Simultaneous Determination of Carbamate and Organophosphorus Pesticides in Honeybees by Liquid Chromatography-Mass Spectrometry

Summary The potential of liquid chromatography-mass spectrometry (LC-MS) has been studied for the simultaneous determination of sixteen carbamate and organophosphorus pesticides in honeybees using a traditional sample preparation protocol based on acetone extraction and dichloromethane partitioning. The performances of both atmospheric pressure chemical ionization (APCI) and electrospray (ES) interfaces were compared. APCI offered better sensitivity and specificity for a higher range of pesticides. Limits of quantification were from 0.01 to 0.17 mg kg^–1, at which recoveries obtained were between 64 and 93%, except for pirimicarb that was at 13%, with relative standard deviations ranging from 7 to 20%. Fenitrothion, fenoxycarb, methiocarb and phoxim were found in bees from Valencian Community beehives at concentrations between 0.03 and 3.75 mg kg^–1.     

溶膜预富集-石墨炉原子吸收法测定痕量钯

强酸性条件下 ,钯 (Ⅱ )与 5 [( 5 氯 2 吡啶 )偶氮 ] 2 ,4 二氨基甲苯 ( 5 Cl PADAT)生成紫红色螯合物 ,该螯合物可与十二烷基苯磺酸钠 (SDBS)生成离子缔合物 ,离子缔合物经 0 .3μm孔径的硝化纤维微孔滤膜富集后 ,于小体积 ( 0 .5mL)的浓硫酸中溶膜 ,用石墨炉原子吸收法 (GFAAS)测定 ,富集倍数可达 2 0 0倍 ,钯含量在 4.69× 1 0 - 1 2 ～ 7.0 9× 1 0 - 9mol/L范围内线性良好 ,检出限为 1 .78×1 0 - 1 2 mol/L。方法用于海水中痕量钯的测定。     

An “Instrumental Approach” to Study the Integration of a Computer Tool Into Mathematics Teaching: the Case of Spreadsheets

This article reports on research focused on the integration of a specific computer tool, the spreadsheet, into mathematics teaching. After presenting some important results obtained by research in this area, we revisit these in the light of an instrumental approach, which we perceive as essential to analyse the construction of mathematical meanings in spreadsheet environments and to understand better the questions of technological integration. Then, these theoretical elements are used in order to design an exploratory experiment with grade 7 pupils and analyse its results.     

非对称核物质中同位旋对称势的动量和密度依赖性

在Brueckner-Hartree-Fock理论框架内, 研究了同位旋非对称核物质中质子和中子单粒子势的动量相关性及其随同位旋非对称度的变化, 在此基础上计算了同位旋对称势, 并讨论了三体核力的影响. 结果表明同位旋对称势对于同位旋非对称度的依赖性很弱, 但对于动量和密度均有较强的依赖性. 当密度固定时, 同位旋对称势随动量增加而减小. 尽管三体核力对于质子和中子单粒子势的动量相关性有较大影响, 但对同位旋对称势的影响很小. 还与目前重离子碰撞输运理论模型中所使用的各种参数化的唯象对称势进行了比较.     

Precise measurement of hyperfine structure in the state of Rb

We demonstrate a technique to measure hyperfine structure using a frequency-stabilized diode laser and an acousto-optic modulator locked to the frequency difference between two hyperfine peaks. We use this technique to measure hyperfine intervals in the 5 P _3/2 state of ⁸⁵Rb and obtain a precision of 20 kHz. We extract values for the magnetic-dipole coupling constant A = 25.038(5) MHz and the electric-quadrupole coupling constant B = 26.011(22) MHz. These values are a significant improvement over previous results. Received 6 March 2003 Published online 15 April 2003     

Dispersion analysis of the least‐squares finite‐element shallow‐water system

The frequency or dispersion relation for the least‐squares mixed formulation of the shallow‐water equations is analysed. We consider the use of different approximation spaces corresponding to co‐located and staggered meshes, respectively. The study includes the effect of Coriolis, and the dispersion properties are compared analytically and graphically with those of the mixed Galerkin formulation. Numerical solutions of a test problem to simulate slow Rossby modes illustrate the theoretical results. Copyright © 2003 John Wiley & Sons, Ltd.     

浅谈搞好高校电子阅览室工作应注意的问题

论述了要使高校电子阅览室很好地发挥效能,应当注意的几个方面。     

空调施工常见问题分析

提出空调工程施工中及安装交工前设备和系统调试存在的问题,并指出空调试车和运行中的注意事项及相应改进方法。     

上郊水库大坝安全鉴定及除险加固措施

针对上郊水库存在的主要质量问题,结合水利部的有关精神和要求,提出了相应的安全鉴定项目以及除险加固措施。     

清末民初"废庙兴学"的历史人类学考察

清末民初,伴随着中国文化及乡村教育现代化的步伐,中国乡村社会曾兴起一股"废庙兴学"之风。其最初只是一种有知之士个人在民间的自发行为;清末新政将其作为教育改革的重要内容,在全国广泛推行(实际上只是部分地区执行);民国初年,"废庙兴学"进入了一个高潮期,对推进乡村教育发挥了一定作用,但遇到了宗教文化和乡村传统势力等重重阻力。"废庙兴学"是一个多面体,它既有促进国民教育、提高民众教育程度的积极作用,又扩大了我国民间宗教文化自身的影响,加强了宗教文化的发展与壮大;也可能成为激化民众社会矛盾、危害国民教育的有效实施,其消极影响不可低估。