Internal Rotation of the Methyl Group in Cations of Toluene Derivatives

The potential of the internal rotation of the methyl group was determined for o-, m-, and p-fluorotoluene cations by pulsed field ionization spectroscopy. The potential of the internal rotational motion was also surveyed for other toluene derivative cations. It was found that the barrier height generally increases by ionization. The increase in the barrier height has been discussed in connection with the reduction of the internal rotational constant B by ionization. The geometrical distortion of the methyl group during the internal rotation has been suggested.     

一种新的改进Canny图像边缘检测算法

针对传统的Canny算法在平滑滤波时对图像边缘检测的影响,以及需要预先设定高低阈值等缺点,本文提出了一种新的Canny边缘检测算法。首先采用自适应中值滤波对图像进行处理;其次,添加45°和135°方向的梯度模板来计算梯度幅值;最后,采用Otsu算法计算经梯度幅值运算得到图像的高低阈值。实验结果表明,该改进的Canny算法具有良好的抗噪性能,并且能精确的检测出边缘信息。     

基于相关法的差分式科氏流量计幅值检测算法

为提高差分式科氏流量计幅值检测的精度,提出了基于相关法的幅值检测算法。首先构造两路与采样信号同频的参考信号,然后分别与采样信号进行互相关得到互相关信号,估计出采样信号的初相位,最后检测出采样信号的幅值。理论分析表明:该方法不受信号非整周期采样的影响。仿真实验结果表明:该方法提高了检测精度,在信噪比45d B时,测量相对误差低于0.25%。     

长链支化聚丙烯的非线性流变行为

通过大幅振荡剪切试验方法, 研究了长链支化聚丙烯的非线性流变学行为, 揭示了长链支化结构与非线性黏弹响应的关系. 利用傅里叶变换流变学方法得到试样的三次倍频相对振幅I_3/1与应变的标度关系, 用于界定线性聚丙烯和长链支化聚丙烯非线性流变行为的差异, 并定义了非线性系数来量度长链支化程度. 在高应变下, I_3/1与应变的变化关系可以进一步描述长链支化在非线性流场下的特性, 并得到了长链支化程度与其非线性响应之间的变化关系. 通过应力波的Lissajous曲线分解, 发现了环内和环间黏弹性的差异, 长链支化结构在大应变流场下的非线性黏弹性响应弱于线性结构, 支化程度越高非线性响应越弱.     

Oscillation of solutions of second-order linear differential equations and corresponding difference equations

In this paper, we present conditions ensuring that solutions of linear second-order differential equations oscillate, provided solutions of corresponding difference equations oscillate. We also establish the converse result, namely, when oscillation of solutions of difference equations implies oscillation of solutions of corresponding differential equations.     

周边面内压力作用下夹层圆板的非线性振动

基于von Krmn薄板理论,讨论了滑动固定基础上周边面内压力作用下夹层圆板的非线性振动问题,应用变分法导出了该问题的非线性特征方程和边界条件,给出了其精确静态解,并使用修正迭代法求解了该方程,导出了夹层圆板振幅和非线性振频的解析关系式．当周边面力使夹层圆板的最低固有频率为零时,就可获得临界载荷的值．     

参数激励的幅值不是很小时Mathieu方程的一种解法

用改进的变形参数法求得了激励的幅值不是小量时Mathieu方程的周期解及过渡曲线。     

Compact DG modules and Gorenstein DG algebras

When the base connected cochain DG algebra is cohomologically bounded, it is proved that the difference between the amplitude of a compact DG module and that of the DG algebra is just the projective dimension of that module. This yields the unboundedness of the cohomology of non-trivial regular DG algebras. When A is a regular DG algebra such that H(A) is a Koszul graded algebra, H(A) is proved to have the finite global dimension. And we give an example to illustrate that the global dimension of H(A) may be infinite, if the condition that H(A) is Koszul is weakened to the condition that A is a Koszul DG algebra. For a general regular DG algebra A, we give some equivalent conditions for the Gorensteiness. For a finite connected DG algebra A, we prove that D^c(A) and D^c(A ^op) admit Auslander-Reiten triangles if and only if A and A ^op are Gorenstein DG algebras. When A is a non-trivial regular DG algebra such that H(A) is locally finite, D^c(A) does not admit Auslander-Reiten triangles. We turn to study the existence of Auslander-Reiten triangles in D_lf^b(A) and D_lf^b (A ^op) instead, when A is a regular DG algebra. This work was supported by the National Natural Science Foundation of China (Grant No. 10731070) and the Doctorate Foundation of Ministry of Education of China (Grant No. 20060246003)     

阵列幅相误差背景下MUSIC算法的DSP实现

针对空间谱估计算法在实际应用中的误差问题,讨论了在存在阵列幅相误差背景下,多重信号分类法(MUSIC:MUltiple SIgnal Classification)测向算法在DSP(Digital Signal Processor)上实现的一种方法.通过设置方位精确的辅助阵元对幅相误差进行校正,辅助阵元的方位信息为误差参数的计算提供了必要的信息量,然后利用MUSIC算法进行波达方向估计,同时利用TI公司高速DSP芯片(TMS320C6713)实现了在阵列幅相误差背景下的MUSIC测向方法.仿真结果证明了该方法的有效性.