OBS突发装配的缓存安全间隔机制

研究了光突发交换边缘路由器上的突发装配,着眼于使其更加通用、合理和高效.为此,引入了单位输入比特率的概念以提高通用性,然后提出和分析了装配中的缓存安全间隔机制及其作用.通过设置适当的缓存安全间隔值,不仅可以避免因缓存溢出引起的分组损失,而且所获得的固定最大发送时间也为突发的信道调度带来了便利.采用边缘路由器上的自相似流量模型,通过网络仿真,讨论了缓存安全间隔取值对突发生成、网络性能及缓存使用的影响,并获得了相关结论.     

膨润土-砂混合物缓冲层径向热传导性

膨润土-砂混合物作为高放废物处置库缓冲材料,在核废料衰变热影响作用下,其稳定性及物理力学性能产生显著变化,这对缓冲回填材料的包封阻隔作用及处置库的安全运行产生重要影响。本研究采用自行设计的装置对按比例缩小后的不同干密度、含水率、掺砂率试样进行热传导模拟试验,并对试验过程进行热-力耦合数值模拟分析,得到了缓冲层温度、应力和应变的变化及分布情况。结果表明,增大试样干密度、含水率和掺砂率均可提高导热性,应力和应变也随之增大,且不同含水率试样产生的结果变化显著;缓冲层靠近热源的位置温度、应力和应变最大,且沿径向方向减小,初始时刻各值变化显著。     

Sensitive DNA biosensor improved by Luteolin copper(II) as indicator based on silver nanoparticles and carbon nanotubes modified electrode

A novel and sensitive electrochemical DNA biosensor has been developed for the detection of DNA hybridization. The biosensor was proposed by using copper(II) complex of Luteolin C₃₀H₁₈CuO₁₂ (CuL₂) as an electroactive indicator based on silver nanoparticles and multi-walled carbon nanotubes (Ag/MWCNTs) modified glassy carbon electrode (GCE). In this method, the 4-aminobenzoic acid (4-ABA) and Ag nanoparticles were covalently grafted on MWCNTs to form Ag/4-ABA/MWCNTs. The proposed method dramatically increased DNA attachment quantity and complementary ssDNA detection sensitivity for its large surface area and good charge-transport characteristics. DNA hybridization detection was performed using CuL₂ as an electroactive indicator. The CuL₂ was synthesized and characterized using elemental analysis (EA) and IR spectroscopy. Cyclic voltammetry (CV) and fluorescence spectroscopy were used to investigate the interaction between CuL₂ and ds-oligonucleotides (dsDNA). It was revealed that CuL₂ presented high electrochemical activity on GCE, and it could be intercalated into the double helices of dsDNA. The target ssDNA of the human hepatitis B virus (HBV) was quantified in a linear range from 3.23 × 10⁻¹² to 5.31 × 10⁻⁹ M (r = 0.9983). A detection limit of 6.46 × 10⁻¹³ M (3σ, n = 11) was achieved.     

反相液相色谱中离子抑制剂的有机调节剂作用

系统地研究了在反相液相色谱（RPLC）流动相中作为离子抑制剂的酸、碱及缓冲溶液对中性化合物保留行为的影响,着重探讨了有机酸、有机碱离子抑制剂的有机调节剂作用,定量地考察了甲醇和乙腈、甲醇和乙酸、甲醇和三乙胺、乙腈和乙酸、乙腈和三乙胺在十八烷基硅烷键合相上洗脱强度之间的关系,为RPLC中有机调节剂的洗脱强度排序提供一种评判方法．另外,讨论了乙酸和三乙胺作为有机调节剂时不同的作用机理．本实验结果对于RPLC分离方法的快速建立和准确优化都具有一定的借鉴意义．     

Effect of Perylene as Electron Acceptor and poly(tetrabromo-p-phenylene Diselenide) as “Buffer Layer” on Heterojunction Solar Cells Performances

Summary : Perylene derivatives, that behave as liquid crystal and might be used as electron acceptors, and poly(tetrabromo-p-phenylenediselenide) (PTBrPDSe) were synthesized with the purpose of using the polymer as buffer layer in solar cells. It was demonstrated that perylene compounds of N,N′-diheptyl-3,4,9,10-perylentetracarboxyldiimide (PTCDI-C7) and N,N′-diundecyl-3,4,9,10-perylentetracarboxyldiimide (PTCDI-C11) enabled obtaining photovoltaic effect when coupled with copper phthalocyanine (CuPc). The power conversion efficiency of the cells prepared from these perylenes is similar, whatever the x value. However this efficiency is smaller than the one achieved when the couple CuPc/C₆₀ (fullerene) is used. More precisely, the best efficiency was obtained when a PTBrPDSe/Au buffer layer is introduced between the ITO anode and the CuPc. It was established that the presence of the thin PTBrPDSe layer allows improving the shunt resistance and consequently the cells performance.     

