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121.
A.T. McBride A. Javili P. Steinmann S. Bargmann 《Journal of the mechanics and physics of solids》2011,59(10):2116-2133
Surfaces can have a significant influence on the overall response of a continuum body but are often neglected or accounted for in an ad hoc manner. This work is concerned with a nonlinear continuum thermomechanics formulation which accounts for surface structures and includes the effects of diffusion and viscoelasticity. The formulation is presented within a thermodynamically consistent framework and elucidates the nature of the coupling between the various fields, and the surface and the bulk. Conservation principles are used to determine the form of the constitutive relations and the evolution equations. Restrictions on the jump in the temperature and the chemical potential between the surface and the bulk are not a priori assumptions, rather they arise from the reduced dissipation inequality on the surface and are shown to be satisfiable without imposing the standard assumptions of thermal and chemical slavery. The nature of the constitutive relations is made clear via an example wherein the form of the Helmholtz energy is explicitly given. 相似文献
122.
Vellaiappillai Tamilavan Myungkwan Song Sung‐Ho Jin Myung Ho Hyun 《Journal of polymer science. Part A, Polymer chemistry》2010,48(23):5514-5521
A series of three new 1‐(2,6‐diisopropylphenyl)‐2,5‐di(2‐thienyl)pyrrole‐based polymers such as poly[1‐(2,6‐diisopropylphenyl)‐2,5‐di(2‐thienyl)pyrrole] ( PTPT ), poly[1,4‐(2,5‐bis(octyloxy)phenylene)‐alt‐5,5'‐(1‐(2,6‐diisopropylphenyl)‐2,5‐di(2‐thienyl)pyrrole)] ( PPTPT ), and poly[2,5‐(3‐octylthiophene)‐alt‐5,5'‐(1‐(2,6‐diisopropylphenyl)‐2,5‐di(2‐thienyl)pyrrole)] ( PTTPT ) were synthesized and characterized. The new polymers were readily soluble in common organic solvents and the thermogravimetric analysis showed that the three polymers are thermally stable with the 5% degradation temperature >379 °C. The absorption maxima of the polymers were 478, 483, and 485 nm in thin film and the optical band gaps calculated from the onset wavelength of the optical absorption were 2.15, 2.20, and 2.13 eV, respectively. Each of the polymers was investigated as an electron donor blending with PC70BM as an electron acceptor in bulk heterojunction (BHJ) solar cells. BHJ solar cells were fabricated in ITO/PEDOT:PSS/polymer:PC70BM/TiOx/Al configurations. The BHJ solar cell with PPTPT :PC70BM (1:5 wt %) showed the power conversion efficiency (PCE) of 1.35% (Jsc = 7.41 mA/cm2, Voc = 0.56 V, FF = 33%), measured using AM 1.5G solar simulator at 100 mW/cm2 light illumination. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
123.
ZHANG QingChao PANG ShuJie LI Yi & ZHANG Tao Key Laboratory of Aerospace Materials Performance School of Materials Science Engineering Beijing University of Aeronautics Astronautics Beijing China 《中国科学:物理学 力学 天文学(英文版)》2011,(9)
Bulk metallic glasses (BMGs) with large supercooled liquid region are promising materials for superplastic forming. In this paper, we demonstrate a microstructure-based strategy to pinpoint the composition with the largest supercooled liquid region in La 86 x Al 14 Cu x (x=16 at%-20 at%) metallic glass system. By monitoring the changes in crystallization behavior of the glassy alloys with composition to search for the alloys exhibiting eutectic crystallization, the glassy alloys with the largest supercooled... 相似文献
124.
125.
