相似文献
84.
布尔“复合函数”的Walsh循环谱和自相关函数 总被引:1,自引:0,他引:1
本文利用布尔随机变量联合分布的分解式给出了布尔“复合函数”和某布尔函数符合率的分解算式,由此求得了布尔“复合函数”的 Walsh循环谱和自相关函数的计算公式,公式清楚地表明了“复合”所得布尔函数的 Walsh循环谱与起“复合”作用的函数和被“复合”的各函数所有线性组合的 Walsh循环谱之间的关系、“复合”所得布尔函数的自相关函数与起“复合”作用的函数谱和被“复合”的各函数的谱及相关函数之间的关系,这两个公式在布尔函数的密码学性质研究中会有广泛的应用. 相似文献
85.
Elżbieta Godlewska M. Mitoraj F. Devred B. E. Nieuwenhuys 《Journal of Thermal Analysis and Calorimetry》2007,88(1):225-230
A Ti–45.9Al–8Nb
(at%) alloy with a lamellar structure (γ+α2)
was oxidised in air at 700, 800, 850 and 900°C in isothermal and thermal
cycling conditions. The reaction progress was followed by thermogravimetric
measurements. In isothermal conditions the oxidation kinetics followed approximately
a parabolic rate law and the rate constants ranged from about 10–12
kg2 m–4 s–1
at 700°C to 10–10 kg2
m–4 s–1
at 900°C. The oxide scales were built of Al2O3
and TiO2, the former being the main component of the
outermost layer. The oxidation behaviour of Ti–45.9Al–8Nb was
referred to a commercial titanium alloy, WT4 (Ti–6Al–1Mn), and
selected oxidation-resistant alloys. 相似文献
86.
Fabian Buffa Gustavo A. Abraham Brian P. Grady Daniel Resasco 《Journal of Polymer Science.Polymer Physics》2007,45(4):490-501
A commercially available aliphatic thermoplastic polyurethane formulated with a methylene bis(cyclohexyl) diisocyanate hard segment and a poly(tetramethylene oxide) soft segment and chain‐extended with 1,4‐butanediol was dissolved in dimethylformamide and mixed with dispersed single‐walled carbon nanotubes. The properties of composites made with unfunctionalized nanotubes were compared with the properties of composites made with nanotubes functionalized to contain hydroxyl groups. Functionalization almost eliminated the conductivity of the tubes according to the conductivity of the composites above the percolation threshold. In most cases, functionalized and unfunctionalized tubes yielded composites with statistically identical mechanical properties. However, composites made with functionalized tubes did have a slightly higher modulus in the rubbery plateau region at higher nanotube fractions. Small‐angle X‐ray scattering patterns indicated that the dispersion reached a plateau in the unfunctionalized composites that was consistent with the plateau in the rubbery plateau region. The room‐temperature modulus and tensile strength increase was proportionally higher than almost all increases seen previously in thermoplastic polyurethanes; however, the increase was still an order of magnitude below what has been reported for the best nanotube–polymer systems. Nanotube addition increased the hard‐segment glass transition temperature slightly, whereas the soft‐segment glass transition was so diffuse that no conclusions could be drawn. Unfunctionalized tubes suppressed the crystallization of the hard segment; whereas functionalized tubes had no effect. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 490–501, 2007 相似文献
87.
The crystallization behavior of miscible syndiotactic polystyrene (sPS) and atactic polystyrene (aPS) blends with different sPS/aPS weight ratios was investigated in supercritical CO2 by using Fourier‐transform infrared spectroscopy, differential scanning calorimetry, and wide‐angle X‐ray diffraction. Supercritical CO2 and aPS exhibited different effects on the conformational change of sPS and competed with each other. Increasing the content of amorphous aPS in the blends made its effect on the conformational change of sPS gradually surpass that of supercritical CO2. Supercritical CO2 favored the formation of the helical conformation of sPS in lower temperature range and the all trans planar conformation in higher temperature range, instead of forming the latter one only in higher temperature range in ambient atmosphere. However, increasing aPS content in the blends pushed the range for forming the helical conformation to lower temperature and made the all trans planar conformation dominant in aPS/sPS 25/75 blend after treating in supercritical CO2 above 60 °C. The all trans planar zigzag conformation was more favorable than the helical conformation after mixing aPS in sPS in supercritical CO2. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1755–1764, 2007 相似文献
88.
利用η-Carleson测度给出了单位球上不同Privalov以及不同加权Bergman-Privalov空间之间的复合算子是度量有界或度量紧的充要条件,并给出了一些函数理论方面的刻画. 相似文献
89.
DaXinSHI YaQingFENG ShunHeZHONG 《中国化学快报》2005,16(5):685-687
Photoinduced synthesis of CO2 and CH4 was investigated using a batch reaction system on several photoactive materials supported on silicon dioxide. Single semiconductor showed higher selectivity to C1 compounds. The production of C2-C3 oxygenates took place preferentially on composite semiconductor photocatalysts. In particular, it was found that acetone was the primary product over Cu/CdS-TiO2/SiO2. 相似文献
90.
1 Results In addition to single wall and multiwall carbon nanotubes[1], several structures,which are more or less related to fullerenes,including carbon nanohorns[2a], carbon nanospheres[2b] and onion like carbon structures[2c] have been reported.A new simple straight forward method to access some of these structures is the solid-state pyrolysis of different organometallic complexes in a sealed vessel,which led so far to carbon nanotubes[3a,b], carbon nanocables[3c] and onions[3d]. 相似文献