Fuel Assembly Arrangement Optimization for NHR-200

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New Membranes Based on Polybenzimidazole for Polymer Fuel Cells

1 Results Acid-doped polybenzimidazoles[1] are particularly appealing because of high proton conductivity with no or low humidification and promising fuel cells performances. PBI, in fact, contains basic functional groups which can easily interact with strong oxo-acids, such as H3PO4 and H2SO4. The acid partially protonates the polymer and partially is freely dispersed in the polymer backbone, so allowing proton migration via Grotthuss mechanism along the anionic chains[2]. Anyway, a technological limit...     

秸秆生物质炭室温吸附气态甲醛的研究

研究采用ZnCl2 活化农业秸秆废弃物的方法制备高比表面积的生物质炭( BACs) ,以实现室温下高效吸附气态甲醛.工业分析和元素分析表明所用农业秸秆是适宜的BACs前体物,且比表面积、扫描电镜、傅里叶红外光谱和热重分析结果表明BACs能够实现理想吸附效果.系统性实验探究了活化条件、O2 和气态甲醛浓度对BACs吸附性...     

基于计算流体力学的熔盐燃料电池电堆的仿真

基于计算流体力学技术，建立并仿真了10kW级顺流型熔融碳酸盐燃料电池（MCFC）电堆的三维模型，对电堆内部的物质、动量和能量守恒过程进行了理论分析，模型考虑了MCFC电堆的一个重要组成部分-波状板，并讨论了波状板尺寸对电堆性能的影响，结果表明，在采用较大尺寸波状板的电堆中，电化学反应进行得更加充分，所建模型对电堆内部流场的设计有一定意义。     

车用发动机的稀薄燃烧系统分析

叙述了车用发动机实现稀薄燃烧的关键技术,介绍了实现车用发动机稀薄燃烧的缸外喷射稀燃系统、直接喷射稀燃系统和均质混合气压燃系统,分析了各稀燃系统的特点以及存在的问题,提出了车用发动机实现稀薄燃烧是提高发动机经济性和改善排放性能的重要途径.     

车用发动机高压电控喷油器的开发研究

以提高大功率车用发动机的动力性,经济性和排放性能为目的,对电控高压喷油器进行开发设计和实验研究,采用中压油源,由系统内部增压器来产生理想喷射所需的高压;通过蓄压装置和高速电磁开关阀控制喷油正时。结果 实验表明：最高喷油压力达１２４ＭＰａ,喷油规律的控制不受发动机转速影响,在系统结构和供油压力确定不变的条件下,完全由高速电磁开关阀的控制信号决定。     

基于TM影像的森林三维绿量的遥感测算

以北京市八达岭林场为研究区,TM影像为数据源,结合地面样地调查数据,利用多元线性回归分析法分树种建立了北京市八达岭林场三维绿量(TGB)的估测模型。对估测模型进行评价和精度验证,得到阔叶林、针叶林、混交林三维绿量模型的决定系数(R2)分别为0.858、0.756、0.759,测算精度为85.63%。基于模型估测八达岭林场的三维绿量,总量为1 498.635万m3;与利用森林资源二类调查数据计算的地面实测三维绿量对比,测算精度为90.89%。     

液化石油气代替汽车燃料的应用现状及性能分析

本文对国内外用液化石油气作为车用燃料的应用状况作以介绍；对双燃料汽车的性能进行了分析。     

阳极负载型SOFC阳极基底厚度对性能的影响

制备不同厚度阳极负载型YSZ薄膜固体氧化物燃料电池 ,并对电池的极化、放电性能进行了测试 .结果表明 ,电池的性能明显受阳极性能的影响 ,阳极过电位大的原因之一是受多孔阳极气体扩散的影响 .降低阳极基底的厚度 ,阳极过电位明显减小 ,电池性能明显提高 .当阳极基底厚度为 0 .5mm时 ,在 80 0℃工作温度下 ,电池的功率密度达到 0 .1 9W·cm- 2 ,较之阳极厚度为 1 .0mm的电池性能提高近 1 .5倍 (0 .1 3W·cm- 2 ) .     

Catalytic Transfer Hydrogenation and Acid Reactions of Furfural and 5-(Hydroxymethyl)furfural over Hf-TUD-1 Type Catalysts

Heterogeneous catalysis, which has served well the petrochemical industry, may valuably contribute towards a bio-based economy by sustainably enabling selective reactions to renewable chemicals. Carbohydrate-containing matter may be obtained from various widespread sources and selectively converted to furanic platform chemicals: furfural (Fur) and 5-(hydroxymethyl)furfural (Hmf). Valuable bioproducts may be obtained from these aldehydes via catalytic transfer hydrogenation (CTH) using alcohols as H-donors under relatively moderate reaction conditions. Hafnium-containing TUD-1 type catalysts were the first of ordered mesoporous silicates explored for the conversion of Fur and Hmf via CTH/alcohol strategies. The materials promoted CTH and acid reactions leading to the furanic ethers. The bioproducts spectrum was broader for the reaction of Fur than of Hmf. A Fur reaction mechanism based on literature data was discussed and supported by kinetic modelling. The influence of the Hf loading and reaction conditions (catalyst load, type of alcohol H-donor, temperature, initial substrate concentration) on the reaction kinetics was studied. The reaction conditions were optimized to maximize the yields of 2-(alkoxymethyl)furan ethers formed from Fur; up to 63% yield was reached at 88% Fur conversion, 4 h/150 °C, using Hf-TUD-1(75), which was a stable catalyst. The Hf-TUD-1(x) catalysts promoted the selective conversion of Hmf to bis(2-alkoxymethyl)furan; e.g., 96% selectivity at 98% Hmf conversion, 3 h/170 °C for Hf-TUD-1(50).