K. Dinesh Kumar Andy H. Tsou Anil K. Bhowmick 《Journal of Polymer Science.Polymer Physics》2010,48(9):972-982
The effects of change in surface energy and bulk viscoelastic properties on the autohesive tack strength of brominated isobutylene‐co‐p‐methylstyrene (BIMS) rubber have been investigated by the addition of hydrocarbon resin (HCR) tackifier and maleated hydrocarbon resin (MA‐g‐HCR) tackifier. The addition of compatible HCR tackifier results in a reasonable increment in the tack strength of BIMS rubber by modifying only the bulk viscoelastic properties (compliance, entanglement molecular weight, relaxation time, self‐diffusion, and monomer friction coefficient values) of BIMS rubber to perform better during the course of bonding and debonding steps of the peel test. Incorporation of MA‐g‐HCR tackifier (containing 5–20 wt % of grafted maleic anhydride) steadily increases the tack strength of BIMS rubber further by precisely modifying both the surface energy and bulk viscoelastic properties to perform much better in the bonding and debonding steps. However, beyond 20 wt % of grafted maleic anhydride in the HCR tackifier, the tack strength starts decreasing due to the incompatibility between the blend components, and hence, the bulk viscoelastic properties required for bond formation are severely retarded by the interrelated reinforcing effect and the phase separation effect of the brittle MA‐g‐HCR tackifier in the BIMS rubber. Hence, the polar groups in a tackifier will contribute to significant enhancement of autohesive tack strength only if the bulk viscoelastic property of the rubber‐tackifier blend is favorable for bond formation and bond separation. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 972–982, 2010 相似文献
126.
It is emphasized that any equation of state (EOS) based on the generalized Lennard-Jones potential or the Mie potential, suffers
from two main shortcomings as pointed out by Stacey and Davis [2]. One of the shortcomings viz. the problem related to imaginary numbers for the exponents in the potential function, has been removed recently by Jiuxun
[11] by using a relationship between the exponents. However, the modified EOS obtained by Jiuxun suffers from the second shortcoming
viz. it gives lower values for −B
0
B″0, an important equation of state parameter related to the second pressure derivative of the bulk modulus. Values of B
0
B″0 obtained by Jiuxun are not consistent with those reported by Stacey and Davis.
相似文献
127.
The track etch rates of
10
20
Ne-ion in cellulose nitrate (LR-115) have been measured for different temperatures and the activation energy is determined.
The experimental results show that both the track etch rate and the normalized track etch rate depend on the energy loss as
well as on etching temperature. The maximum etched track length of
10
20
Ne-ion agrees with the theoretically computed range. The experimental results show that there is no sharp threshold, at least
in CN(LR-115). 相似文献
128.
本文用随机理论对松散介质的流动进行分析,得出了移动漏斗、放出体及松动体的表面方程式和运动场中松散介质的密度分布计算式。建立了松散介质流动时必须满足的条件,并指出放出体及松动体均不是椭球体,它们最大的宽度不在其长轴的1/2处,而是随矿岩的物理力学性质的变化而上下移动。 相似文献
129.
This paper formulates a model for finding a minimum cost routing in a network for a heterogeneous fleet of ships engaged in pickup and delivery of several liquid bulk products. The problem is frequently encountered by maritime chemical transport companies, including oil companies serving an archipelago of islands. The products are assumed to require dedicated compartments in the ship. The problem is to decide how much of each product should be carried by each ship from supply ports to demand ports, subject to the inventory level of each product in each port being maintained between certain levels that are set by the production rates, the consumption rates, and the storage capacities of the various products in each port. This important and challenging inventory constrained multi-ship pickup–delivery problem is formulated as a mixed-integer nonlinear program. We show that the model can be reformulated as an equivalent mixed-integer linear program with special structure. Over 100 test problems are randomly generated and solved using CPLEX 7.5. The results of our numerical experiments illuminate where problem structure can be exploited in order to solve larger instances of the model. Part II of the sequel will deal with new algorithms that take advantage of model properties. 相似文献
130.
G. Berchiesi G. Rafaiani G. Vitali F. Farhat 《Journal of Thermal Analysis and Calorimetry》1995,44(6):1313-1319
The behavior of the molten system acetamide-electrolyte, including the peculiarity of the structure and the consequent relevant properties, such as the megavalue of the dielectric constant, was reported earlier. The probable structure is a micellar system composed of salt micelles dispersed in an amorphous solvent. The present paper reports measurements in a related system: fluoroacetamide-sodium trifluoroacetate. The phase diagram, the ultrasonic absorption of both longitudinal and shear waves, and the longitudinal relaxation time of the nuclear magnetic momentum were measured at different temperatures. The most importnat result was thatT 1 (NMR relaxation time) on the19F nucleus shows that the amide and salt participate in different environments. The amide environment is less rigid; this proves that the system must be considered microheterogeneous. Moreover, the present system exhibited: 1) a less extended concentration area where supercooling phenomena occur; 2) a much broader curve of the real part of the mechanical impedance versus frequency; 3) a higher bulk viscosity in comparison with the CH3CONH2?CF3COONa supercapacitive system. 相似文献