FTIR光谱快速鉴别刺梨黄酮的研究

采用傅里叶变换红外光谱（FTIR）分析了新鲜野生刺梨果肉、烘干刺梨果肉以及室温存放数日后刺梨果肉的红外光谱特性。为对比新鲜果肉与烘干果肉样品中刺梨黄酮的红外光谱特性,以新鲜野生刺梨果实为研究对象,分别采用了超声辅助溶剂萃取法和超声结合酶辅助半仿生法提取刺梨黄酮。并使用无水乙醇作为超声辅助溶剂萃取法的萃取剂萃取刺梨黄酮,以及使用胃蛋白酶,胰酶和胆汁等模仿胃肠消化的环境,在模拟半仿生条件下提取刺梨黄酮。在两种提取方法中,新鲜果肉和烘干果肉分别反应了0,0.5,1,1.5,2和2.5 h。分别测定了新鲜果肉刺梨黄酮和烘干果肉刺梨黄酮的红外光谱数据。然后,通过分析刺梨黄酮的红外光谱特性,比较了两种方法所提取刺梨黄酮的最佳特征波长组合,得知在相同的反应条件下,反应时间为1.5 h时,超声辅助溶剂萃取法中新鲜果肉与烘干果肉提取物红外光谱对应的透射率强度分别为83.5%和84%;超声结合酶辅助半仿生法中新鲜果肉与烘干果肉提取物红外光谱对应的透射率强度分别为32%和38%。因此,结合郎伯-比尔定律可知,反应时间相同时,对于刺梨黄酮的提取,超声结合酶辅助半仿生法优于超声辅助溶剂萃取法。除此之外,我们发现随着反应时间延长,两种提取方法所获提取物的红外光谱吸收峰强度均呈上升趋势,但是反应2 h后该提取物的红外光谱吸收峰强度趋于平稳。结果表明,刺梨黄酮在3 419 cm-1（羟基O-H伸缩振动）、1 615 cm-1（羰基C═O键伸缩振动）和1 053 cm-1（烷基）处的红外吸收峰对刺梨的新鲜程度具有较好的识别效果;通过比较分析,新鲜果肉与室温存放数日后果肉中的刺梨黄酮物质的红外光谱吸收峰分别与槲皮素和山奈酚吸收峰波数一致;在相同实验条件下,两种提取方法中烘干果肉刺梨黄酮提取物浓度均高于新鲜刺梨果肉。该研究可为刺梨功能化药品和食品的制作及鉴定提供参考。     

STUDY ON ELIMINATING FLUORESCENCE IN COTTON PULP WITH PERACETIC ACID

INTRODUCTIONIn resent years people have paid more and more attention to the elimination of fluorescence in cotton linter for the sake of getting better cotton linter pulp since some user ask for higher quality cotton pulp. Cotton linter is a kind of industrial material used to make fine paper, synthetic fiber, medicine additives and other chemical products. Some impurities containing fluorescence usually enter into linter during the processing and purchase, especially in the low grade of l…     

关于半纤维素对纸张物理强度的影响

本文对半纤维素在纸张抄造过程中的作用进行了阐述,指出了加入和保留一定量的半纤维素对纸张物理强度的影响。     

过醋酸蒸煮脱除棉浆荧光的工艺研究

通过正交及单因素实验，初步探讨了过醋酸在棉浆蒸煮过程中脱除荧光的效果，并分析了原料预处理对制浆工艺的影响。优化工艺制得棉浆得率迭91％，ISO白度达87．76％，棉浆中荧光的脱除率达90％以上。     

A recursive linear programming analysis of the future of the pulp and paper industry in the United States: Changes in supplies and demands,and the effects of recycling

The impacts of increased paper recycling on the U.S. pulp and paper sector are investigated, using the North American Pulp And Paper (NAPAP) model. This dynamic spatial equilibrium model forecasts the amount of pulp, paper and paperboard exchanged in a multi-region market, and the corresponding prices. The core of the model is a recursive price-endogenous linear programming system that simulates the behavior of a competitive industry. The model has been used to make forecasts of key variables describing the sector from 1986 to 2012, demand for paper would have the greatest impact on the amount of wood used. But the minimum recycled content policies envisaged currently would have no more effect than what will come about due to unregulated market forces.     