基于机场货运预测的GM(1,1)建模过程问题分析

运用灰色系统GM(1,1)模型进行预测时,模拟精度和预测精度是关注的焦点.对原始数据构造缓冲算子和进行完整的前期检验,运用等维灰数递补的动态建模方法,针对误差建立残差修正模型,都可以提高预测的可信度.通过归纳建模各阶段可能出现的典型问题以及解决方法,以期对建立优化模型有所帮助.最后建立GM(1,1)模型预测天津滨海机场货邮吞吐量.     

控制发送策略对IPsec的补充和完善

针对IPsec无法解决的安全隐患提出了一种新的网络安全协议——有限制发送协议,在新的协议中,如果主机向网络发送大量的具有攻击性的数据包时,其发送权利将会受到限制,从而保证网络的安全.采用OPNET仿真软件对新的协议进行了仿真,仿真结果表明,采用新的协议时,网络性能要好.以目标客户机平均HTTP响应时间为例,采用新的协议时,平均HTTP响应时间为0.013 s,不采用新的协议时,平均HTTP响应时间为0.032 s.     

OBS网络中基于优先级与突发包分割的光缓存方法研究

为了提高OBS网络的QoS,降低数据包的丢失率,研究了现有的基于优先级与突发包分割的OBS光缓存方法,提出了一种改进的基于优先级与突发包分割的光缓存方法.该方法综合考虑了其他空闲信道和FDL,并引入了空闲信道剩余时间对FDL延迟时间的判断,能够更加有效地判断数据包的丢失与否,从而确保数据包的低丢失率,保证OBS的QoS,提高整个网络的性能.     

ZnO 空穴缓冲层对OLED 性能的影响

本文利用无机材料ZnO作为空穴缓冲层,制备了结构为ITO/ZnO/NPB/Alq3/Al的有机电致发光器件。用计算机控制的KEITHLEY2400-PR655系统测量器件的电压-电流-亮度特性。研究结果表明,当ZnO薄膜的厚度为2 nm时,器件的电流效率可达1.65 cd/A,最大亮度为3 449 cd/m2;而没有加入缓冲层的同类器件,最大亮度仅为869.7 cd/m2,最大电流效率为0.46 cd/A。由此可以看出,加入ZnO空穴缓冲层后,最大亮度提高3.97倍,最大电流效率提高3.59倍。分析认为适当厚度的ZnO薄膜降低了发光层空穴的浓度,提高了电子和空穴的复合率,从而降低了电流密度,提高了器件的电流效率,改善了器件性能。     

Performance improvement of MEH-PPV:PCBM solar cells using bathocuproine and bathophenanthroline as the buffer layers

In this work, bathocuproine (BCP) and bathophenanthroline (Bphen), commonly used in small-molecule organic solar cells (OSCs), are adopted as the buffer layers to improve the performance of the polymer solar cells (PSCs) based on poly(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene) (MEH-PPV): [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) bulk heterojunction. By inserting BCP or Bphen between the active layer and the top cathode, all the performance parameters are dramatically improved. The power conversion efficiency is increased by about 70% and 120% with 5-nm BCP and 12-nm Bphen layers, respectively, when compared with that of the devices without any buffer layer. The performance enhancement is attributed to BCP or Bphen (i) increasing the optical field, and hence the absorption in the active layer, (ii) effectively blocking the excitons generated in MEH-PPV from quenching at organic/aluminum (Al) interface due to the large band-gap of BCP or Bphen, which results in a significant reduction in series resistance (Rs), and (iii) preventing damage to the active layer during the metal deposition. Compared with the traditional device using LiF as the buffer layer, the BCP-based devices show a comparable efficiency, while the Bphen-based devices show a much larger efficiency. This is due to the higher electron mobility in Bphen than that in BCP, which facilitates the electron transport and extraction through the buffer layer to the cathode.