锇-聚乙烯吲哚配合物修饰电极对肾上腺素的电催化氧化

研究了配位聚合物锇 -聚乙烯吲哚 [Os( bpy) 2 ( PVI) 1 0 Cl]Cl和 Nafion双层膜修饰玻碳电极的电化学特性 ,该膜对肾上腺素 ( EP)的电化学氧化有催化作用 ,在通常的生理条件下 ( p H7.0 ) ,催化电流与 EP浓度在1 .0× 1 0 - 6～ 8.6× 1 0 - 5 mol/L范围内呈良好的线性关系 ,相关系数为 0 .9987.Nafion膜排除了抗坏血酸( AA)的干扰 ,表现出较高的灵敏度、选择性及良好的稳定性 .该电极可在 +2 50 m V下进行 EP的安培法测定 .用旋转圆盘电极对电催化过程的动力学进行了研究 ,催化速率常数 kch为 3 .53× 1 0 3mol- 1 · L· s- 1 .在较高 EP浓度下 ,催化电流与浓度的关系表现出 Michaelis-Menten型响应 ,Michaelis-Menten常数 Km 为1 .4 7mmol/L.     

基于DSP的IMDCT快速算法

修正离散余弦变换 ( MDCT)在音视频信号编码中得到广泛地应用 ,其快速算法在实时编解码系统中尤为重要。论文给出了一种适用于数字信号处理器 ( DSP)实现的修正离散余弦反变换 ( IMDCT)快速算法—用 M/ 2点时间抽取 ( decimation in time,DIT)分裂基 FFT实现 2 M点的IMDCT。算法是基于蝶形运算组成 ,在 DSP中可以获得很高的运算效率。该算法的蝶形运算结构同样适用于正向MDCT。在由定点 DSP实现的活动图像专家组 ( MPEG)音频层 III解码器中 ,与 MPEG音频压缩标准 ISO/ IEC 11172 -3中给出的 IMDCT运算量相比较 ,该文提出的 IMDCT快速算法节省了 2 / 3的运算时间和 1/ 2的存储空间。     

多取代C60-聚苯乙烯材料的合成及微观摩擦学研究

为设计并合成具有优良摩擦学性能的润滑材料和研究其摩擦润滑机理 ,介绍了表面修饰的 C6 0 功能高分子复合新材料的摩擦学研究工作。采用自由基聚合方法合成了多取代 C6 0 -聚苯乙烯 ,对其物理化学性能做了表征 ,并采用 L B膜制备技术制备分子有序膜和原子力 /摩擦力显微镜测试微观摩擦学特性。测试结果表明 ,实验合成了目标产物 ,这种高分子材料可形成有序且紧密的 L B膜 ,可望成为有效的分子润滑材料     

在关联噪声驱动下双稳系统的MFPT

讨论了在关联噪声驱动下双稳系统的瞬变性质 ,计算了该系统的平均第一通过时间 (MFPT) .数值计算表明 :在正关联的条件下 (λ>0 ) ,MFPT随噪声关联τ增大而减少 ;在负关联的条件下 (λ <0 ) ,MFPT随τ增大而增大 .同时还发现 ,在完全正关联的条件下 (λ=1 ) ,若加性噪声强度等于乘性噪声强度 (α =D) ,则MFPT趋于无穷大 ;若α/D≈ 0 .87,则平均第一通过时间等于零 .     

New exact solutions of nonlinear Klein--Gordon equation

New exact solutions, expressed in terms of the Jacobi elliptic functions, to the nonlinear Klein--Gordon equation are obtained by using a modified mapping method. The solutions include the conditions for equation's parameters and travelling wave transformation parameters. Some figures for a specific kind of solution are also presented.     

Partially coherent nonparaxial modified Bessel--Gauss beams

The concept of partially coherent nonparaxial modified Bessel--Gauss (MBG) beams is proposed. Based on the generalized Rayleigh-Sommerfeld diffraction integral, the analytical propagation equations of nonparaxial MBG beams in free space are derived and analysed, and some special cases are discussed. In particular, under the paraxial approximation our results reduce to the corresponding paraxial ones. Numerical calculation examples are given to illustrate the dependence of intensity and spectral degree of coherence on the beam order $m$, \textit{$\xi $} and $f$ parameters, and to compare the difference between the paraxial and nonparaxial results.     

质子辐照不锈钢中氢气泡产生和演化研究

采用质子辐照模拟方法和正电子湮没寿命测量方法研究了质子辐照在国产改进型316L不锈钢中产生的氢气泡及其随辐照质子注量的演化过程。5×10^12,5×10^13,5×10^14／cm^2质子辐照的实验结果表明,辐照在不锈钢中产生氢气泡的尺度随辐照质子注量增加而增大,在质子注量为5×10^14／cm^2时氢气泡尺寸达到0．62nm,气泡的浓度随质子注量增加而减小。The bubble production and evolution in the home-made modified 316L stainless steel have been investigated by the proton irradiation simulation technique and the positron annihilation lifetime measurement. The experimental results of 5 × 10^12, 5 × 10^13 and 5 × 10^14/cm^2 proton irradiations show that the produced bubble size increases, while the bubble concentration decreases, with the increasing of the irradiation proton flueence. At the proton irradiation fluence of 5 × 10^14/cm^2 the bubble size reaches 0.62 nm.     

Hydrogen bonding of modified bases involving Watson‐Crick sites: Crystal structure and conformation of Benzyl 6‐aminopurine‐7‐carboxylate

Crystals of benzyl 6‐aminopurine‐7‐carboxylate (C₁₃H₁₁N₅O₂) are monoclinic, space group C2/c, Z = 8, with a = 25.448 (9), b = 6.052 (1), c = 16.975 (6)Å, β = 112.05 (5)°, M = 269.27, D_m= 1.49, D_x= 1.48 g/cm³. The structure was determined from three‐dimensional diffractometric data by the multisolution technique and refined to a final reliability factor of 0.068. The molecule is planar with an intramolecular hydrogen bond from one of the amino hydrogens, H_a(N6) to the keto oxygen O(10) of the acyl group. The molecules are hydrogen bonded across the center of inversion by a pair of intermolecular hydrogen bonds using the Watson‐Crick sites. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

血红蛋白在纳米孔径氧化铝膜修饰电极上的直接电化学

运用电化学包埋法成功将血红蛋白(Hb)固定于纳米孔阳极氧化铝膜(AAO)修饰的玻碳电极(GC)表面, 制得Hb/PPy/AAO/GC修饰电极, 并对Hb/PPy/AAO/GC修饰电极的制备条件进行了优化. 研究了Hb/PPy/AAO/GC修饰电极在磷酸缓冲液(pH＝6.8)中的电化学行为, 探讨了血红蛋白在AAO修饰电极表面的直接电子转移机理. 结果表明阳极氧化铝膜不仅保持了血红蛋白的生物活性, 而且通过它的纳米尺寸效应, 实现了Hb与电极之间的直接电子转移. 其研究内容对生命科学和临床医学有着重要意义.     

Periodic folded waves for a （2＋1）-dimensional modified dispersive water wave equation

A general solution, including three arbitrary functions, is obtained for a (2+1)-dimensional modified dispersive water-wave (MDWW) equation by means of the WTC truncation method. Introducing proper multiple valued functions and Jacobi elliptic functions in the seed solution, special types of periodic folded waves are derived. In the long wave limit these periodic folded wave patterns may degenerate into single localized folded solitary wave excitations. The interactions of the periodic folded waves and the degenerated single folded solitary waves are investigated graphically and found to be completely elastic.