蔗渣浆的压力过氧化氢漂白

对烧碱-蒽醌(Soda-AQ)法蔗渣浆分别进行了螯合预处理(Q)和常压过氧化氢(P)、压力过氧化氢(PO)漂白的研究,探讨了单段PO漂白蔗渣浆的可行性.正交试验结果表明,PO漂白蔗渣浆优化的漂白条件为漂白温度100℃、时间80min、压力0.6MPa、NaOH用量0.4%.PO漂白浆的白度较高,达84.0%ISO,特性黏度为825.3mL/g,比QP漂白浆的白度高9.9%ISO;PO漂白浆的物理强度性能也较好,浆料的抗张指数为66.67N.m/g,撕裂指数为9.34mN.m2/g,耐破指数为4.31 kPa.m2/g,耐折度为39次.PO漂白废水的化学耗氧量、生化耗氧量及色度较低,漂白废水可全部逆流回用,大大减少了污染排放.     

Polarization beats in a pillar microcavity

The beats of the Stokes luminescence parameters in pillar semiconductor microcavities are theoretically analysed. The beats are originated by a slight in-plane anisotropy of the pillar. The influence of the coherence time of exciton polaritons on the decay rate of polarization oscillations of the emission of light by the cavity is revealed. This link is essential for studies of the dynamic properties of polariton condensates in pillar microcavities.     

Low-Loss Many-to-One Fiber Couplers with Few or Single-Moded Inputs and a Multi-Mode Output

The coupling of light from a number of few or single-moded fibers into a single multi-mode fiber is analyzed using geometric optics, and simple results demonstrating mode conservation are derived. Coupling from multiple single-mode fibers into a multi-mode fiber is investigated in detail using the overlap integral to determine coupling into each mode of the output fiber as a function of the light phase in the inputs. As well as results with practical relevance to fiber tapped delay-line filters and optical CDMA, the analysis provides pedagogic insight into light propagation and the light-gathering properties of fiber.     

全亚麻卷烟纸的研制与开发

对亚麻纤维进行打浆、抄片,检测物理指标,根据抄片指标,制定出适合生产全亚麻卷烟纸的打浆工艺,根据生产车间工艺设备配置,对盘磨磨齿进行选择、对打浆功率进行调整,对打浆浓度、打浆度、湿质量进行控制,成功开发出预期目标的全亚麻卷烟纸.     

Raman Micro-Spectroscopy of Dental Pulp Stem Cells: An Approach to Monitor the Effects of Cone Beam Computed Tomography Low-Dose Ionizing Radiation

The objective of this study was to determine the molecular and biochemical changes in dental pulp stem cells (DPSCs) due to consecutive low-dose ionizing radiation exposures using label-free Raman micro-spectroscopy (RMS). Ionizing radiation produces biological damage leading to health effects of varying severity. The effects and subsequent health implications caused by exposure to low-dose radiation, such as diagnostic exposure, remain ambiguous. We identified Raman biomarkers characteristic to low-dose cone beam computed tomography (CBCT) irradiation of the DPSCs. The biomarkers were monitored inside the cells using the relative intensity distribution of the 785 and 1734?cm^?1 bands. The control cells presented a higher relative intensity of the nucleic acid specific Raman bands, whereas the irradiated cells revealed an increased intensity of the lipid-induced bands. The results obtained in this study demonstrate the capability of RMS for the detection of cell response to diagnostic radiation dose levels. This may indicate the potential of the technique for future applications such as monitoring the radiation responses in pediatric patients suffering repeated radiological exposures.