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21.
对影响作物高产的光合作用碳同化的生理限制因子进行了分析,提出内外因子结合考虑是提高作物的光合效率和产量的关键. 相似文献
22.
采用计算机接口、软硬件相结合的方法对水下潜器三维成像数字传输测试系统进行设计。误码检测电路是由ISA总线并配以相应的外围电路构成的号虑到系统应用的通用性,测试信号的码速范围设计为40~125Mbps,另外还介绍了硬件、软件的设计原理以及系统实验。 相似文献
23.
研究了耦合效应对多壁纳米碳管非线性光致发光的影响.采用π 轨道紧束缚模型,从理论上得到了层间耦合会减小多壁碳纳米管的带隙和电子跃迁几率.从而说明了多壁碳纳米管的荧光很难观察到的原因. 相似文献
24.
Fabian Buffa Gustavo A. Abraham Brian P. Grady Daniel Resasco 《Journal of Polymer Science.Polymer Physics》2007,45(4):490-501
A commercially available aliphatic thermoplastic polyurethane formulated with a methylene bis(cyclohexyl) diisocyanate hard segment and a poly(tetramethylene oxide) soft segment and chain‐extended with 1,4‐butanediol was dissolved in dimethylformamide and mixed with dispersed single‐walled carbon nanotubes. The properties of composites made with unfunctionalized nanotubes were compared with the properties of composites made with nanotubes functionalized to contain hydroxyl groups. Functionalization almost eliminated the conductivity of the tubes according to the conductivity of the composites above the percolation threshold. In most cases, functionalized and unfunctionalized tubes yielded composites with statistically identical mechanical properties. However, composites made with functionalized tubes did have a slightly higher modulus in the rubbery plateau region at higher nanotube fractions. Small‐angle X‐ray scattering patterns indicated that the dispersion reached a plateau in the unfunctionalized composites that was consistent with the plateau in the rubbery plateau region. The room‐temperature modulus and tensile strength increase was proportionally higher than almost all increases seen previously in thermoplastic polyurethanes; however, the increase was still an order of magnitude below what has been reported for the best nanotube–polymer systems. Nanotube addition increased the hard‐segment glass transition temperature slightly, whereas the soft‐segment glass transition was so diffuse that no conclusions could be drawn. Unfunctionalized tubes suppressed the crystallization of the hard segment; whereas functionalized tubes had no effect. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 490–501, 2007 相似文献
25.
The crystallization behavior of miscible syndiotactic polystyrene (sPS) and atactic polystyrene (aPS) blends with different sPS/aPS weight ratios was investigated in supercritical CO2 by using Fourier‐transform infrared spectroscopy, differential scanning calorimetry, and wide‐angle X‐ray diffraction. Supercritical CO2 and aPS exhibited different effects on the conformational change of sPS and competed with each other. Increasing the content of amorphous aPS in the blends made its effect on the conformational change of sPS gradually surpass that of supercritical CO2. Supercritical CO2 favored the formation of the helical conformation of sPS in lower temperature range and the all trans planar conformation in higher temperature range, instead of forming the latter one only in higher temperature range in ambient atmosphere. However, increasing aPS content in the blends pushed the range for forming the helical conformation to lower temperature and made the all trans planar conformation dominant in aPS/sPS 25/75 blend after treating in supercritical CO2 above 60 °C. The all trans planar zigzag conformation was more favorable than the helical conformation after mixing aPS in sPS in supercritical CO2. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1755–1764, 2007 相似文献
26.
1 Results In addition to single wall and multiwall carbon nanotubes[1], several structures,which are more or less related to fullerenes,including carbon nanohorns[2a], carbon nanospheres[2b] and onion like carbon structures[2c] have been reported.A new simple straight forward method to access some of these structures is the solid-state pyrolysis of different organometallic complexes in a sealed vessel,which led so far to carbon nanotubes[3a,b], carbon nanocables[3c] and onions[3d]. 相似文献
27.
《Magnetic resonance in chemistry : MRC》2003,41(8):599-602
Gradient‐enhanced pulse schemes are presented for the detection of quaternary and methylene carbons. The new pulse schemes permit the detection of quaternary and methylene (—CH2) carbons or CH2 carbons alone from a single experiment. Efficient suppression of CH and CH3 carbons in all the pulse schemes is achieved by creating their antiphase magnetization and then dephasing using gradients. In the pulse schemes for detection of only CH2 carbons, the quaternary carbons are also suppressed either by dephasing using gradients or by rendering them unobservable by retaining in longitudinal order. The experimental results of the gradient pulse schemes are demonstrated on cholesteryl acetate and cyclosporin A. These one‐dimensional techniques, because of their simplicity and the ease of performing the experiments, can be important for routine chemical applications. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
28.
Hiroshi Sugimoto Hiromitsu Ohshima Shohei Inoue 《Journal of polymer science. Part A, Polymer chemistry》2003,41(22):3549-3555
The first successful example of the formation of polycarbonate from 1-atm carbon dioxide and epoxide was demonstrated by the alternating copolymerization of carbon dioxide and epoxide with manganese porphyrin as a catalyst. The copolymerization of carbon dioxide and cyclohexene oxide with (porphinato)manganese acetate proceeded under the 1-atm pressure of carbon dioxide to give a copolymer with an alternating sequence. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3549–3555, 2003 相似文献
29.
Multiwalled carbon nanotubes were modified by carboxy groups. Four independent methods for the determination of the degree
of functionalization of the surface were proposed: 13C NMR spectroscopy, thermogravimetry, titrimetry, and fluorimetry. The first two methods show the total content of carboxy
groups in the sample, and the latter two methods give information about the content of the surface groups only.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 291–295, February, 2008. 相似文献
30.
刘超颖 《河北科技大学学报》1996,(1)
为了确定棉纤维性能对精梳纱性能的影响,分别从梳棉前的纤维中和同一纺纱工艺流程的粗纱中选同样9种不同的纤维作为试样进行实验。根据实验数据.得到了纤维性能与纱线性能之间关系的回归方程式,为从纤维直接预测纱线性能提供了一条快速、简捷的方法和途径。 相似文献